1,4-di-tert-butyl-2,5-bis-(2,3-epoxy-propoxy)-benzene | 64777-22-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,4-di-tert-butyl-2,5-bis-(2,3-epoxy-propoxy)-benzene
• 英文别名: 1,4-Di-tert-butyl-2,5-bis-(2,3-epoxy-propoxy)-benzol；2-[[2,5-Ditert-butyl-4-(oxiran-2-ylmethoxy)phenoxy]methyl]oxirane
• CAS: 64777-22-6
• 化学式: C₂₀H₃₀O₄
• 分子量: 334.456
• InChiKey: IMJWYODDPLPNHC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  24
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  43.5
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  环氧氯丙烷 、 alkaline earth salt of/the/ methylsulfuric acid 生成 1,4-di-tert-butyl-2,5-bis-(2,3-epoxy-propoxy)-benzene
  参考文献：
  名称：

  Bis-glycidyl ethers of hindered dihydroxybenzenes and process for their manufacture

  摘要：

  公开号：

  US02739160A1

文献信息

• Epoxy resin composition
  申请人：TOTOKASEI Co., Ltd.

  公开号：EP0620238A2

  公开（公告）日：1994-10-19

  An epoxy resin composition comprising an epoxy resin component containing at least 5% by weight of an epoxy resin of Formula [I], an epoxy hardener, and an inorganic filler as essential constituents: [wherein R and R1 denote alkyl of C2 to C6, and n is an integer repetition unit from 0 to 10.]. The epoxy resin composition, when used as a molding material, is low in water absorption rate and flexural modulus (low stress).

  一种环氧树脂组合物，由环氧树脂组分、环氧固化剂和无机填料组成，其中环氧树脂组分的主要成分是至少 5%（按重量计）的式[I]环氧树脂、环氧固化剂和无机填料： [其中 R 和 R1 表示 C2 至 C6 的烷基，n 是 0 至 10 的整数重复单位]。环氧树脂组合物用作成型材料时，吸水率和弯曲模量（低应力）都很低。
• Thermosetting epoxy powder coatings having improved degassing properties
  申请人：MORTON INTERNATIONAL, INC.

  公开号：EP1050564A2

  公开（公告）日：2000-11-08

  Provided are low temperature curing thermosetting epoxy powder coating compositions comprising at least one non-crystalline epoxy resin, at least one crystalline epoxy resin, a curing agent, and a cure catalyst. Coatings made from such powder compositions exhibit a substantial reduction in bubble entrapment, enough to prevent a visible haze from forming in the coating, when cured at low temperatures demanded by brass substrates, while the powders from which the coatings are made still exhibit good storage stability and melt-processability.

  本文提供的低温固化热固性环氧粉末涂料组合物包含至少一种非结晶环氧树脂、至少一种结晶环氧树脂、固化剂和固化催化剂。用这种粉末组合物制成的涂料在黄铜基材所需的低温下固化时，气泡夹带量大大减少，足以防止在涂层中形成可见的雾度，同时制成涂料的粉末仍具有良好的贮存稳定性和熔融加工性。
• METHOD OF CRYSTALLIZING ORGANIC OLIGOMER, EPOXY RESIN COMPOSITION CONTAINING ORGANIC OLIGOMER OBTAINED BY THE METHOD AND EPOXY RESIN CURED MATERIAL
  申请人：Tohto Kasei Co., Ltd.

  公开号：EP1640048A1

  公开（公告）日：2006-03-29

  For the purpose to provide a method to crystallize organic oligomer of low crystallizing speed without using a specific apparatus and without wasting huge energy, and to provide epoxy resin composition suited as the sealing material for semi-conductor containing the organic oligomer obtained by said method following method is found out. That is, the method for crystallization of organic oligomers comprising, after fluidizing powdered or granulated seed crystals of organic oligomer in an apparatus with powder stirring mechanism, pouring liquid of same crystallizable organic oligomer continuously or by batch into said apparatus so that to mix and disperse, then growing up crystals of the organic oligomer in said apparatus.

