3,3'-bis(p-aminophenoxy)diphenyl sulfone | 84668-26-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,3'-bis(p-aminophenoxy)diphenyl sulfone
• 英文别名: Bis(3-(4-aminophenoxy)phenyl)sulfone；4-[3-[3-(4-aminophenoxy)phenyl]sulfonylphenoxy]aniline
• CAS: 84668-26-8
• 化学式: C₂₄H₂₀N₂O₄S
• 分子量: 432.5
• InChiKey: VZZOONBAZHZSEB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  31
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  113
• 氢给体数：
  2
• 氢受体数：
  6

文献信息

• [EN] POLYMERS FOR USE IN ELECTRONIC DEVICES<br/>[FR] POLYMÈRES DESTINÉS À ÊTRE UTILISÉS DANS DES DISPOSITIFS ÉLECTRONIQUES
  申请人：DUPONT ELECTRONICS INC

  公开号：WO2020018617A1

  公开（公告）日：2020-01-23

  In Formula I: Qa is CRX, SiRx, GeRx, PRX, or N; Qb is CRy, SiRy, GeRy, PRy, or N; R1, R2, and R3 are the same or different at each occurrence and are F, CN, alkyl, fluoroalkyl, unsubstituted or substituted hydrocarbon aryl, unsubstituted or substituted heteroaryl, alkoxy, fluoroalkoxy, unsubstituted or substituted aryloxy, silyl, or siloxy, where adjacent R1 groups can be joined together to form a fused aromatic ring; Rx is H, F, CN, alkyl, fluoroalkyl, unsubstituted or substituted hydrocarbon aryl, unsubstituted or substituted heteroaryl, alkoxy, fluoroalkoxy, unsubstituted or substituted aryloxy, silyl, siloxy, or R6; Ry is H, F, CN, alkyl, fluoroalkyl, unsubstituted or substituted hydrocarbon aryl, unsubstituted or substituted heteroaryl, alkoxy, fluoroalkoxy, unsubstituted or substituted aryloxy, silyl, siloxy, or R7; R6 and R7 are the same or different and are NH2 ArNH2, or OArNH2; Ar is the same or different at each occurrence and is an unsubstituted or substituted C6-18 hydrocarbon aryl; m and n are the same or different and are an integer from 0-2, such that m + n < 2; x is an integer from 0-4; y and z are the same or different and are an integer from 0 to the maximum available.

  在公式I中：Qa是CRX，SiRx，GeRx，PRX或N；Qb是CRy，SiRy，GeRy，PRy或N；R1、R2和R3在每次出现时相同或不同，并且是F，CN，烷基，氟烷基，未取代或取代的碳氢基芳基，未取代或取代的杂环芳基，烷氧基，氟烷氧基，未取代或取代的芳氧基，硅烷基或硅氧基，其中相邻的R1基团可以结合在一起形成融合的芳香环；Rx是H，F，CN，烷基，氟烷基，未取代或取代的碳氢基芳基，未取代或取代的杂环芳基，烷氧基，氟烷氧基，未取代或取代的芳氧基，硅烷基，硅氧基或R6；Ry是H，F，CN，烷基，氟烷基，未取代或取代的碳氢基芳基，未取代或取代的杂环芳基，烷氧基，氟烷氧基，未取代或取代的芳氧基，硅烷基，硅氧基或R7；R6和R7相同或不同，并且是NH2 ArNH2或OArNH2；Ar在每次出现时相同或不同，并且是未取代或取代的C6-18碳氢基芳基；m和n相同或不同，并且是0-2的整数，使得m + n < 2；x是0-4的整数；y和z相同或不同，并且是0到最大可用的整数。
• Compound
  申请人：Rolic AG

  公开号：EP1070731A1

  公开（公告）日：2001-01-24

  The present invention provides a compound comprising a repeating unit of formula (I)    in which: Arepresents a nitrogen atom, a carbon atom, a group -CR1- or an aromatic or alicyclic group, wherein R1 represents a hydrogen atom or lower alkyl, Mrepresents a repeating monomer unit; n1 to n3each independently represent 0 or an integer having a value of from 1 to 3, with the proviso that 1 < n1 + n2 + n3 < 4; P1, P2, P3each independently represent a photoactive group; and B1 to B4each independently represent a residue of general formula II as well as photoactive polymers prepared from such compounds and the use of such compounds in the preparation of liquid crystal orientation layers and structured and unstructured electro-optical elements.

