1,4-bis(2-methacryloyloxyethylthio)xylylene | 112503-98-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,4-bis(2-methacryloyloxyethylthio)xylylene
• 英文别名: p-bis(beta-methacryloxyethylthio)xylylene；1,4-bis(methacryloyloxyethylthiomethyl)benzene；2-[[4-[2-(2-methylprop-2-enoyloxy)ethylsulfanylmethyl]phenyl]methylsulfanyl]ethyl 2-methylprop-2-enoate
• CAS: 112503-98-7
• 化学式: C₂₀H₂₆O₄S₂
• 分子量: 394.556
• InChiKey: OJRFWSBEXBWPTJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  26
• 可旋转键数：
  14
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  103
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  甲基丙烯酸酐 、 1,4-bis-[(2-hydroxy-ethylsulfanyl)-methyl]-benzene 在 三乙胺 、 碳酸氢钠 作用下， 以 二氯甲烷 、 水 为溶剂， 反应 48.5h， 以98%的产率得到1,4-bis(2-methacryloyloxyethylthio)xylylene
  参考文献：
  名称：

  WO2008/101806

  摘要：

  公开号：

文献信息

• High refractive index monomers, compositions and uses thereof
  申请人：Craciun Liliana

  公开号：US20080200582A1

  公开（公告）日：2008-08-21

  The invention relates to novel sulfur-containing (meth)acrylic monomers and compositions thereof characterized by a high refractive index, for optical and industrial applications. The invention also relates to a method for preparing high refractive index polymeric materials and more specifically to a method for formation of ultraviolet cast optical lenses and compositions thereof comprising the sulfur-containing (meth)acrylic monomers.

  本发明涉及一种新型含硫（甲基）丙烯酸单体及其组合物，其具有高折射率，适用于光学和工业应用。本发明还涉及一种制备高折射率聚合材料的方法，更具体地涉及一种形成紫外线铸造光学透镜的方法和组合物，其中包括含硫（甲基）丙烯酸单体。
• TRANSPARENT PLASTIC MATERIAL, OPTICAL ARTICLE MADE THEREFROM, AND PRODUCTION PROCESS
  申请人：SEIKO EPSON CORPORATION

  公开号：EP0716102A1

  公开（公告）日：1996-06-12

  A transparent plastic material which is free from color tone unevenness, does not cause deposition, can selectively absorb only the light with specified wavelengths, selectively intercepts or reduces dazzling light, and intercepts hazardous ultraviolet radiations. The material comprises a polymer produced by polymerizing at least one monomer in the presence of a polymerization initiator or catalyst and containing a complex compound represented by the general formula (I): A₂M(OH)(H₂O), wherein M represents Sc, Y, La, Pt, Nd, Pm, Sm, Gd, Dy, Ho, Er, Tm or Lu; and A represents a ligand having a fundamental structure represented by formula (a) and forming a chelate complex containing at least either an aryl group or a heterocyclic group.

  一种透明塑料材料，它没有色调不均匀现象，不会造成沉积，只能选择性地吸收特定波长的光，选择性地拦截或减少眩光，并能拦截有害的紫外线辐射。该材料包括一种聚合物，由至少一种单体在聚合引发剂或催化剂存在下聚合而成，并含有通式 (I) 所代表的复合物：A₂M(OH)(H₂O)，其中 M 代表 Sc、Y、La、Pt、Nd、Pm、Sm、Gd、Dy、Ho、Er、Tm 或 Lu；A 代表具有式(a)代表的基本结构并形成至少含有芳基或杂环基的螯合物的配体。
• Photochromic curable composition
  申请人：TOKUYAMA CORPORATION

  公开号：EP0940694A1

  公开（公告）日：1999-09-08

  The present invention relates to a photochromic curable composition suited for the production of a photochromic cured product having excellent optical properties such as a high refractive index and a large Abbe's number, having favorable photochromic properties such as a large color density, and having good fatigue resistance, and to a photochromic lens obtained by curing the photochromic curable composition. The photochromic curable composition is characterized by comprising 100 parts by weight of a polymerizable monomer containing at least 10% by weight of a sulfur-containing (meth)acrylate polymerizable monomer represented by the following general formula (1), wherein R1, R2 and R3 may be the same or different and are hydrogen atoms or methyl groups, and n is an integer of 1 to 10, and 0.001 to 10 parts by weight of a photochromic compound.

  本发明涉及一种光致变色可固化组合物，该组合物适用于生产光致变色固化产品，该产品具有优异的光学性能，例如高折射率和大阿贝数，具有良好的光致变色性能，例如大色密度，并且具有良好的抗疲劳性，本发明还涉及通过固化该光致变色可固化组合物而获得的光致变色透镜。光致变色可固化组合物的特征是包含 100 重量份的可聚合单体，其中含有至少 10% 重量份的含硫（甲基）丙烯酸酯可聚合单体，其代表通式如下(1)、 其中 R1、R2 和 R3 可以相同或不同，并且是氢原子或甲基，n 是 1 至 10 的整数、 和 0.001 至 10 重量份的光致变色化合物。
• RADIATION CURING RESIN COMPOSITION AND CURED PRODUCT THEREOF
  申请人：Mitsubishi Chemical Corporation

  公开号：EP1561765A1

  公开（公告）日：2005-08-10

  A radiation-curable resin composition comprising an inorganic component containing a silica particle composed of a hydrolyzate of an oligomer of an alkoxysilane and a monomer and/or an oligomer thereof, wherein viscosity at 25°C is from 1,000 to 10,000 centipoises.

  一种辐射固化树脂组合物，其中包含一种无机成分，该无机成分含有由烷氧基硅烷的低聚物及其单体和/或低聚物的水解物组成的二氧化硅颗粒，25°C 时的粘度为 1,000 至 10,000 厘泊。
• Bis(4-mercaptophenyl)sulfide derivatives, process for the preparation thereof and electronic components
  申请人：——

  公开号：US20030189808A1

  公开（公告）日：2003-10-09

  The present invention provides a bis(4-mercaptophenyl) sulfide derivative represented by general formula 1. This derivative is a monomer that can form a dielectric film suitable for an electronic component. The present invention further provides a method for producing this derivative and an electronic component having high characteristics under excellent humidity and high temperature. 1

  本发明提供了一种由通式 1 表示的双（4-巯基苯基）硫醚衍生物。该衍生物是一种可形成适用于电子元件的介电薄膜的单体。本发明进一步提供了一种生产这种衍生物的方法和一种在极高湿度和高温条件下具有高特性的电子元件。 1