申请人:NIPPON SHOKUBAI CO., LTD.
公开号:EP0368563A2
公开(公告)日:1990-05-16
This invention provides drilling fluid additives composed of copolymers which are obtainable by an industrially favorable process and superior in heat-resisting property. Furthermore, even though the additives are used in a relatively small amount, those sufficiently prevent change in properties of drilling fluid due to various kinds of hard water components being contained in underground water or cement as well as due to sea water, and the additives are able to display the properties of drilling fluid constantly regardless of presence or absence of salts.
Drilling fluid additives of the present invention are composed of water-soluble copolymer ( A ) having average molecular weight of 1,000 - 50,000, which are led from monomer components composed of a monomer ( I ) of 40 - 99.5 molar percentages in a series of unsaturated carboxylic acids, as shown in the following general formula ( I ), and an unsaturated monomer ( II ) of 0.5 - 60 molar percentages in a series of ( meth )allylethers, as shown in the general formula ( II ).
In the formula ( I ), each of A1 and A2 independently represents hydrogen, methyl, or -COOX2, and A1 and A2 are not -COOX2 at the same time. A3 represents hydrogen, methyl, or -CH2COOX3 and, in a case that A3 is -CH2COOX3, each of A1 and A2 independently represents hydrogen or methyl. Each of X1, X2, and X3, independently or at the same time represents hydrogen, monovalent metal, divalent metal, ammonium, or organic amine.
In the formula ( II ) R1 represents hydrogen or methyl , and Z represents hydroxyl; a sulfonic acid group or its monovalent metal salt, divalent metal salt, ammonium salt, and organic amine salt; a phosphoric ( or phosphorous ) acid group or its monovalent metal salt, divalent metal salt, ammonium salt, and organic amine salt.
本发明提供了由共聚物组成的钻井液添加剂,这些添加剂可以通过工业化的有利工艺获得,并且具有优异的耐热性能。此外,即使添加剂的用量较少,也足以防止由于地下水或水泥中含有的各种硬水成分以及海水而引起的钻井液性质的变化,而且无论是否含有盐分,添加剂都能持续显示钻井液的性质。
本发明的钻井液添加剂由平均分子量为 1,000 - 50,000 的水溶性共聚物( A )组成,这些共聚物是由单体组分组成的,其中单体( I )为摩尔百分比为 40 - 99.5 的不饱和羧酸系列,如以下通式( I )所示;不饱和单体( II )为摩尔百分比为 0.5 - 60 的甲基烯丙基醚系列,如通式( II )所示。
在式 ( I )中,A1 和 A2 各自独立地代表氢、甲基或-COOX2,且 A1 和 A2 不是同时代表-COOX2。A3 代表氢、甲基或-CH2COOX3,在 A3 为-CH2COOX3 的情况下,A1 和 A2 各自独立地代表氢或甲基。X1、X2 和 X3 各自独立地或同时代表氢、一价金属、二价金属、铵或有机胺。
在式(II)中,R1 代表氢或甲基,Z 代表羟基;磺酸基团或其一价金属盐、二价金属盐、铵盐和有机胺盐;磷酸(或磷)基团或其一价金属盐、二价金属盐、铵盐和有机胺盐。