chlorophosphoric acid bis-(3,5-dimethyl-phenyl ester) | 58377-73-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: chlorophosphoric acid bis-(3,5-dimethyl-phenyl ester)
• 英文别名: Chlorophosphorsaeure-bis-(3,5-dimethyl-phenylester)；bis(3,5-dimethylphenyl) chlorophosphate；Bis(3,5-dimethylphenyl) phosphorochloridate；1-[chloro-(3,5-dimethylphenoxy)phosphoryl]oxy-3,5-dimethylbenzene
• CAS: 58377-73-4
• 化学式: C₁₆H₁₈ClO₃P
• 分子量: 324.744
• InChiKey: VYHGCXOQLBEEJN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  chlorophosphoric acid bis-(3,5-dimethyl-phenyl ester) 、 水 生成 Bis(3,5-dimethylphenyl) hydrogen phosphate
  参考文献：
  名称：

  MAKARENKO I. M.; AKSENOVA T. F., SVERDL. IN-T HAP. X-BA. SVERDLOVSK, 1975. 6 S., BIBLIOGR. 12 NAZV. (RUKOP+

  摘要：

  DOI：
• 作为产物：
  描述：

  2,5-二甲基苯酚 、 三氯氧磷 生成 chlorophosphoric acid bis-(3,5-dimethyl-phenyl ester)
  参考文献：
  名称：

  MAKARENKO I. M.; AKSENOVA T. F., SVERDL. IN-T HAP. X-BA. SVERDLOVSK, 1975. 6 S., BIBLIOGR. 12 NAZV. (RUKOP+

  摘要：

  DOI：

文献信息

• Flame retardant, additive compositions, and flame retardant polyurethanes
  申请人：Hussain Saadat

  公开号：US20050113495A1

  公开（公告）日：2005-05-26

  Provided are new flame retardants and liquid flame retardant additive compositions of low viscosity for use in flexible polyurethane foams. The new flame retardants are the reaction product of at least one brominated aromatic diester diol with at least one alcohol-reactive agent. Preferred liquid flame retardant additive compositions are capable of minimizing visible scorching of the foam during its production. Flexible flame retardant polyurethane foams and methods for their production are also provided. The flame retardant additive compositions are formed at least from a) at least one reaction product of a brominated aromatic diester diol and an alcohol-reactive agent; b) at least one hindered amine antioxidant; and c) at least one phenolic antioxidant in which the phenolic ring is substituted by an alkanoic acid alkyl ester group in which alkanoic acid moiety has in the range of 2 to about 4 carbon atoms and the alkyl group has in the range of about 6 to about 16 carbon atoms.

  本文提供了用于软质聚氨酯泡沫的新型阻燃剂和低粘度液体阻燃添加剂组合物。新型阻燃剂是至少一种溴化芳香族二酯二醇与至少一种醇反应剂的反应产物。优选的液态阻燃添加剂组合物能够在泡沫生产过程中最大限度地减少可见的焦烧现象。此外，还提供了柔性阻燃聚氨酯泡沫及其生产方法。阻燃添加剂组合物至少由以下物质形成：a) 至少一种溴化芳香族二酯二元醇与醇反应剂的反应产物；b) 至少一种受阻胺抗氧化剂；c) 至少一种酚类抗氧化剂，其中酚环被烷酸烷基酯基团取代，烷酸分子的碳原子数在 2 至约 4 之间，烷基的碳原子数在约 6 至约 16 之间。
• Benzoylresorcinol-based phosphate ester compounds as flame retardants
  申请人：Durairaj B. Raj

  公开号：US20060063865A1

  公开（公告）日：2006-03-23

  Benzoylresorcinol-based phosphate esters are obtained by reacting a benzoylresorcinol compound with a chlorophosphate. The benzoylresorcinol-based phosphate esters can function as flame retardants and/or UV stabilizers for polycarbonates (PC), poly(phenylene oxide) (PPO), polyesters (e.g., PET and PBT), polycarbonate and acrylonitrile-butadiene-styrene terpolymer (PC/ABS) blends, poly(phenylene oxide) and high-impact polystyrene (PPO/HIPS) blends and other polymers. The benzoylresorcinol-based phosphate ester flame retardants may possess enhanced thermal stability compared to resorcinol based phosphate ester (RDP). Synthetic procedures and applications of the benzoylresorcinol-based phosphate esters compounds are provided.

  苯甲酰间苯二酚基磷酸酯是通过苯甲酰间苯二酚化合物与氯磷酸酯反应而得到的。苯甲酰间苯二酚基磷酸酯可作为阻燃剂和/或紫外线稳定剂，用于聚碳酸酯（PC）、聚环氧苯烯烃（PPO）、聚酯（如 PET 和 PBT）、聚碳酸酯和丙烯腈-丁二烯-苯乙烯三元共聚物（PC/ABS）混合物、聚环氧苯烯烃和高抗冲聚苯乙烯（PPO/HIPS）混合物以及其他聚合物。与间苯二酚基磷酸酯（RDP）相比，苯甲酰基间苯二酚基磷酸酯阻燃剂可能具有更高的热稳定性。本文还介绍了苯甲酰基间苯二酚基磷酸酯化合物的合成过程和应用。
• FLAME RETARDANT, ADDITIVE COMPOSITIONS, AND FLAME RETARDANT POLYURETHANES
  申请人：ALBEMARLE CORPORATION

  公开号：EP1685176A2

  公开（公告）日：2006-08-02
• PHOSPHATE ESTER FLAME RETRADANTS FROM RESORCINOL-KETONE REACTION PRODUCTS
  申请人：INDSPEC CHEMICAL CORPORATION

  公开号：EP1797055A2

  公开（公告）日：2007-06-20
• Resorcinol carbonate-based phosphate ester compounds as flame retardants
  申请人：Durairaj B. Raj

  公开号：US20060063866A1

  公开（公告）日：2006-03-23

  Resorcinol carbonate-based phosphate esters are prepared by reacting resorcinol carbonates with phosphorous oxychloride or a chlorophosphate. The resorcinol carbonates can be synthesized by the reaction of resorcinol with phosgene or diphenyl carbonate. The resorcinol carbonate-based phosphate esters can be used as flame retardants and perhaps flowing agents.