苯甲酸,混合物和2,2',2''-次氮基三乙醇(1:1) | 13090-86-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 苯甲酸,混合物和2,2',2''-次氮基三乙醇(1:1)
• 英文名称: benzoic acid triethanolammonium salt
• 英文别名: Triethanolamine benzoate；benzoic acid;2-[bis(2-hydroxyethyl)amino]ethanol
• CAS: 13090-86-3
• 化学式: C₆H₁₅NO₃*C₇H₆O₂
• 分子量: 271.313
• InChiKey: LBCOWMYTAXJNER-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -3.1
• 重原子数：
  19
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  105
• 氢给体数：
  4
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  三乙醇胺 、 苯甲酸 以 甲醇 为溶剂， 反应 1.0h， 以94%的产率得到苯甲酸,混合物和2,2',2''-次氮基三乙醇(1:1)
  参考文献：
  名称：

  生物活性羧酸的三乙醇铵盐

  摘要：

  合成的生物活性羧酸（烟酸，肉桂酸，苯甲酸，水杨酸，草酸，丙二酸，琥珀酸，苹果酸，柠檬酸）的三乙醇铵盐（protatranes）的收率超过90％。通过红外光谱和X射线衍射分析研究了合成化合物的结构。

  DOI：

  10.1134/s1070363215120075

文献信息

• Repurposing cycloaddition of β-carbonyl phosphonate and azide to synthesize triazolyl phosphonates <i>via</i> ionic-liquid-based data-driven screening
  作者：Anlian Zhu、Dongshuang Fan、Yanbo You、Honglei Wang、Yang Zhao、Jianji Wang、Lingjun Li

  DOI：10.1039/d2gc02461f

  日期：——

  liquids for discovering new reactivity, developing potent synthetic reactions, and even simplifying bioactivity evaluations. Using ILDDS, we repurposed the cycloaddition of β-carbonyl phosphonate and azide to synthesize triazolyl phosphonates that usually produced phosphonate-leaving products under the traditional conditions. And then, the repurposed cycloaddition reaction allows the access of triazolyl

  膦酸是一类广泛存在于天然产物和人工合成的功能分子中的重要结构单元。Nature 使用 β-羰基膦酸作为通用结构单元来获取结构多样的膦酸衍生物，这为化学家提供了一种仿生方法，但是，它受到化学反应过程中 C-P 键断裂的不利趋势的限制。为了应对这一挑战，我们在此开发了一种基于离子液体的数据驱动筛选 (ILDDS)，该方法可以综合利用离子液体的多功能效应来发现新的反应性、开发有效的合成反应，甚至简化生物活性评估。使用 ILDDS，我们重新利用 β-羰基膦酸酯和叠氮化物的环加成来合成三唑基膦酸酯，在传统条件下通常会产生膦酸酯离去产物。然后，重新利用的环加成反应允许在温和条件下使用带有各种取代基的三唑基膦酸酯。此外，一个集成的工作流程结合了模块化和组合合成、简单的纯化和原位生物活性评估可以从头设计并以高通量方式实施，最终导致快速获得膦酸盐化合物以抑制立枯丝核菌的生长。
• Ink, and ink-jet recording method and instrument using the same
  申请人：CANON KABUSHIKI KAISHA

  公开号：EP0648821A2

  公开（公告）日：1995-04-19

  Disclosed herein is an ink comprising a coloring material and a liquid medium dissolving or dispersing the coloring material therein, wherein the ink contains in combination a compound of the general formula wherein R₁ denotes hydrogen, a nitro group or an amino group, and R₂ denotes a carboxyl group, a sulfonic group, a phosphoric group or a salt thereof, and at least one compound selected from the group consisting of primary to tertiary amines, derivatives thereof, and complexes thereof.

  本文公开了一种油墨，它由着色材料和溶解或分散着色材料的液体介质组成，其中油墨含有通式为 其中 R₁ 表示氢、硝基或氨基，R₂ 表示羧基、磺酸基、磷酸基或其盐，以及至少一种选自由伯胺到叔胺、其衍生物和其络合物组成的组的化合物。
• Production process of cross-linked polyaspartic acid resin
  申请人：MITSUI CHEMICALS, INC.

