1-dodecyl-1,1-dimethylhydrazonium chloride | 3291-13-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1-dodecyl-1,1-dimethylhydrazonium chloride
• 英文别名: 1,1-dimethyl-1-dodecylhydrazinium chloride；Hydrazinium, 1-dodecyl-1,1-dimethyl-, chloride；amino-dodecyl-dimethylazanium;chloride
• CAS: 3291-13-2
• 化学式: C₁₄H₃₃N₂*Cl
• 分子量: 264.882
• InChiKey: WFVSHGAJUZDRBJ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.86
• 重原子数：
  17
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  偏二甲肼 、 1-氯十二烷 反应 11.0h， 以94%的产率得到1-dodecyl-1,1-dimethylhydrazonium chloride
  参考文献：
  名称：

  摘要：

  Onium salts QZ (Z = Cl, Br) having a lipophilic (Q = R3NR', where R' = C16H33) or readily extractable (into organic phase) cation (Q = Ph4P) exhibit a high catalytic activity in phase-transfer alkaline hydrolysis of N-benzyloxycarbonylglycine 4-nitraphenyl ester in the two-phase system chloroform-borate buffer (pH 10). No catalytic effect is observed in the presence of hydrophilic ammonium salts [Et4NCl, Et3PhCH2NCl, Me-2(NH2)NCH2CH2N(NH2)Me(2)(.)2Br(-)] and those insoluble in organic solvents [(Me)(3)NNH(CH2)(2)COO- (.) 2H(2)O, Me-2(NH2)NCH2CO-, Me-2(NH2)N(CH2)(3)SO3-]. These data suggest extraction mechanism of the process. The activity of lipophilic cation Q is determined mainly by two factors: its extractibility, on the one hand, and the ability to form micelles, on the other.

  DOI：

  10.1023/a:1016334125761

文献信息

• ——
  作者：O. V. Baranova、V. V. Kosmynin、V. A. Savelova、A. N. Shendrik、N. I. Korotkikh、G. F. Raenko、A. F. Popov

  DOI：10.1023/a:1016334125761

  日期：——

  Onium salts QZ (Z = Cl, Br) having a lipophilic (Q = R3NR', where R' = C16H33) or readily extractable (into organic phase) cation (Q = Ph4P) exhibit a high catalytic activity in phase-transfer alkaline hydrolysis of N-benzyloxycarbonylglycine 4-nitraphenyl ester in the two-phase system chloroform-borate buffer (pH 10). No catalytic effect is observed in the presence of hydrophilic ammonium salts [Et4NCl, Et3PhCH2NCl, Me-2(NH2)NCH2CH2N(NH2)Me(2)(.)2Br(-)] and those insoluble in organic solvents [(Me)(3)NNH(CH2)(2)COO- (.) 2H(2)O, Me-2(NH2)NCH2CO-, Me-2(NH2)N(CH2)(3)SO3-]. These data suggest extraction mechanism of the process. The activity of lipophilic cation Q is determined mainly by two factors: its extractibility, on the one hand, and the ability to form micelles, on the other.
• Drozdetskii; Drozdova; Koval'chuk, Russian Journal of Applied Chemistry, 1999, vol. 72, # 12, p. 2101 - 2102
  作者：Drozdetskii、Drozdova、Koval'chuk、Tsvinger

  DOI：——

  日期：——
• Surface-active properties of a series of 1,1-dimethyl-1-alkylhydrazinium chlorides
  作者：M. G. Shcherban’、T. Yu. Nasretdinova、N. A. Kladova、A. V. Radushev、E. V. Burdakova

  DOI：10.1134/s1070427207030159

  日期：2007.3

  The surface-active properties of a series of 1,1-dimethyl-1-alkylhydrazinium chlorides with C-10-C-18 in length were studied in comparison with Neonol AF 9-12 and Oksifos B surfactants. The limiting wetting angle, detergent and solubilization power, and foaming kinetics of these surfactants were studied in relation to the concentration of formation of monomolecular layer and type of the resulting micellar structures.