tri(methoxyethoxyethoxyethoxy)boroxine | 322471-05-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 有机硼氧烷
• 英文名称: tri(methoxyethoxyethoxyethoxy)boroxine
• 英文别名: 2,4,6-Tris(2-(2-(2-methoxyethoxy)ethoxy)ethoxy)-1,3,5,2,4,6-trioxatriborinane；2,4,6-tris[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]-1,3,5,2,4,6-trioxatriborinane
• CAS: 322471-05-6
• 化学式: C₂₁H₄₅B₃O₁₅
• 分子量: 570.012
• InChiKey: XHSSYJIHEHAECQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.91
• 重原子数：
  39
• 可旋转键数：
  30
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  138
• 氢给体数：
  0
• 氢受体数：
  15

反应信息

• 作为产物：
  描述：

  boron trioxide 、 三甘醇单甲醚 以 甲苯 为溶剂， 以70%的产率得到tri(methoxyethoxyethoxyethoxy)boroxine
  参考文献：
  名称：

  Boroxine ring compounds as dissociation enhancers in gel polyelectrolytes

  摘要：

  In order to combine the advantages of both traditional gel electrolytes and polyelectrolytes, a novel polyelectrolyte which incorporates a boroxine ring-containing anion-trapping agent has been explored. Poly(lithium 2-acrylamido-2-methyl-1-propanesulfonate) (PAMPSLi), ethylene carbonate (EC) and tri(methoxyethoxyethoxyethoxy)boroxine (TME(3)Bx) were combined to prepare various gel systems. The thermal properties and conductivities of these gels have been investigated. A conductivity of 10(-3.6) S cm(-1) at 20 degreesC has been achieved in a gel polyelectrolyte system with a molar ratio of [EC]:[TME(3)Bx]:[Li+] = 24:1.7:1. Temperature-dependent NMR measurements indicated that a significant interaction exists between the boroxine ring and the polyelectrolyte. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0013-4686(03)00151-8

文献信息

• Mehta, Mary Anne; Fujinami, Tatsuo; Inoue, Satoshi, Electrochimica Acta, 2000, vol. 45, # 8-9, p. 1175 - 1180
  作者：Mehta, Mary Anne、Fujinami, Tatsuo、Inoue, Satoshi、Matsushita, Kazumi、Miwa, Takashi、Inoue, Takayoshi

  DOI：——

  日期：——