N,n,n,n-四烯丙基-1,4-二氨基丁烷 | 54391-08-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: N,n,n,n-四烯丙基-1,4-二氨基丁烷
• 英文名称: tetra-N-allyl-butanediyldiamine
• 英文别名: Tetra-N-allyl-butandiyldiamin；N,N,N',N'-Tetraallyl 1,4-diamino butane；N,N,N',N'-tetrakis(prop-2-enyl)butane-1,4-diamine
• CAS: 54391-08-1
• 化学式: C₁₆H₂₈N₂
• 分子量: 248.412
• InChiKey: WYRJQOPVEMCABI-UHFFFAOYSA-N

物化性质

• 沸点：
  96-98 °C(Press: 0.1 Torr)
• 密度：
  0.863±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  18
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2921290000

反应信息

• 作为反应物：
  描述：

  溴甲烷 、 N,n,n,n-四烯丙基-1,4-二氨基丁烷 生成 N,N,N',N'-tetraallyl-N,N'-dimethyl-N,N'-butanediyl-di-ammonium; dibromide
  参考文献：
  名称：

  Preparation and Polymerization of Unsaturated Quaternary Ammonium Compounds. VII. Derivatives of 1,X-Diamino-alkanes¹

  摘要：

  DOI：

  10.1021/ja01599a068
• 作为产物：
  描述：

  tetra-N-allyl-succinamide 在 lithium aluminium tetrahydride 、 乙醚 作用下， 生成 N,n,n,n-四烯丙基-1,4-二氨基丁烷
  参考文献：
  名称：

  The Course of the Reaction of 1,4- and 1,5-Dihalo- and Di-(arylsulfonoxy)-alkanes with Diallylamine

  摘要：

  DOI：

  10.1021/ja01612a014

文献信息

• METHOD OF INCREASING MASS TRANSFER RATE OF ACID GAS SCRUBBING SOLVENTS
  申请人：THE UNIVERSITY OF KENTUCKY RESEARCH FOUNDATION

  公开号：US20140294705A1

  公开（公告）日：2014-10-02

  A method of increasing the overall mass transfer rate of acid gas scrubbing solids is disclosed. Various catalyst compounds for that purpose are also disclosed.

  本发明揭示了一种增加酸气洗涤固体的总传质速率的方法。还揭示了用于此目的的各种催化剂化合物。
• Papermaking chemical, method for manufacturing same, and paper containing same
  申请人：Kiyosada Toshitsugu

  公开号：US20050272889A1

  公开（公告）日：2005-12-08

  A novel (meth)acrylamide polymer capable of forming a papermaking chemical exhibiting an excellent paper strengthening effect, drainage improvement effect, retention improvement effect, plybond strength enhancing effect, surface strength enhancing effect, and sizing improvement effect in acid, neutral, or alkaline papermaking systems, as well as a method for manufacturing this polymer, and paper that makes use of this polymer and has excellent bursting strength, internal bond strength, and other such properties is provided. This is a (meth)acrylamide polymer produced by polymerizing a monomer (a) expressed by the following general formula 1, the following monomer (b), and the following monomer (c): (a) general formula 1: (b) a (meth)acrylamide; (c) an ionic monomer other than monomer (a) expressed by general formula 1 above

  提供了一种新型（甲基）丙烯酰胺聚合物，能够形成一种造纸化学品，具有优异的造纸强化效果、排水改善效果、保留改善效果、层压强度增强效果、表面强度增强效果和尺寸稳定性改善效果，适用于酸性、中性或碱性造纸系统，以及制造该聚合物的方法和使用该聚合物的纸张，具有优异的爆裂强度、内部粘合强度和其他类似性能。该聚合物是通过聚合以下通式1所表示的单体（a）、以下单体（b）和以下单体（c）制备的：（a）通式1：（b）（甲基）丙烯酰胺；（c）除通式1所述的单体（a）之外的离子单体。
• Process for producing polymers of monoallylamine
  申请人：ETHYL CORPORATION

  公开号：EP0242791A2

  公开（公告）日：1987-10-28

  Polymers of monoallylamine are produced by polymerizing monoallylamine in an aqueous reaction medium in the presence of a multivalent metal ion-hydrogen peroxide polymerization initiator. Metal ion sources such as FeCl3, FeCl2, MnCI2 and CuCl2 have been successfully used. The monoallylamine is normally introduced into the polymerization system in the form of a water soluble salt of monoallylamine. The hydrogen peroxide is preferably introduced either continuously or periodically during the reaction.

