10-decyloxy-9,10-dihydro-9-oxa-10-phosphaphenanthrene | 52458-38-5

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: 10-decyloxy-9,10-dihydro-9-oxa-10-phosphaphenanthrene
• 英文别名: 6-(Decyloxy)-6H-dibenzo[c,e][1,2]oxaphosphinine；6-decoxybenzo[c][2,1]benzoxaphosphinine
• CAS: 52458-38-5
• 化学式: C₂₂H₂₉O₂P
• 分子量: 356.445
• InChiKey: WEFMTVNJCFTOFQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.6
• 重原子数：
  25
• 可旋转键数：
  10
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  10-decyloxy-9,10-dihydro-9-oxa-10-phosphaphenanthrene 在 对甲苯磺酸甲酯 作用下， 反应 24.0h， 生成 10-decyl-9-oxa-10-phosphaphenanthrene-10-oxide
  参考文献：
  名称：

  A Novel and Effective Synthetic Approach to 9,10-Dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) Derivatives

  摘要：

  DOPO and its derivatives generally exhibit an outstanding performance as flame retardants in various polymers. Starting from trivalent 10-alkoxy-10H-9-oxa-10-phosphaphenanthrenes, a broad range of DOPO derivatives was synthesized via transesterification with aliphatic alcohols and subsequent Michaelis-Arbuzou rearrangement using catalytic amounts of p-toluenesulfonic acid methylester. Due to the considerable differences in the nature of the alcohols employed, several procedures for processing them are presented.

  DOI：

  10.1080/10426500701407417
• 作为产物：
  描述：

  6-ethoxy-6H-dibenzo[c,e][1,2]oxaphosphinine 、 癸醇 120.0 ℃ 、1.0 kPa 条件下， 生成 10-decyloxy-9,10-dihydro-9-oxa-10-phosphaphenanthrene
  参考文献：
  名称：

  A Novel and Effective Synthetic Approach to 9,10-Dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) Derivatives

  摘要：

  DOPO and its derivatives generally exhibit an outstanding performance as flame retardants in various polymers. Starting from trivalent 10-alkoxy-10H-9-oxa-10-phosphaphenanthrenes, a broad range of DOPO derivatives was synthesized via transesterification with aliphatic alcohols and subsequent Michaelis-Arbuzou rearrangement using catalytic amounts of p-toluenesulfonic acid methylester. Due to the considerable differences in the nature of the alcohols employed, several procedures for processing them are presented.

  DOI：

  10.1080/10426500701407417

文献信息

• [EN] SUBSTITUTED PYRIDONES AS INHIBITORS OF POLY(ADP-RIBOSE) POLYMERASE (PARP)<br/>[FR] PYRIDONES SUBSTITUES INHIBITEURS DE LA POLY(ADP-RIBOSE) POLYMERASE (PARP)
  申请人：AVENTIS PHARMA INC

  公开号：WO2005097750A1

  公开（公告）日：2005-10-20

  The present invention discloses and claims a series of 2,3,5-substituted pyridone derivatives as defined herein. This invention also relates to methods of making these compounds. The compounds of this invention are inhibitors of poly(adenosine 5'-diphosphate ribose) polymerase (PARP) and are therefore useful as pharmaceutical agents, especially in the treatment and/or prevention of a variety of diseases, including diseases associated with the central nervous system and cardiovascular disorders.

  本发明公开并声明了一系列如下定义的2,3,5-取代吡啶酮衍生物。本发明还涉及制备这些化合物的方法。本发明的化合物是多聚腺苷酸二磷酸核糖酶（PARP）的抑制剂，因此在制药剂中特别用于治疗和/或预防各种疾病，包括与中枢神经系统和心血管疾病相关的疾病。
• Thermoplastic resin composition and elastomer composition
  申请人：——

  公开号：US20040106732A1

  公开（公告）日：2004-06-03

  Provided are a thermoplastic resin composition which is excellent in oil resistance, heat resistance, weatherability, impact resistance, transparency, and moldability, and which can be produced economically, an elastomer composition with low hardness and high tensile strength which is excellent in oil resistance and compression set, and a molded object produced by molding the thermoplastic resin composition or elastomer composition. The composition is produced by compounding a thermoplastic resin or an elastomer with a block copolymer having at least one methacrylic ester polymer block and at least one acrylic ester polymer block. Also provided are a process for producing a methacrylic ester-acrylic ester-methacrylic ester block copolymer which requires hardly any purification, which is excellent in heat resistance and weatherability, and in which the molecular weight and the molecular-weight distribution are controlled, and a methacrylic ester-acrylic ester-methacrylic ester block copolymer produced by the process.

