2,3-dimethyl-5-hydroxy-1,4,4a,10a-tetrahydro-9,10-anthraquinone | 122199-99-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 2,3-dimethyl-5-hydroxy-1,4,4a,10a-tetrahydro-9,10-anthraquinone
• 英文别名: (+/-)-5-hydroxy-2,3-dimethyl-(4arH,9acH)-1,4,4a,9a-tetrahydro-anthraquinone；5,9,10-Trihydroxy-2,3-dimethyl-1,4-dihydro-anthracen；2,3-Dimethyl-1,4-dihydro-anthracentriol-(5,9,10)；(+/-)-5-Hydroxy-2,3-dimethyl-(4arH,9acH)-1,4,4a,9a-tetrahydro-anthrachinon；(4aR,9aS)-5-hydroxy-2,3-dimethyl-1,4,4a,9a-tetrahydroanthracene-9,10-dione
• CAS: 122199-99-9
• 化学式: C₁₆H₁₆O₃
• 分子量: 256.301
• InChiKey: LULGOSNRNOJJFD-NWDGAFQWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  19
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  54.4
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2,3-dimethyl-5-hydroxy-1,4,4a,10a-tetrahydro-9,10-anthraquinone 、 alkaline earth salt of/the/ methylsulfuric acid 生成 1-hydroxy-6,7-dimethylanthracene-9,10-dione
  参考文献：
  名称：

  Mentally disordered parricide and stranger killers admitted to high-security care. 1: A descriptive comparison

  摘要：

  Parricide is an uncommon crime, so that many of the descriptive studies suffer from methodological shortcomings of small sample sizes and a non-representative ascertainment. We describe a consecutive series of mentally disordered offenders convicted of parricide who were admitted to high-security care and we compare their index characteristics with a group convicted of killing one or more strangers. The main findings were that the parricides were more likely to suffer from schizophrenia but less likely to have had a disrupted childhood and criminal history, as compared with those who had killed a stranger. Those in the parricide group had made a previous attack on their victim in 40% of cases. Overall, the study confirmed some of the differences that one might expect between these two groups of homicides, which had entirely different relationships to their victims.

  DOI：

  10.1080/09585180122057
• 作为产物：
  描述：

  5-羟基对萘醌 、 2,3-二甲基-1,3-丁二烯 反应 72.0h， 生成 2,3-dimethyl-5-hydroxy-1,4,4a,10a-tetrahydro-9,10-anthraquinone
  参考文献：
  名称：

  Desimoni, Giovanni; Faita, Giuseppe; Righetti, Pierpaolo, Journal of the Chemical Society. Perkin transactions II, 1989, p. 437 - 442

  摘要：

  DOI：