bis{bis(pentafluorophenyl)phosphino}methane | 913069-16-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis{bis(pentafluorophenyl)phosphino}methane
• 英文别名: bis(dipentafluorophenylphosphino)ethane；dfppm；Bis(2,3,4,5,6-pentafluorophenyl)phosphanylmethyl-bis(2,3,4,5,6-pentafluorophenyl)phosphane；bis(2,3,4,5,6-pentafluorophenyl)phosphanylmethyl-bis(2,3,4,5,6-pentafluorophenyl)phosphane
• CAS: 913069-16-6
• 化学式: C₂₅H₂F₂₀P₂
• 分子量: 744.206
• InChiKey: HHXYBDNPNJOADS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8
• 重原子数：
  47
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  20

反应信息

• 作为反应物：
  描述：

  dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer 、 bis{bis(pentafluorophenyl)phosphino}methane 以 苯 为溶剂， 以70%的产率得到[(η5,κP-C5Me4CH2C6F4-2-P(C6F5)CH2P(C6F5)2)RhCl2]
  参考文献：
  名称：

  Complexes of η5, κP-cyclopentadienyl-phosphine ligands by chelate-assisted dehydrofluorinative coupling; the coupling of bis{bis(pentafluorophenyl)phosphino}methane to η5-pentamethylcyclopentadienyl in a rhodium complex

  摘要：

  The reaction between [{(eta(5)-C5Me5)RhCl(mu-Cl)}(2)] and (C6F5)(2)PCH2P(C6F5)(2) in refluxing benzene yields the singly linked complex [{(eta(5),kappa P-C5Me4CH2C6F4-2-P(C6F5)CH2P(C6F5)(2))}RhCl2] in which only one phosphorus atom is coordinated to the rhodium. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2006.01.019

文献信息

• Synthesis of Piano Stool Complexes Employing the Pentafluorophenyl-Substituted Diphosphine (C₆F₅)₂PCH₂P(C₆F₅)₂ and the Effect of Phosphine Modifiers on Hydrogen Transfer Catalysis
  作者：Andrew C. Marr、Mark Nieuwenhuyzen、Ciara L. Pollock、Graham C. Saunders

  DOI：10.1021/om070089i

  日期：2007.5.1

  Ruthenium, rhodium, and iridium piano stool complexes of the pentafluorophenyl-substituted diphosphine (C6F5)2PCH2P(C6F5)2 (2) have been prepared and structurally characterized by single-crystal X-ray diffraction. The η5,κP-Cp−P tethered complex [(η5,κP-C5Me4CH2C6F4-2-P(C6F5)CH2P(C6F5)2}RhCl2] (9), in which only one phosphorus is coordinated to the rhodium, was prepared by thermolysis of a slurry

  五氟苯基取代的二膦（C 6 F 5）2 PCH 2 P（C 6 F 5）2（2）的钌，铑和铱钢琴凳配合物已经制备，并通过单晶X射线衍射对其结构进行了表征。的η 5，κ P -Cp-P系留物[（η 5，κ P -C 5我4 CH 2 C ^ 6 ˚F 4 -2-P（C 6 ˚F 5）CH 2 P（C 6 ˚F 5）2 } RhCl 2 ]（9），其中仅一种磷与铑配位，是通过热解[Cp * RhCl（μ-Cl）] 2和2的浆液制备的，并通过单晶进行结构表征X射线衍射。束缚发生通过的η分子内dehydrofluorinative耦合5 -五甲基配位体和κ P，κ P配位的2。在一个磷原子的束缚力解离时发生的几何变化。已经研究了将膦配体引入到钢琴凳子氢转移催化剂的配位球中的作用。发现氟化膦配合物的配合物以与主要催化剂相比有利的速率转移氢，特别是当膦和环戊二烯基官能团被束缚时。高度螯合η 5，κ P，κ大号-Cp-PP络合物[（η
• COMPOSITION AND POLYMER
  申请人：Asahi Kasei Kabushiki Kaisha

  公开号：EP2735581B1

  公开（公告）日：2021-07-14
• Composition and Polymer
  申请人：Nakamura Akitake

  公开号：US20140121293A1

  公开（公告）日：2014-05-01

  Disclosed is a composition comprising (A) at least one compound selected from the group consisting of an ether compound having two or more ether groups, a trivalent phosphorus compound, and a ketone compound, (B) a boron trihalide, and (C) an episulfide compound.
• US9334371B2
  申请人：——

  公开号：US9334371B2

  公开（公告）日：2016-05-10
• US9738757B2
  申请人：——

  公开号：US9738757B2

  公开（公告）日：2017-08-22