  本发明提供了一种化合物，其包含具有如下式（I）的重复单元：其中：A表示氮原子、碳原子、基团-CR1-或芳香族或脂环基团，其中R1表示氢原子或较低的烷基，M表示重复单体单位；n1至n3分别独立地表示0或取值为1至3的整数，但需满足1 < n1 + n2 + n3 < 4；P1、P2、P3分别独立地表示光活性基团；B1至B4分别独立地表示通式II的残基，以及从这些化合物制备的光活性聚合物以及这些化合物在液晶取向层和结构化和非结构化的电光元件制备中的使用。
• Asymmetric Diamine Compounds Containing Two Functional Groups and Polymers Therefrom
  申请人：KOREA ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGY

  公开号：US20150045481A1

  公开（公告）日：2015-02-12

  The present invention relates to a novel diamine compound, wherein two substituents R and R′ are introduced asymmetrically, and a polymer thereof. The polymer may have excellent solubility in the organic solvent and allows for easy processibility after imidization, thus giving proper film maintaining superior properties, such as thermal, mechanical, and optical properties for applications in electrical, electronic, or optical materials.

  本发明涉及一种新型二胺化合物，其中引入了两个不对称的取代基R和R'，以及其聚合物。该聚合物在有机溶剂中具有出色的溶解性，并在酰亚胺化后易于加工，从而形成具有优越热性能、机械性能和光学性能的适用于电气、电子或光学材料的适当薄膜。
• IMIDE-LINKED MALEIMIDE AND POLYMALEIMIDE COMPOUNDS
  申请人：Mizori Farhad G.

  公开号：US20110130485A1

  公开（公告）日：2011-06-02

  The invention is directed to maleimide thermosets incorporating imide-extended mono-, bis-, or polymaleimide compounds. These imide-extended maleimide compounds are prepared by the condensation of appropriate anhydrides with appropriate diamines to give amine terminated compounds. These compounds are then condensed with excess maleic anhydride to yield imide-extended maleimide compounds.

  这项发明涉及将咪唑烯烃热固性树脂与亚酰亚胺扩展的单、双或多咪唑烯烃化合物结合。这些亚酰亚胺扩展的咪唑烯烃化合物是通过适当的酐与适当的二胺进行缩合反应制备的，以得到末端带有胺基的化合物。然后，这些化合物与过量的马来酸酐缩合，得到亚酰亚胺扩展的咪唑烯烃化合物。
• SYNTHESIS AND POLYMERIZATION OF OLIGOMERIC ALIPHATIC-AROMATIC BASED PHTHALONITRILES
  申请人：The Government of the United States of America, as represented by the Secretary of the Navy

  公开号：US20160168326A1

  公开（公告）日：2016-06-16

  A phthalonitrile compound having the formula below. The value n is a positive integer. Each R has a hydrocarbon chain optionally having —O— or —SiR′ 2 —O—. Each R′ is an aliphatic group. Each Ar is an aromatic group with the proviso that Ar contains at least two aromatic rings when n is 1 and R is an alkylene group. A method of: reacting an excess of a dihydroxyaromatic compound with a dihalocompound to form an oligomer; and reacting the oligomer with 4-nitrophthalonitrile to form the phthalonitrile compound, where Ar is an aromatic group.

  具有以下公式的邻苯二腈化合物。值n为正整数。每个R具有一个烃链，可选地具有—O—或—SiR′2—O—。每个R′是一个脂肪族基团。每个Ar是一个芳香族基团，但当n为1且R为烷基基团时，Ar至少包含两个芳香环。一种方法：用过量的二羟基芳香化合物与二卤化合物反应形成寡聚体；然后将寡聚体与4-硝基邻苯二腈反应形成邻苯二腈化合物，其中Ar是一个芳香族基团。