N-(2-(甲基丙烯酰)乙基)-N,N-二甲基-1-丁胺溴化物 | 66062-59-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: N-(2-(甲基丙烯酰)乙基)-N,N-二甲基-1-丁胺溴化物
• 英文名称: N-(n-butyl)-N,N-dimethyl-N-[2-(methacryloyloxy)ethyl]ammoniumbromide
• 英文别名: 2-(N-butyl-N,N-dimethylamino)ethyl methacrylate bromide；BDMAEMA Br；Methacryloyloxyethylbutyldimethylammonium bromide；butyl-dimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium;bromide
• CAS: 66062-59-7
• 化学式: Br*C₁₂H₂₄NO₂
• 分子量: 294.232
• InChiKey: JPTOEYVAAZFYGV-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -1.01
• 重原子数：
  16
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  N-(2-(甲基丙烯酰)乙基)-N,N-二甲基-1-丁胺溴化物 在 双氟磺酰亚胺钾盐 作用下， 以 水 为溶剂， 反应 3.0h， 以90%的产率得到N-(n-butyl)-N,N-dimethyl-N-[2-(methacryloyloxy)ethyl]ammonium bis(fluorosulfonyl)imide
  参考文献：
  名称：

  Polymeric ionic liquids based on ether functionalized ammoniums and perfluorinated sulfonimides

  摘要：

  A new family of polymeric ionic liquids (PILs) based on alkyl and alkyl ether substituted ammoniums and perfluorinated sulfonimides (i.e., bis(fluorosulfonyl)imide (FSI-), and bis(trifluoromethanesulfonyl)imide (TFSI-)) have been synthesized by polymerization of the corresponding ionic liquid monomers (ILMs). Their structures and compositions have been characterized by H-1 and F-19 NMR, FTIR and viscosity-average molecular weight (M-v). The physicochemical properties of both the ILMs and the PILs have been studied in terms of thermal stability, phase transition, and ionic conductivity. All the prepared ILMs and PILs reveal excellent thermal stabilities to greater than 250 degrees C. The PILs containing alkyl ether side unit show significant decrease in glass transition temperature (T-g), the values of T-g of the alkyl ether based-PILs are all significantly lower by 10-77 degrees C in magnitude than those of the corresponding alkyl based ones. The ionic conductivity of alkyl ether based-PILs in the best case increases up to 4.0 x 10(-6) S cm(-1) at 30 degrees C, and reaches 7.6 x 10(-5) S cm(-1) at 60 degrees C, and outperform their ammonium counterparts with alkyl side chain that were synthesized as references. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.polymer.2014.03.041
• 作为产物：
  描述：

  正溴丁烷 、 甲基丙烯酸二甲氨乙酯 以 乙酸乙酯 为溶剂， 反应 24.0h， 生成 N-(2-(甲基丙烯酰)乙基)-N,N-二甲基-1-丁胺溴化物
  参考文献：
  名称：

  用于将 CO2 和环氧化物吸收转化为环状碳酸酯的聚合物离子液体膜

  摘要：

  聚合物离子液体膜 (PILM) 通过光引发聚合 DMAEMA 基离子液体 (IL) 和共聚单体将 CO 2转化为环状碳酸酯而制备。研究了官能团和阴离子的影响，以找到最佳的离子液体单体。基于 [DMAEMA-EtOH]Br 的 PILM 表现出最高的碳酸丙酯 (PC) 产率 (98%)，接近 [DMAEMA-EtOH]Br 单体的产率。此外，PILMs可以催化气态环氧丙烷（PO）和CO 2转化为 PC 的 PO 转化率为 87.3%，而纯聚合离子液体的 PO 转化率仅为气态 PO 的 3.1%。优异的催化活性可归因于 PILM 的高活性催化位点和出色的溶胀能力。干燥的 PILM 可以吸收 PO 蒸气并溶胀成具有丰富孔隙的膜，其中含有丰富的活性位点，可有效地将 PO 和 CO 2催化为 PC。

