N,N,N',N'-tetrakis(4-aminophenyl)benzidine | 3547-23-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N,N',N'-tetrakis(4-aminophenyl)benzidine
• 英文别名: Tetrakis(p-aminophenyl)benzidine；4-N-[4-[4-(4-amino-N-(4-aminophenyl)anilino)phenyl]phenyl]-4-N-(4-aminophenyl)benzene-1,4-diamine
• CAS: 3547-23-7
• 化学式: C₃₆H₃₂N₆
• 分子量: 548.69
• InChiKey: YROIXLFLYRDCBC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  42
• 可旋转键数：
  7
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  111
• 氢给体数：
  4
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  N,N,N'N'-Tetrakis-benzidin 在 乙醇 、 palladium 10% on activated carbon 、 一水合肼 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以0.66 g的产率得到N,N,N',N'-tetrakis(4-aminophenyl)benzidine
  参考文献：
  名称：

  四胺长径比和灵活性决定 Zn8L6 自组装结构的框架对称性

  摘要：

  导出了金属有机胶囊组装的几何设计规则。具有T 、 T h 、 S 6和D 3对称性的Zn 8 L 6假立方体的优选非对映异构构型显示取决于其组成的矩形亚基的长宽比和构象灵活性。计算方法使进一步的设计原理得以破译。

  DOI：

  10.1002/anie.202217987

文献信息

• IR-ray absorptive amino compound and optical recording medium by use
  申请人：Canon Kabushiki Kaisha

  公开号：US05245030A1

  公开（公告）日：1993-09-14

  An IR-ray absorptive compound represented by the formula (1) or (2): ##STR1## and an optical recording medium having a substrate and an organic dye thin film, comprising the formulae (1) and/or (2).

  一种由公式（1）或（2）表示的红外吸收化合物：##STR1##和一种光学记录介质，包括基板和有机染料薄膜，其中包括公式（1）和/或（2）。
• IR-ray absorptive compound and optical recording medium by use thereof
  申请人：Canon Kabushiki Kaisha

  公开号：US05108873A1

  公开（公告）日：1992-04-28

  An IR-ray absorptive compound represented by the formula (1) or (2): ##STR1## and an optical recording medium having a substrate and an organic dye thin film, comprising the formulae (1) and/or (2).

  一种由公式（1）或（2）表示的红外线吸收化合物：##STR1##以及具有基板和有机染料薄膜的光记录介质，包括公式（1）和/或（2）。
• RESIN COMPOSITION, RESIN SHEET, CURED RESIN PRODUCT, RESIN SUBSTRATE, AND LAMINATE SUBSTRATE
  申请人：TDK CORPORATION

  公开号：US20200377647A1

  公开（公告）日：2020-12-03

  A resin composition including a main agent containing an epoxy compound, a curing agent, and inorganic particles, the curing agent includes an aromatic compound in which a ratio of the number of carbon atoms constituting an aromatic ring to a total number of carbon atoms in one molecule is 85% or more, a content of the inorganic particles is 40 to 75 vol % based on a total amount of components other than a solvent, the inorganic particles include boron nitride particles and particles different from the boron nitride particles, and a content of the boron nitride particles is 3 to 35 vol % based on a total amount of components other than a solvent.
• Tetramine Aspect Ratio and Flexibility Determine Framework Symmetry for Zn ₈ L ₆ Self‐Assembled Structures
  作者：Jack A. Davies、Andrew Tarzia、Tanya K. Ronson、Florian Auras、Kim E. Jelfs、Jonathan R. Nitschke

  DOI：10.1002/anie.202217987

  日期：2023.3

  Geometric design rules for the assembly of metal-organic capsules were derived. The preferred diastereomeric configurations of Zn8L6 pseudo-cubes, with T, Th, S6 and D3 symmetry, are shown to depend upon the aspect ratio and conformational flexibility of their constituent rectangular subunits. Computational methods allowed further design principles to be deciphered.

  导出了金属有机胶囊组装的几何设计规则。具有T 、 T h 、 S 6和D 3对称性的Zn 8 L 6假立方体的优选非对映异构构型显示取决于其组成的矩形亚基的长宽比和构象灵活性。计算方法使进一步的设计原理得以破译。