1,3-bis[(7-nitro-2,3-dihydro-isoindol-1-one-2-yl)methyl]benzene | 1078159-20-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异吲哚及其衍生物
• 英文名称: 1,3-bis[(7-nitro-2,3-dihydro-isoindol-1-one-2-yl)methyl]benzene
• 英文别名: 7-nitro-2-[[3-[(4-nitro-3-oxo-1H-isoindol-2-yl)methyl]phenyl]methyl]-3H-isoindol-1-one
• CAS: 1078159-20-2
• 化学式: C₂₄H₁₈N₄O₆
• 分子量: 458.43
• InChiKey: UXZASPSWEOLXHE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  34
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  132
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  2-甲基-6-硝基苯甲酸 在 N-溴代丁二酰亚胺(NBS) 、 potassium carbonate 、 三乙胺 、 过氧化苯甲酰 作用下， 以 甲醇 、 四氯化碳 、 N,N-二甲基甲酰胺 为溶剂， 反应 45.0h， 生成 1,3-bis[(7-nitro-2,3-dihydro-isoindol-1-one-2-yl)methyl]benzene
  参考文献：
  名称：

  OXYGEN SCAVENGING MOLECULES, ARTICLES CONTAINING SAME, AND METHODS OF THEIR USE

  摘要：

  该发明涉及结构为公式I和II的化合物：其中X从O、S和NH组成的群体中选择；Y、A和B从N和CH组成的群体中独立选择；D、E和F从CH、N、O和S组成的群体中独立选择；符号代表单键或双键；R1、R2和R3从H、电子吸引基团和电子释放基团组成的群体中独立选择。在其他实施方式中，这些化合物被用作氧清除剂，以及在屏障组合物和制品中使用。

  公开号：

  US20110251395A1

文献信息

• Oxygen Scavenging Molecules, Articles Containing Same, And Methods Of Their Use
  申请人：Deshpande Girish Nilkanth

  公开号：US20080277622A1

  公开（公告）日：2008-11-13

  The invention relates to compounds of the structure of formula I and II: where X is selected from the group consisting of O, S and NH; Y, A and B are independently selected from the group consisting of N and CH; D, E and F are independently selected from the group consisting of CH, N, O and S; the symbol — represents a single or a double bond; and R 1 , R 2 and R 3 are independently selected from the group consisting of H, electron withdrawing groups and electron releasing groups. In other embodiments, the compounds are used as oxygen scavengers and in barrier compositions and articles.

  本发明涉及结构式I和II的化合物：其中X选自O，S和NH组成的群体；Y，A和B独立地选自N和CH组成的群体；D，E和F独立地选自CH，N，O和S组成的群体；符号—表示单键或双键；R1，R2和R3独立地选自H，电子提取基团和电子释放基团组成的群体。在其他实施例中，这些化合物被用作氧气清除剂和隔离物组成和物品。
• Oxygen scavenging molecules, articles containing same, and methods of their use
  申请人：Plastipak Packaging, Inc.

  公开号：US10125096B2

  公开（公告）日：2018-11-13

  The invention relates to compounds of the structure of formula I and II: where X is selected from the group consisting of O, S and NH; Y, A and B are independently selected from the group consisting of N and CH; D, E and F are independently selected from the group consisting of CH, N, O and S; the symbol - - - - represents a single or a double bond; and R1, R2 and R3 are independently selected from the group consisting of H, electron withdrawing groups and electron releasing groups. In other embodiments, the compounds are used as oxygen scavengers and in barrier compositions and articles.

  本发明涉及式 I 和 II 结构的化合物： 其中 X 选自 O、S 和 NH 组成的组；Y、A 和 B 独立地选自 N 和 CH 组成的组；D、E 和 F 独立地选自 CH、N、O 和 S 组成的组；符号 - - - - 代表单键或双键；以及 R1、R2 和 R3 独立地选自 H、取电子基团和释电子基团组成的组。在其他实施方案中，这些化合物可用作氧清除剂以及阻隔组合物和物品。
• Oxygen scavenging compositions, articles containing same, and methods of their use
  申请人：Plastipak Packaging, Inc.

  公开号：US11338983B2

  公开（公告）日：2022-05-24

  The disclosure relates to oxygen scavenging compositions, methods of making the compositions, articles prepared from the compositions, and methods of making the articles. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.

  本发明涉及氧清除组合物、组合物的制造方法、由组合物制备的物品以及物品的制造方法。本摘要旨在作为在特定技术领域进行搜索的扫描工具，并非对本发明的限制。
• Oxygen Scavenging Compositions, Articles Containing Same, and Methods of Their Use
  申请人：Constar International, Inc.

  公开号：US20130285277A1

  公开（公告）日：2013-10-31

  The disclosure relates to transition metal compositions, methods of making the compositions, articles prepared from the compositions, and methods of making the articles. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.
• Oxygen Scavenging Molecules, Articles Containing Same, and Methods of Their Use
  申请人：Plastipak Packaging, Inc.

  公开号：US20170088332A1

  公开（公告）日：2017-03-30

  The invention relates to compounds of the structure of formula I and II: where X is selected from the group consisting of O, S and NH; Y, A and B are independently selected from the group consisting of N and CH; D, E and F are independently selected from the group consisting of CH, N, O and S; the symbol ---- represents a single or a double bond; and R 1 , R 2 and R 3 are independently selected from the group consisting of H, electron withdrawing groups and electron releasing groups. In other embodiments, the compounds are used as oxygen scavengers and in barrier compositions and articles.