2-[3-methyl-4-(naphthalene-1-yl)phenyl]-4,6-bis(2,2'-bipyridin-6-yl)(1,3,5)triazine | 1008522-41-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 2-[3-methyl-4-(naphthalene-1-yl)phenyl]-4,6-bis(2,2'-bipyridin-6-yl)(1,3,5)triazine
• 英文别名: 2-(3-Methyl-4-naphthalen-1-ylphenyl)-4,6-bis(6-pyridin-2-ylpyridin-2-yl)-1,3,5-triazine
• CAS: 1008522-41-5
• 化学式: C₄₀H₂₇N₇
• 分子量: 605.701
• InChiKey: STMQEDKZVRCYKJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.4
• 重原子数：
  47
• 可旋转键数：
  6
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  90.2
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  2-(4-Bromo-3-methylphenyl)-4,6-bis(2,2'-bipyridin-6-yl)(1,3,5)triazine 、 1-萘硼酸 在 四(三苯基膦)钯 potassium carbonate 作用下， 以 乙醇 、 水 、 甲苯 为溶剂， 反应 5.5h， 以55%的产率得到2-[3-methyl-4-(naphthalene-1-yl)phenyl]-4,6-bis(2,2'-bipyridin-6-yl)(1,3,5)triazine
  参考文献：
  名称：

  EP2055704

  摘要：

  公开号：

文献信息

• COMPOUND HAVING TRIAZINE RING STRUCTURE SUBSTITUTED WITH PYRIDYL GROUP AND ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：Hodogaya Chemical Co., Ltd.

  公开号：EP2055704A1

  公开（公告）日：2009-05-06

  The present invention is to provide an organic compound having excellent characteristics as a material for an organic EL device having a high efficiency and a high durability, and to provide an organic EL device having a high efficiency and a high durability using the compound. The invention relates to a compound having a triazine ring structure having pyridyl groups attached thereto, which is represented by the general formula (1); and to an organic electroluminescent device comprising a pair of electrodes and at least one organic layer interposed between the electrodes, wherein the compound is used as a constituent material of at least one of the organic layer(s): wherein Ar represents a substituted or unsubstituted aromatic hydrocarbon group, a substituted or unsubstituted aromatic heterocyclic group, or a substituted or unsubstituted condensed polycyclic aromatic group; R1 to R8 may be the same or different from one another and each independently represents a hydrogen atom, a fluorine atom, a trifluoromethyl group, a cyano group, an alkyl group, a substituted or unsubstituted aromatic hydrocarbon group, a substituted or unsubstituted aromatic heterocyclic group, or a substituted or unsubstituted condensed polycyclic aromatic group.

  本发明旨在提供一种具有优异特性的有机化合物，作为具有高效率和高耐用性的有机电致发光器件的材料，并提供一种使用该化合物的具有高效率和高耐用性的有机电致发光器件。本发明涉及一种具有三嗪环结构的化合物，其上连接有吡啶基，通式（1）表示该化合物；本发明还涉及一种有机电致发光器件，该器件包括一对电极和至少一个夹在电极之间的有机层，其中该化合物用作至少一个有机层的组成材料： 其中 Ar 代表取代或未取代的芳香烃基团、取代或未取代的芳香杂环基团或取代或未取代的缩合多环芳香基团；R1 至 R8 可以相同或互不相同，各自独立地代表氢原子、氟原子、三氟甲基、氰基、烷基、取代或未取代的芳香烃基、取代或未取代的芳香杂环基、取代或未取代的缩合多环芳香基。
• Compound having triazine ring structure substituted with group and organic electroluminescent device
  申请人：Hodogaya Chemical Co., Ltd.

  公开号：EP2236506A1

  公开（公告）日：2010-10-06

  A compound having a triazine ring structure having pyridyl groups attached thereto, which is represented by the following general formula (1): wherein Ar represents a substituted phenyl group having a substituent selected from a fluorine atom, a chlorine atom, a cyano group, a nitro group, a cycloalkyl group, an alkoxy group, an amino group, a phenyl group, a naphthyl group, an anthryl group, a fluorenyl group, a styryl group, a biphenylyl group, a pyridyl group, a pyridoindolyl group, a quinolyl group, a benzothiazolyl group, a benzothiophenyl group, and a triazinyl group, which may be further substituted; R1 to R8 may be the same or different from one another and each independently represents a hydrogen atom, a fluorine atom, a trifluoromethyl group, a cyano group, an alkyl group, a substituted or unsubstituted aromatic hydrocarbon group, a substituted or unsubstituted aromatic heterocyclic group, or a substituted or unsubstituted condensed polycyclic aromatic group.

  一种具有三嗪环结构的化合物，其上连接有吡啶基，其通式如下（1）： 其中 Ar 代表取代基为取代苯基的基团，取代基选自氟原子、氯原子、氰基、硝基、环烷基、烷氧基、氨基、苯基、萘基、蒽基、芴基、苯乙烯基、双链烷基、蒽基、芴基、苯乙烯基、联苯基、吡啶基、吡啶吲哚基、喹啉基、苯并噻唑基、苯并噻吩基和三嗪基，这些基团可被进一步取代；R1 至 R8 可以相同或彼此不同，各自独立地代表氢原子、氟原子、三氟甲基、氰基、烷基、取代或未取代的芳香烃基、取代或未取代的芳香杂环基、取代或未取代的缩合多环芳香基。