tris(4-trimethylsilylfuran-3-yl)boroxine | 148367-34-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 有机硼氧烷
• 英文名称: tris(4-trimethylsilylfuran-3-yl)boroxine
• 英文别名: tris<4-(trimethylsilyl)furan-3-yl>boroxine；Boroxin, tris[4-(trimethylsilyl)-3-furanyl]-；[4-[4,6-bis(4-trimethylsilylfuran-3-yl)-1,3,5,2,4,6-trioxatriborinan-2-yl]furan-3-yl]-trimethylsilane
• CAS: 148367-34-4
• 化学式: C₂₁H₃₃B₃O₆Si₃
• 分子量: 498.179
• InChiKey: UBOHSLVLQQPQDD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.65
• 重原子数：
  33
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  67.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  tris(4-trimethylsilylfuran-3-yl)boroxine 在 双氧水 作用下， 以 四氢呋喃 为溶剂， 以60%的产率得到4-trimethylsilyl-3(2H)-furanone
  参考文献：
  名称：

  Song, Zhi Zhong; Wong, Henry N. C., Journal of the Chinese Chemical Society, 1995, vol. 42, # 4, p. 673 - 680

  摘要：

  DOI：
• 作为产物：
  描述：

  三氯化硼 、 3,4-Bis(trimethylsilyl)furan 以 二氯甲烷 为溶剂， 以98%的产率得到tris(4-trimethylsilylfuran-3-yl)boroxine
  参考文献：
  名称：

  Song, Zhi Zhong; Zhou, Zhong Yuan; Mak, Thomas C. W., Angewandte Chemie, 1993, vol. 105, # 3, p. 406 - 408

  摘要：

  DOI：

文献信息

• Regiospecific substitution of the carbon–boron bond of tris(4-trimethylsilylfuran-3-yl)boroxine and tris(4-methylfuran-3-yl)boroxine. Model approaches towards sesquiterpenoid furanoeudesmanes
  作者：Chung-Yan Yick、Tsun-Keung Tsang、Henry N.C Wong

  DOI：10.1016/s0040-4020(02)01519-3

  日期：2003.1

  Furan-containing compounds occur abundantly in nature. Among them, the sesquiterpenoid furanoeudesmanes are particularly interesting due to their allergenic, plant-growth inhibiting, antibacterial as well as antitumor properties. Recently an organoboron protocol has been developed in our laboratory for the preparation of regiospecific-substituted furans. By utilizing such methodology, two common intermediates 1 and 2 that may lead to the synthesis of naturally occurring tubipofuran (3) furanoeudesm-4-ene (4) and furanoeudesma-1,4-dien-6-one (5) were obtained. (C) 2003 Elsevier Science Ltd. All rights reserved.
• Song, Zhi Zhong; Wong, Henry N. C., Journal of the Chinese Chemical Society, 1995, vol. 42, # 4, p. 673 - 680
  作者：Song, Zhi Zhong、Wong, Henry N. C.

  DOI：——

  日期：——
• Song, Zhi Zhong; Zhou, Zhong Yuan; Mak, Thomas C. W., Angewandte Chemie, 1993, vol. 105, # 3, p. 406 - 408
  作者：Song, Zhi Zhong、Zhou, Zhong Yuan、Mak, Thomas C. W.、Wong, Henry N. C.

  DOI：——

  日期：——