申请人:DEGUSSA AG
公开号:US20020119272A1
公开(公告)日:2002-08-29
A good layer adhesion can be achieved in a composite having two or more layers wherein
a layer I is obtained from a molding composition which has the following components:
a) from 0 to 80 parts by weight of a polyamide selected from the group consisting of PA6, PA66, PA6/66 and a mixture thereof;
b) from 0.05 to 100 parts by weight of a polyamine-polyamide copolymer; and
c) from 0 to 80 parts by weight of a polyamide selected from the group consisting of PA11, PA12, PA612, PA1012, PA1212 and a mixture thereof;
wherein a total of the parts by weight of components a), b) and c) is 100;
wherein at least 20 parts by weight of components a) and b) is a monomer unit which is obtained from caprolactam and/or from a combination of hexamethylenediamine/adipic acid; and
wherein at least 20 parts by weight of components b) and c) is a monomer unit which is obtained from &ohgr;-aminoundecanoic acid, laurolactam, a mixture of hexamethylenediamine and 1,12-dodecanedioic acid, a mixture of 1,10-decanediamine and 1,12-dodecanedioic acid, and/or a mixture of 1,12-dodecanediamine and 1,12-dodecanedioic acid.
在具有两个或多个层的复合材料中可以实现良好的层间附着,其中层I是从模塑组合物中获得的,该组合物具有以下组分:a)从0到80重量份的聚酰胺,所述聚酰胺选自PA6,PA66,PA6 / 66和其混合物的群组成;b)从0.05到100重量份的聚酰胺-聚酰胺共聚物;以及c)从0到80重量份的聚酰胺,所述聚酰胺选自PA11,PA12,PA612,PA1012,PA1212和其混合物的群组成;其中组分a),b)和c)的重量份总和为100;其中至少20重量份的组分a)和b)是从己内酰胺和/或己二胺/己二酸的组合物中获得的单体单位;以及其中至少20重量份的组分b)和c)是从ω-氨基十一酸,月桂内酯,己二胺和1,12-十二二酸的混合物,1,10-癸二胺和1,12-十二二酸的混合物,和/或1,12-十二二胺和1,12-十二二酸的混合物中获得的单体单位。