  DOI：

  10.1016/j.mcat.2022.112597

文献信息

• Effects of interaction between a polycation and a nonionic polymer on their cross-assembly into mixed micelles
  作者：Xinyuan Wan、Yi Zhang、Ya Deng、Qin Zhang、Jiehua Li、Kunjie Wang、Jianshu Li、Hong Tan、Qiang Fu

  DOI：10.1039/c5sm00380f

  日期：——

  length in quaternary ammonium salts, and the alkyl chain length also influences the distribution and the alkyl chain orientation of quaternary ammonium salts on mixed micelle surfaces. In addition, cytotoxicity of these mixed micelles can be markedly reduced by PPEG compared with their corresponding PQAs, but their good antibacterial activities are still maintained to a certain degree, as evaluated

  为了研究聚（季铵）盐（PQAs）与聚（乙二醇）在自然条件下的相互作用对混合胶束表面结构和性能的影响，首先设计了一系列PQA，并通过原子转移法合成了使用分别由溴丁烷，溴辛烷和溴十二烷季铵化的甲基丙烯酸2-（二甲氨基）乙酯（DMAEMA）进行自由基聚合（ATRP）。还通过ATRP使用聚（乙二醇）甲基醚甲基丙烯酸酯制备了具有相似聚合度的聚（聚乙二醇）甲基醚甲基丙烯酸酯（PPEG）。接下来，将这些PQA与等重量的PPEG在水中混合，以交叉组装成混合胶束。这些混合胶束的结构和特征通过荧光测量来表征，1个H NMR）和氢-氢相关光谱核磁共振（H-H COZY NMR）。这些结果表明，PQA和PPEG混合物可以交叉组装成具有低CMC的混合胶束。可以通过改变季铵盐中的烷基链长度来定制PQA和PPEG混合物的表面结构，粒度，尺寸分布和Zeta电位，并且烷基链长度也会影响季铵盐的分布和烷基链取向在混合的胶束表
• Polymeric ionic liquids tailored by different chain groups for the efficient conversion of CO₂ into cyclic carbonates
  作者：Ting Ying、Xin Tan、Qian Su、Weiguo Cheng、Li Dong、Suojiang Zhang

  DOI：10.1039/c9gc00010k

  日期：——

  catalysts, polymeric ionic liquids as heterogeneous catalysts are tailored for the transformation of CO2 into cyclic carbonates. Herein, six types of self-polymerized polymeric ionic liquids are successfully synthesized by changing the substitutions. Amongst those catalysts, hydroxyl-rich polymeric ionic liquids, especially P(DMAEMA-EtOH)Br, exhibit the highest conversion (96%) to propyl carbonate, which

  为了实现催化剂的高利用率和易于回收利用，量身定制了作为非均相催化剂的聚合物离子液体，用于CO 2的转化变成环状碳酸盐。在本文中，通过改变取代成功地合成了六种类型的自聚合的聚合物离子液体。在这些催化剂中，富含羟基的聚合物离子液体，尤其是P（DMAEMA-EtOH）Br，表现出最高的碳酸丙酯转化率（96％），这几乎可以与本体离子液体的反应性相媲美。羟基的存在不仅大大提高了反应性，而且还提高了热稳定性。分子动力学计算和XPS分析证实，P（DMAEMA-EtOH）Br与环氧化物结合的能力与其单体相当。动态光散射数据表明，减小聚合物颗粒的流体动力学半径有助于更大程度地暴露活性位点，从而导致高反应性。此外，在H-NMR研究的基础上提出了协同催化机理。这种使用聚合物离子液体的环保工艺为转化一氧化碳提供了有希望的催化剂2成增值化学品。
• Polymeric ionic liquid membranes for the absorption-conversion of CO2 and epoxides into cyclic carbonates
  作者：Yifan Liu、Li Dong、Yichao Wang、Qian Su、Xianghai Meng、Weiguo Cheng

  DOI：10.1016/j.mcat.2022.112597

  日期：2022.9

  Polymeric ionic liquid membranes (PILMs) were prepared by photo-initiated polymerization of DMAEMA-based ionic liquids (ILs) and co-monomers for the conversion of CO2 into cyclic carbonates. The influences of functional groups and anions were investigated to find the optimal ionic liquid monomer. The PILM based on [DMAEMA-EtOH]Br exhibited the highest propyl carbonate (PC) yield (98%), which was close

