2-[4'-(4''-bromophenoxy)phenyl]pyridine | 842121-92-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-[4'-(4''-bromophenoxy)phenyl]pyridine
• 英文别名: 2-[4-(4-Bromophenoxy)phenyl]pyridine
• CAS: 842121-92-0
• 化学式: C₁₇H₁₂BrNO
• 分子量: 326.192
• InChiKey: TYZFPZPXZXGBDR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  22.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  iridium(III) chloride 、 2-[4'-(4''-bromophenoxy)phenyl]pyridine 以 乙二醇乙醚 为溶剂， 反应 20.0h， 生成 iridium(III) bis{2-[4'-(4''-bromophenoxy)phenyl]pyridinato-N,C2'} μ-chloro bridged dimer
  参考文献：
  名称：

  [EN] AROMATIC MONOMER-AND CONJUGATED POLYMER-METAL COMPLEXES
  [FR] COMPLEXES METALLIQUES A BASE DE MONOMERE AROMATIQUE ET DE POLYMERE CONJUGUE

  摘要：

  描述了一种用于制备电子设备（如发光二极管(LED)设备）聚合物的卤代芳香单体-金属复合物。该芳香单体-金属复合物设计包括一个破坏共轭的连接基团，从而有利地减少或防止芳香单体片段与金属复合物片段之间的电子共轭。破坏共轭通常是为了保留从芳香单体-金属复合物形成的聚合物中金属复合物的磷光发射特性。由此产生的共轭电致发光聚合物具有精确控制的金属配合和电子性质，这些性质与聚合物主链的性质基本或完全独立。

  公开号：

  WO2005016945A1
• 作为产物：
  描述：

  2-(4-phenoxyphenyl)pyridine 在 N-溴代丁二酰亚胺(NBS) 作用下， 以 DMF (N,N-dimethyl-formamide) 为溶剂， 生成 2-[4'-(4''-bromophenoxy)phenyl]pyridine
  参考文献：
  名称：

  [EN] AROMATIC MONOMER-AND CONJUGATED POLYMER-METAL COMPLEXES
  [FR] COMPLEXES METALLIQUES A BASE DE MONOMERE AROMATIQUE ET DE POLYMERE CONJUGUE

  摘要：

  描述了一种用于制备电子设备（如发光二极管(LED)设备）聚合物的卤代芳香单体-金属复合物。该芳香单体-金属复合物设计包括一个破坏共轭的连接基团，从而有利地减少或防止芳香单体片段与金属复合物片段之间的电子共轭。破坏共轭通常是为了保留从芳香单体-金属复合物形成的聚合物中金属复合物的磷光发射特性。由此产生的共轭电致发光聚合物具有精确控制的金属配合和电子性质，这些性质与聚合物主链的性质基本或完全独立。

  公开号：

  WO2005016945A1

文献信息

• Aromatic monomer-and conjugated polymer-metal complexes
  申请人：Yu Wanglin

  公开号：US20050031900A1

  公开（公告）日：2005-02-10

  A halogenated aromatic monomer-metal complex useful for preparing a polymer for electronic devices such as a light-emitting diode (LED) device is described. The aromatic monomer-metal complex is designed to include a linking group that disrupts conjugation, thereby advantageously reducing or preventing electron delocalization between the aromatic monomer fragment and the metal complex fragment. Disruption of conjugation is often desirable to preserve the phosphorescent emission properties of the metal complex in a polymer formed from the aromatic monomer-metal complex. The resultant conjugated electroluminescent polymer has precisely controlled metal complexation and electronic properties that are substantially or completely independent of those of the polymer backbone.
• AROMATIC MONOMER- AND CONJUGATED POLYMER-METAL COMPLEXES
  申请人：YU Wanglin

  公开号：US20100160631A1

  公开（公告）日：2010-06-24

  A halogenated aromatic monomer-metal complex useful for preparing a polymer for electronic devices such as a light-emitting diode (LED) device is described. The aromatic monomer-metal complex is designed to include a linking group that disrupts conjugation, thereby advantageously reducing or preventing electron delocalization between the aromatic monomer fragment and the metal complex fragment. Disruption of conjugation is often desirable to preserve the phosphorescent emission properties of the metal complex in a polymer formed from the aromatic monomer-metal complex. The resultant conjugated electroluminescent polymer has precisely controlled metal complexation and electronic properties that are substantially or completely independent of those of the polymer backbone.
• US7705528B2
  申请人：——

  公开号：US7705528B2

  公开（公告）日：2010-04-27
• US8071769B2
  申请人：——

  公开号：US8071769B2

  公开（公告）日：2011-12-06
• [EN] AROMATIC MONOMER-AND CONJUGATED POLYMER-METAL COMPLEXES<br/>[FR] COMPLEXES METALLIQUES A BASE DE MONOMERE AROMATIQUE ET DE POLYMERE CONJUGUE
  申请人：DOW GLOBAL TECHNOLOGIES INC

  公开号：WO2005016945A1

  公开（公告）日：2005-02-24

  A halogenated aromatic monomer-metal complex useful for preparing a polymer for electronic devices such as a light-emitting diode (LED) device is described. The aromatic monomer-metal complex is designed to include a linking group that disrupts conjugation, thereby advantageously reducing or preventing electron delocalization between the aromatic monomer fragment and the metal complex fragment. Disruption of conjugation is often desirable to preserve the phosphorescent emission properties of the metal complex in a polymer formed from the aromatic monomer-metal complex. The resultant conjugated electroluminescent polymer has precisely controlled metal complexation and electronic properties that are substantially or completely independent of those of the polymer backbone.

  描述了一种用于制备电子设备（如发光二极管(LED)设备）聚合物的卤代芳香单体-金属复合物。该芳香单体-金属复合物设计包括一个破坏共轭的连接基团，从而有利地减少或防止芳香单体片段与金属复合物片段之间的电子共轭。破坏共轭通常是为了保留从芳香单体-金属复合物形成的聚合物中金属复合物的磷光发射特性。由此产生的共轭电致发光聚合物具有精确控制的金属配合和电子性质，这些性质与聚合物主链的性质基本或完全独立。