9-dibutylamino-6-(1-naphthyl)-5H-benzo[a]phenoxazine-5-one | 1427678-01-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并恶嗪类
• 英文名称: 9-dibutylamino-6-(1-naphthyl)-5H-benzo[a]phenoxazine-5-one
• 英文别名: 9-(Dibutylamino)-6-naphthalen-1-ylbenzo[a]phenoxazin-5-one；9-(dibutylamino)-6-naphthalen-1-ylbenzo[a]phenoxazin-5-one
• CAS: 1427678-01-0
• 化学式: C₃₄H₃₂N₂O₂
• 分子量: 500.64
• InChiKey: NEFRUIBQWCFYFX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.4
• 重原子数：
  38
• 可旋转键数：
  8
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  41.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  5-dibutylamino-2-nitrosophenol hydrochloride salt 在 2-双环己基膦-2',6'-二甲氧基联苯 、 tris-(dibenzylideneacetone)dipalladium(0) 、 sodium carbonate 作用下， 以 乙醇 、 水 、 N,N-二甲基甲酰胺 、 甲苯 为溶剂， 反应 19.0h， 生成 9-dibutylamino-6-(1-naphthyl)-5H-benzo[a]phenoxazine-5-one
  参考文献：
  名称：

  Solid-state fluorescence of 6-aryl-9-(dibutylamino)benzo[a]phenoxazin-5-ones

  摘要：

  6(9-Anthryl)- and 6(1-naphthyl)-9-(dibutylamino)benzo[a]phenoxazin-5-ones exhibited fluorescence maximum at around 700 nm in the crystalline form. Their fluorescence quantum yields were significantly higher than that of previously reported 6-perfluoro[4-methyl-3(1-methylethyl)pent-2-en-2-oxy] derivative due to the isolated dimer-type packing. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2013.02.083

文献信息

• Solid-state fluorescence of 6-aryl-9-(dibutylamino)benzo[a]phenoxazin-5-ones
  作者：Masaki Matsui、Yukiyo Ando、Osamu Tokura、Yasuhiro Kubota、Kazumasa Funabiki

  DOI：10.1016/j.tet.2013.02.083

  日期：2013.4

  6(9-Anthryl)- and 6(1-naphthyl)-9-(dibutylamino)benzo[a]phenoxazin-5-ones exhibited fluorescence maximum at around 700 nm in the crystalline form. Their fluorescence quantum yields were significantly higher than that of previously reported 6-perfluoro[4-methyl-3(1-methylethyl)pent-2-en-2-oxy] derivative due to the isolated dimer-type packing. (C) 2013 Elsevier Ltd. All rights reserved.