S-phenyl-O-i-propyl thiolcarbonate | 17659-14-2

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: S-phenyl-O-i-propyl thiolcarbonate
• 英文别名: S-Phenyl-O-isopropyl-thiolcarbonat；O-Isopropyl-S-phenyl-thiolcarbonat；Propan-2-yl phenylsulfanylformate；propan-2-yl phenylsulfanylformate
• CAS: 17659-14-2
• 化学式: C₁₀H₁₂O₂S
• 分子量: 196.27
• InChiKey: RNVBSSCFWFJDAR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  异丙醇 、 硫代氯甲酸苯酯 在 potassium carbonate 作用下， 生成 S-phenyl-O-i-propyl thiolcarbonate
  参考文献：
  名称：

  Base-catalyzed conversion of thiolcarbonate esters into sulfides. Reactions of xanthate esters

  摘要：

  DOI：

  10.1021/jo01275a070

文献信息

• Convenient Route to Thiocarbonates from Alcohols, Thiols, and Triphosgene
  作者：Barahman Movassagh、Mohammad Soleiman-Beigi

  DOI：10.1080/00397910903457258

  日期：2010.11.3

  An efficient and simple one-pot, three-component procedure has been introduced for the preparation of various thiocarbonates from thiols, alcohols, and triphosgene in dichloromethane.

  介绍了一种有效且简单的一锅三组分程序，用于在二氯甲烷中从硫醇、醇和三光气制备各种硫代碳酸酯。
• A new method for synthesis of S-aryl-O-alkyl thiolcarbonates: selenium-catalyzed reaction of alcohols with carbon monoxide and diaryl disulfides
  作者：Yutaka Nishiyama、Ken Maehira、Junko Nakase、Noboru Sonoda

  DOI：10.1016/j.tetlet.2005.08.108

  日期：2005.10

  A unique catalytic ability of selenium has been developed. When alcohols were allowed to react with diaryl disulfides in the presence of a catalytic amount of selenium under a pressurized carbon monoxide, S-aryl-O-alkyl thiolcarbonates were obtained in moderate to good yields.

  已经开发出硒独特的催化能力。当在加压的一氧化碳下，在催化量的硒的存在下使醇与二芳基二硫化物反应时，以中等至良好的产率获得了S-芳基-O-烷基硫代碳酸酯。
• 461. Cytotoxic compounds. Part III. Some derivatives of p-(NN-di-2-chloroethyl- and of p,-(NN-di-2-bromoethyl-amino)thiophenol
  作者：A. M. Creighton、L. N. Owen、G. R. White

  DOI：10.1039/jr9610002375

  日期：——
• Compounds to Identify Beta-Lactamases, and Methods of Use Thereof
  申请人：The Regents of the University of California

  公开号：US20220177947A1

  公开（公告）日：2022-06-09

  Provided herein are β-lactamase probes that can be used to identify specific types and classes of β-lactamases in a sample, and methods of use thereof.
• Base-catalyzed conversion of thiolcarbonate esters into sulfides. Reactions of xanthate esters
  作者：Frank Norton Jones

  DOI：10.1021/jo01275a070

  日期：1968.11