1,3-diformyl-2,4,6-triethylbenzene dioxime | 135779-00-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,3-diformyl-2,4,6-triethylbenzene dioxime
• 英文别名: 1,3-Diformyl-2,4,6-tri-ethylbenzene dioxime；N-[[2,4,6-triethyl-3-(hydroxyiminomethyl)phenyl]methylidene]hydroxylamine
• CAS: 135779-00-9
• 化学式: C₁₄H₂₀N₂O₂
• mdl: MFCD00443672
• 分子量: 248.325
• InChiKey: YVCZCIUCJDTVGQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  18
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  65.2
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,3-diformyl-2,4,6-triethylbenzene dioxime 在 sodium hydroxide 、 sodium hypochlorite 作用下， 以 二氯甲烷 为溶剂， 反应 1.0h， 以75%的产率得到1,3-dicyano-2,4,6-triethyl-benzene N,N'-dioxide
  参考文献：
  名称：

  Synthesis of stable functionally substituted nitrile oxides of the aromatic series

  摘要：

  Stable functionally substituted mononitrile oxides were obtained from the previously obtained sterically hindered aldehydes of the mesitylene series. The previously unknown bisnitrile oxide was also synthesized from triethylbenzene; the compound is an effective crosslinking agent. The synthesis was carried out via the stage of oximation and oxidation of the oxime by sodium hypochlorite.

  DOI：

  10.1007/bf00961380
• 作为产物：
  描述：

  2,4,6-triethylisophthalaldehyde 在 sodium hydroxide 、 盐酸羟胺 作用下， 以 乙醇 、 水 为溶剂， 反应 4.0h， 以74%的产率得到1,3-diformyl-2,4,6-triethylbenzene dioxime
  参考文献：
  名称：

  Synthesis of stable functionally substituted nitrile oxides of the aromatic series

  摘要：

  Stable functionally substituted mononitrile oxides were obtained from the previously obtained sterically hindered aldehydes of the mesitylene series. The previously unknown bisnitrile oxide was also synthesized from triethylbenzene; the compound is an effective crosslinking agent. The synthesis was carried out via the stage of oximation and oxidation of the oxime by sodium hypochlorite.

  DOI：

  10.1007/bf00961380

文献信息

• Synthesis of stable functionally substituted nitrile oxides of the aromatic series
  作者：A. P. Yakubov、D. V. Tsyganov、L. I. Belen'kii、M. M. Krayushkin

  DOI：10.1007/bf00961380

  日期：1991.5

  Stable functionally substituted mononitrile oxides were obtained from the previously obtained sterically hindered aldehydes of the mesitylene series. The previously unknown bisnitrile oxide was also synthesized from triethylbenzene; the compound is an effective crosslinking agent. The synthesis was carried out via the stage of oximation and oxidation of the oxime by sodium hypochlorite.