  公开号：EP0866084A2

  公开（公告）日：1998-09-23

  A process is disclosed for producing with good productivity a cross-linked polyaspartic acid resin having biodegradability and high water absorbency. The process features inclusion of one of the following steps: (a) a polysuccinimide, which has been brought into a dispersed state by a dispersant, and a cross-linking agent are reacted to produce the cross-linked polyaspartic acid resin; (b) imide rings of a cross-linked polysuccinimide are subjected to a hydrolysis reaction while controlling a swelling degree of a resulting gel, whereby the cross-linked polyaspartic acid resin is produced; and (c) a gel of a cross-linked polysuccinimide, which has been obtained by reacting a cross-linking agent to a solution of a polysuccinimide in an organic solvent, is disintegrated to subject imide rings of the cross-linked polysuccinimide to a hydrolysis reaction, so that the cross-linked polyaspartic acid resin is produced. The process may also include one or both of the following steps as needed: (d) a gel of the cross-linked polyaspartic acid resin is washed with water and/or a water-miscible organic solvent; and (e) the polysuccinimide is produced using a basic amino acid as a cross-linking agent.

  本发明公开了一种工艺，用于生产具有生物降解性和高吸水性的交联聚天冬氨酸树脂，生产效率高。该工艺的特点是包含以下步骤之一：(a) 通过分散剂使聚琥珀酰亚胺进入分散状态，并与交联剂反应，生成交联聚天冬氨酸树脂；(b) 将交联聚琥珀酰亚胺的酰亚胺环进行水解反应，同时控制所得凝胶的溶胀度，从而生成交联聚天冬氨酸树脂；(c) 将交联剂与聚琥珀酰亚胺在有机溶剂中的溶液反应而得到的交联聚琥珀酰亚胺凝胶分解，使交联聚琥珀酰亚胺的酰亚胺环发生水解反应，从而制得交联聚天冬氨酸树脂。根据需要，该工艺还可包括以下一个或两个步骤：(d) 用水和/或水混溶有机溶剂洗涤交联聚天冬氨酸树脂的凝胶；(e) 使用碱性氨基酸作为交联剂生产聚琥珀酰亚胺。
• Micro-granulose particulates
  申请人：——

  公开号：US20030089281A1

  公开（公告）日：2003-05-15

  Substantially hydrated cementitious particulates useful for delivering admixtures and additives into adhesives, coatings, paints, and other matrix compositions such as cement, concrete, masonry, mortar, fireproofing, shotcrete, and others. Preferred embodiments include intermixing at least one admixture, water, and hydratable cementitious binder to provide a substantially hydrated hardened mass and comminuting the hardened mass into particulates. Alternatively, or in addition, one or more admixtures may be coated onto the external surface area of the particulates, which are microscopically granulosic, to provide accurate and high level loading.

  基本水化的水泥基微粒可用于将外加剂和添加剂输送到粘合剂、涂料、油漆和其他基质组合物（如水泥、混凝土、砖石、砂浆、防火材料、喷射混凝土等）中。优选的实施方案包括将至少一种外加剂、水和可水化的水泥基粘结剂混合在一起，以提供基本水化的硬化块，并将硬化块粉碎成颗粒。另外，也可以将一种或多种外加剂涂覆在微粒的外表面区域（微观上呈颗粒状），以提供精确的高水平装载。
• Composition for film formation, method of film formation, and silica-based film
  申请人：JSR CORPORATION

  公开号：US20030091838A1

  公开（公告）日：2003-05-15

  A composition for film formation which comprises: (A) a product of hydrolysis and condensation obtained by hydrolyzing and condensing at least one silane compound selected from the group consisting of compounds represented by the formula (1), compounds represented by the formula (2), and compounds represented by the formula (3) in the presence of water and an ammonium compound, and (B) an organic solvent.

  一种用于成膜的组合物，它包括 (A) 至少一种硅烷化合物的水解和缩合产物，该硅烷化合物选自由式（1）、式（2）和式（3）所代表的化合物组成的组，在水和铵化合物存在下水解和缩合得到，以及 (B) 有机溶剂。