  提供了一种热塑性树脂组合物，具有优异的耐油性、耐热性、耐候性、抗冲击性、透明度和成型性，且可经济生产；一种低硬度、高拉伸强度的弹性体组合物，具有优异的耐油性和压缩回弹性；以及由该热塑性树脂组合物或弹性体组合物成型而成的成型物。该组合物通过将热塑性树脂或弹性体与至少具有一个甲基丙烯酸酯聚合物块和至少一个丙烯酸酯聚合物块的嵌段共聚物混合制备而成。 同时提供了一种制备甲基丙烯酸酯-丙烯酸酯-甲基丙烯酸酯嵌段共聚物的方法，该方法几乎不需要纯化，具有优异的耐热性和耐候性，并且分子量和分子量分布可控；以及由该方法制备的甲基丙烯酸酯-丙烯酸酯-甲基丙烯酸酯嵌段共聚物。
• Curable composition
  申请人：——

  公开号：US20040249026A1

  公开（公告）日：2004-12-09

  Provided is a curable composition which can easily regulate the properties of a cured object prepared therefrom, which can prepare a cured object that does not substantially discolor or soften a finishing agent or coating material applied to the surface thereof, and which has a high curing rate in the inner regions. The curable composition contains (A) a polymer having at least one mercapto group at the molecular ends, the polymer being derived from a thiocarbonylthio group-containing polymer (a2) prepared by polymerizing a monomer (a1) which contains an acrylic ester as a principal component and which contains 50% by weight or more of the acrylic ester and less than 50% by weight of a monomer copolymerizable with the acrylic ester in the presence of a thiocarbonylthio group-containing compound; (B) a compound having at least two mercapto groups per molecule; and (C) an oxidizing agent.

  提供了一种可治愈的组合物，可以轻松调节所制备的治愈物体的性质，可以制备出不会显着变色或软化表面上涂有精加工剂或涂层材料的治愈物体，并且具有内部区域高固化速率。可治愈组合物包含（A）一种聚合物，在分子末端具有至少一个巯基，该聚合物是由含有硫代羰基硫基的聚合物（a2）衍生而来，所述聚合物是通过在含有硫代羰基硫基化合物的存在下聚合含有丙烯酸酯为主要成分且含有50％或更多丙烯酸酯和少于50％与丙烯酸酯共聚的单体（a1）而制备的；（B）每个分子中至少有两个巯基的化合物；和（C）氧化剂。
• SHEET FOR SOLAR CELL, AND SOLAR CELL MODULE
  申请人：Miyashita Yo

  公开号：US20120097220A1

  公开（公告）日：2012-04-26

  Provided are a sheet for a solar cell of a monolayer construction or a multilayer construction based on a polyphenylene ether-based resin layer formed of a resin composition using a polyphenylene ether as a main component, which has excellent durability, excellent flame retardancy, excellent dimensional stability and high adhesiveness with a encapsulating resin layer or the like, and a solar cell module obtained by providing the sheet for a solar cell.

  提供的是一种基于聚苯乙醚为主要成分的树脂组成物形成的单层结构或多层结构的太阳能电池片的材料，该材料具有优异的耐久性、优异的阻燃性、优异的尺寸稳定性和高粘附性，能够与封装树脂层等紧密结合，以及通过提供该太阳能电池片材料获得的太阳能电池模块。
• POLYVINYL ACETAL COMPOSITION, LAMINATE, AND USE THEREOF
  申请人：Asanuma Yoshiaki

  公开号：US20120202070A1

  公开（公告）日：2012-08-09

  It is an object of the invention to provide a plasticized polyvinyl acetal composition that is suitably used for an intermediate film of a laminated glass and other applications, specifically, the polyvinyl acetal composition being characterized in that in cases when a layer that is composed of the polyvinyl acetal composition and another resin layer such as a resin layer of a polycarbonate, a poly(meth)acrylic acid ester, or a styrene thermoplastic elastomer are laminated, the plasticizer does not migrate from the polyvinyl acetal layer. The present invention relates to a polyvinyl acetal composition including 100 parts by mass of a polyvinyl acetal and 0.5 to 100 parts by mass of an ester plasticizer or ether plasticizer that is amorphous or has a melting point of 30° C. or less, and has a hydroxyl value of 15 to 450 mgKOH/g.

  本发明的目的是提供一种塑化的聚乙烯醇醛组合物，适用于夹层玻璃和其他应用的中间膜，具体而言，该聚乙烯醇醛组合物的特点在于，在由聚乙烯醇醛组合物和另一种树脂层（如聚碳酸酯、聚（甲基）丙烯酸酯或苯乙烯热塑性弹性体层的树脂层）组成的层层压合时，塑化剂不会从聚乙烯醇醛层中迁移。本发明涉及一种聚乙烯醇醛组合物，包括100份质量份的聚乙烯醇醛和0.5至100份质量份的酯类塑化剂或醚类塑化剂，其为非晶态或具有30°C或更低的熔点，并具有15至450mgKOH/g的羟值。