  单烯丙基胺聚合物是在水性反应介质中，在多价金属离子-过氧化氢聚合引发剂的存在下，通过聚合单烯丙基胺生产出来的。 已成功使用的金属离子源有 FeCl3、FeCl2、MnCI2 和 CuCl2。 单烯丙基胺通常以单烯丙基胺水溶性盐的形式引入聚合体系。 过氧化氢最好在反应过程中连续或定期引入。
• Poly(amic acid) solution, use thereof and polyimide film or polyimide-coated material obtained therefrom
  申请人：UNITIKA LTD.

  公开号：EP0705862A1

  公开（公告）日：1996-04-10

  This invention provides a poly(amic acid) solution which does not contain aprotic polar solvents such as DMF, NMP, DMAc, DMSO, as well as a polyimide film obtained therefrom having appropriate flexibility and a small coefficient of linear thermal expansion and a coated material in which the polyimide film is formed on a substrate. More particularly, it provides a poly(amic acid) solution which has an aromatic poly(amic acid) and a tertiary amine as the solute and a water soluble alcohol compound and/or a water soluble ether compound as the solvent and contains substantially no aprotic polar solvent, as well as a polyimide film obtained from the poly(amic acid) solution and a coated material obtained by forming the film on a substrate.

  本发明提供了一种不含诸如 DMF、NMP、DMAc、DMSO 等钝极性溶剂的聚(氨基)酸溶液，以及由其获得的具有适当柔韧性和较小线性热膨胀系数的聚酰亚胺薄膜和在基材上形成聚酰亚胺薄膜的涂层材料。 更具体地说，本发明提供了一种以芳香族聚(amic acid)和叔胺为溶质、以水溶性醇类化合物和/或水溶性醚类化合物为溶剂且基本上不含烷基极性溶剂的聚(amic acid)溶液，以及一种由聚(amic acid)溶液得到的聚酰亚胺薄膜和一种在基底上形成该薄膜的涂层材料。
• Additive for papermaking and process for papermaking
  申请人：JAPAN PMC CORPORATION

  公开号：EP0735186A2

  公开（公告）日：1996-10-02

  A novel additive for papermaking is disclosed. The additive comprises an aqueous solution of a copolymer obtained by reacting (a) an acrylamide, (b) a vinyl monomer which is copolymerizable with component (a) and has a cationic group, (c) at least one of vinyl monomers which are copolymerizable with component (a) and (b) and have 2, 3 or 4 carboxyl groups in a molecule thereof and/or a salt thereof, optionally (e) a nonionic monomer which is copolymerizable with components (a), (b) and (c) if desired, and (d) a cross-linking compound, in the presence of (f) at least one of ethylene glycol, diethylene glycol, diethanolamine and glycerin. This novel additive for papermaking is able to achieve excellent freeness and yield in the process of papermaking and provides paper with increased strength.

  本发明公开了一种新型造纸添加剂。该添加剂包括一种共聚物的水溶液，该共聚物通过以下反应获得：(a) 丙烯酸酰胺；(b) 可与组分（a）共聚并带有阳离子基团的乙烯基单体；(c) 可与组分（a）和（b）共聚并在其分子中带有 2、(d) 交联化合物，(f) 至少乙二醇、二甘醇、二乙醇胺和甘油中的一种。 这种新型造纸添加剂能够在造纸过程中获得极佳的白度和产量，并提高纸张强度。