(E)-1-mesitoxy-1-phenylpropene | 136667-20-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (E)-1-mesitoxy-1-phenylpropene
• 英文别名: 1,3,5-trimethyl-2-[(E)-1-phenylprop-1-enoxy]benzene
• CAS: 136667-20-4
• 化学式: C₁₈H₂₀O
• 分子量: 252.356
• InChiKey: UNMJWXZPTFFZLN-YAXRCOADSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  19
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1-phenyl-2-(2',4',6'-trimethylphenyl)propan-1-one 生成 (E)-1-mesitoxy-1-phenylpropene
  参考文献：
  名称：

  WAGNER, PETER J.;ZHOU, BOLI, J. AMER. CHEM. SOC., 110,(1988) N 2, 611-612

  摘要：

  DOI：

文献信息

• Effects of steric congestion on photochemistry: enol ether formation from .alpha.-mesityl ketones
  作者：Peter J. Wagner、Boli. Zhou

  DOI：10.1021/ja00210a057

  日期：1988.1

  Transposition photochimique de mesityl-2 aleanophenones en alkyl-3 dimethyl-4,6 phenyl-2 indanols-2 et en enol-ethers

  Transposition photochimique de mesityl-2 aleanophenones enalkyl-3 二甲基-4,6 phenyl-2 indanols-2 et en enol-ethers
• Wagner, Peter J.; Zhou, Boli; Hasegawa, Tadashi, Journal of the American Chemical Society, 1991, vol. 113, # 25, p. 9640 - 9654
  作者：Wagner, Peter J.、Zhou, Boli、Hasegawa, Tadashi、Ward, Donald L.

  DOI：——

  日期：——
• WAGNER, PETER J.;ZHOU, BOLI, J. AMER. CHEM. SOC., 110,(1988) N 2, 611-612
  作者：WAGNER, PETER J.、ZHOU, BOLI

  DOI：——

  日期：——
• [EN] ENANTIOSELECTIVE AMINATION AND ETHERIFICATION___________________<br/>[FR] AMINATION ET ETHERIFICATION ENANTIOSELECTIVE
  申请人：UNIV YALE

  公开号：WO2004024684A2

  公开（公告）日：2004-03-25

  The present invention is directed to a catalyst composition, comprising: (1) a catalyst precursor having the general structure MSXn wherein M is a transition metal selected from the group consisting of iridium, molybdenum, and tungsten; S is a coordinating ligand; X is a counterion; and n is an integer from 0 to 5; and (2) a phosphoramidite ligand having the structure wherein O-Cn-O is an aliphatic or aromatic diolate and wherein R1, R2, R3 and R4 are selected from the group consisting of substituted or unsubstituted aryl groups, substituted or unsubstituted heteroaryl groups, substituted or unsubstituted aliphatic groups, and combinations thereof, with the proviso that at least one of R1, R2, R3, or R4 must be a substituted or unsubstituted aryl or heteroaryl group. The present invention is also directed to activated catalysts made from the above catalyst composition, as well as methods of allylic amination and etherification using the above catalysts.