N'-[1,2-Dimethyl-prop-(E)-ylidene]-N-methyl-N-pyridin-2-yl-hydrazine | 72076-48-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: N'-[1,2-Dimethyl-prop-(E)-ylidene]-N-methyl-N-pyridin-2-yl-hydrazine
• 英文别名: 2-Butanone, 3-methyl-, methyl-2-pyridinylhydrazone；N-methyl-N-[(E)-3-methylbutan-2-ylideneamino]pyridin-2-amine
• CAS: 72076-48-3
• 化学式: C₁₁H₁₇N₃
• 分子量: 191.276
• InChiKey: BUXOJTOEXKTTDF-JLHYYAGUSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  28.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  N'-[1,2-Dimethyl-prop-(E)-ylidene]-N-methyl-N-pyridin-2-yl-hydrazine 生成 2,3-二氢-1,3,3-三甲基-2-亚甲基-1H-吡咯并[2,3-b]吡啶
  参考文献：
  名称：

  Red Colouring Photochromic 6′-Substituted Spiroindolinon Aphth[2,1-b][1,4]Oxazines

  摘要：

  Electron donating/withdrawing substituents and electronegative centres have been successfully employed in substantially widening the range of photo-generated colours available in the spiroindolinonaphthoxazine class of photochromic materials.

  DOI：

  10.1080/10587259408037780
• 作为产物：
  描述：

  2-氯吡啶 以 甲苯 为溶剂， 生成 N'-[1,2-Dimethyl-prop-(E)-ylidene]-N-methyl-N-pyridin-2-yl-hydrazine
  参考文献：
  名称：

  Red Colouring Photochromic 6′-Substituted Spiroindolinon Aphth[2,1-b][1,4]Oxazines

  摘要：

  Electron donating/withdrawing substituents and electronegative centres have been successfully employed in substantially widening the range of photo-generated colours available in the spiroindolinonaphthoxazine class of photochromic materials.

  DOI：

  10.1080/10587259408037780

文献信息

• Red Colouring Photochromic 6′-Substituted Spiroindolinon Aphth[2,1-b][1,4]Oxazines
  作者：M. Rickwood、S. D. Marsden、M. E Ormsby、A. L. Staunton、D. W. Wood、J. D. Hepworth、C. D. Gabbutt

  DOI：10.1080/10587259408037780

  日期：1994.5

  Electron donating/withdrawing substituents and electronegative centres have been successfully employed in substantially widening the range of photo-generated colours available in the spiroindolinonaphthoxazine class of photochromic materials.