  聚合物离子液体膜 (PILM) 通过光引发聚合 DMAEMA 基离子液体 (IL) 和共聚单体将 CO 2转化为环状碳酸酯而制备。研究了官能团和阴离子的影响，以找到最佳的离子液体单体。基于 [DMAEMA-EtOH]Br 的 PILM 表现出最高的碳酸丙酯 (PC) 产率 (98%)，接近 [DMAEMA-EtOH]Br 单体的产率。此外，PILMs可以催化气态环氧丙烷（PO）和CO 2转化为 PC 的 PO 转化率为 87.3%，而纯聚合离子液体的 PO 转化率仅为气态 PO 的 3.1%。优异的催化活性可归因于 PILM 的高活性催化位点和出色的溶胀能力。干燥的 PILM 可以吸收 PO 蒸气并溶胀成具有丰富孔隙的膜，其中含有丰富的活性位点，可有效地将 PO 和 CO 2催化为 PC。
• ANALYTE CONCENTRATION MEASURING METHOD, PARTICLE CONTAINING AGGLUTINATED FLUORESCENT MATERIAL, AND INSPECTION DEVICE
  申请人：Sekisui Chemical Co., Ltd.

  公开号：EP3508852A1

  公开（公告）日：2019-07-10

  This analyte concentration measuring method including: preparing a mixed solution by mixing a sample solution containing an analyte, with a solution containing aggregation-induced emission fluorescent material-containing particles that have a binding partner which binds with the analyte and that agglutinate and fluoresce when the analyte binds to the binding partner; measuring the fluorescence intensity generated from the aggregation-induced emission fluorescent material-containing particles in the mixed solution; and comparing a fluorescence intensity calibration curve for analyte concentration with the fluorescence intensity, and associating the fluorescence intensity with the analyte concentration in the mixed solution. Employing agglutinating-luminescent-material-containing particles enables measurements to be carried out with a satisfactory detection sensitivity while suppressing background fluorescence.

  这种分析物浓度测量方法包括 制备混合溶液，将含有被分析物的样品溶液与含有聚集诱导发射荧光材料的颗粒的溶液混合，该颗粒具有与被分析物结合的结合伴侣，当被分析物与结合伴侣结合时，该颗粒会凝集并发出荧光； 测量混合溶液中含有聚集诱导发射荧光材料的颗粒产生的荧光强度；以及 将分析物浓度的荧光强度校准曲线与荧光强度进行比较，并将荧光强度与混合溶液中的分析物浓度联系起来。使用含凝集发光材料的颗粒可以在抑制本底荧光的同时，以令人满意的检测灵敏度进行测量。
• Influence of Zwitterions on Thermomechanical Properties and Morphology of Acrylic Copolymers: Implications for Electroactive Applications
  作者：Tianyu Wu、Frederick L. Beyer、Rebecca H. Brown、Robert B. Moore、Timothy E. Long

  DOI：10.1021/ma201211j

  日期：2011.10.25

  n-Butyl acrylate-based zwitterionomers and ionomers containing 3-[[2-(methacryloyloxy)ethyn(dimethypammonio]-1-propanesulfonate (SBMA) and 2-[butyl(dimethyl)amino]ethyl methacrylate methanesulfonate (BDMAEMA MS), respectively, were synthesized using conventional free radical polymerization. Size-exclusion chromatography confirmed the molecular weights of the copolymers exceeded the critical molecular weight between entanglements (Me) for poly(n-butyl acrylate). Differential scanning calorimetry (DSC), small-angle X-ray scattering (SAXS), and atomic force microscopy (AFM) revealed that zwitterionomers promoted more well-defined microphase separation than cationic analogues. Dynamic mechanical analyses (DMA) of the copolymers showed a rubbery plateau region due to physical cross-links between charges for zwitterionomers only. Since SBMA and BDMAEMA MS have very similar chemical structures, we attributed improved microphase separation and superior elastomeric performance of the zwitterionomers to stronger association between covalently tethered charged pairs.