  为了提供一种结晶速度较低的有机低聚物的结晶方法，而不使用特定的设备，也不浪费巨大的能量，并提供适合作为含有通过所述方法获得的有机低聚物的半导体的密封材料的环氧树脂组合物，发现了以下方法。即，有机低聚物的结晶方法包括：将粉末状或颗粒状的有机低聚物籽晶在带有粉末搅拌机构的设备中流化后，将相同的可结晶有机低聚物的液体连续或分批倒入所述设备中，使其混合并分散，然后在所述设备中长出有机低聚物的晶体。
• METHOD FOR PRODUCING FIBER-REINFORCED THERMALLY MOLTEN EPOXY RESIN
  申请人：Nagase ChemteX Corporation

  公开号：EP1882714A1

  公开（公告）日：2008-01-30

  Disclosed herein are a method for producing a fiber-reinforced thermally meltable epoxy resin having excellent heat resistance using a thermally meltable epoxy resin having a high melting initiation temperature and a fiber-reinforced plastic molded by the method. The method for producing a fiber-reinforced thermally meltable epoxy resin comprises the steps of: (I) impregnating reinforcing fibers with a compound (A) having two epoxy groups in one molecule and a compound (B) having two phenolic hydroxyl groups in one molecule; and (II) linearly polymerizing the compounds (A) and (B) impregnated into the reinforcing fibers by polyaddition reaction, wherein at least a part of the compound (A) and/or at least a part of the compound (B) are/is a compound having a fluorene skeleton, and the compound (A) and the compound (B) are mixed in such a ratio that the number of moles of epoxy groups in the compound (A) is 0.9 to 1.1 times the number of moles of phenolic hydroxyl groups in the compound (B).

  本发明公开了一种使用具有高熔融起始温度的热熔性环氧树脂生产具有优异耐热性的纤维增强热熔性环氧树脂的方法，以及用该方法模塑的纤维增强塑料。生产纤维增强热熔性环氧树脂的方法包括以下步骤：(I) 用一个分子中含有两个环氧基团的化合物（A）和一个分子中含有两个酚羟基的化合物（B）浸渍增强纤维；(II) 通过加成反应使浸渍在增强纤维中的化合物(A)和(B)线性聚合，其中至少一部分化合物(A)和/或至少一部分化合物(B)是/是具有芴骨架的化合物，化合物(A)和化合物(B)的混合比例为化合物(A)中环氧基团摩尔数的 0.9至1.1倍。
• PROCESS FOR PRODUCTION OF THERMOPLASTIC CURED EPOXY RESIN WITH TRANSPARENCY TO VISIBLE LIGHT, AND THERMOPLASTIC EPOXY RESIN COMPOSITION
  申请人：Nagase ChemteX Corporation

  公开号：EP2386587A1

  公开（公告）日：2011-11-16

  A process for the production of a thermoplastic cured epoxy resin which is transparent to visible light, characterized by curing (A) an epoxy compound having two epoxy groups in one molecule with (B) a compound having two phenolic hydroxyl groups in one molecule by means of (C) a cure accelerator consisting of at least one compound represented by general formula (1):         Rn-NHm (1) [wherein R is a monovalent C2-10 hydrocarbon group which may have a hydroxyl group at the β position to the nitrogen atom (with the proviso that when R has three or more carbon atoms, R includes both straight-chain and branched-chain hydrocarbon groups) ; when R has no hydroxyl group, R has a number of carbon atoms of 3 to 10; n is an integer of 1 to 3, and m is an integer of 2 to 0, with the sum of n and m being 3; and when multiple Rs are present, the Rs may be the same or different].

  一种生产对可见光透明的热塑性固化环氧树脂的工艺，其特征在于通过(C)一种至少由一种通式(1)代表的化合物组成的固化促进剂，将(A)一种一个分子中含有两个环氧基团的环氧化合物与(B)一种一个分子中含有两个酚羟基的化合物固化： Rn-NHm (1) [其中 R 为一价 C2-10 烃基，该烃基在氮原子的 β 位可带有羟基（但当 R 有三个或三个以上碳原子时，R 包括直链和支链烃基）；当 R 没有羟基时，R 的碳原子数为 3 至 10；n 为 1 至 3 的整数，m 为 2 至 0 的整数，n 和 m 之和为 3；当存在多个 R 时，R 可以相同或不同]。