Mesityl dichlorophosphate | 149864-64-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Mesityl dichlorophosphate
• 英文别名: 2-dichlorophosphoryloxy-1,3,5-trimethylbenzene
• CAS: 149864-64-2
• 化学式: C₉H₁₁Cl₂O₂P
• 分子量: 253.06
• InChiKey: VSLBACCOWAWFEY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  Calix[4]resorcinarene 、 Mesityl dichlorophosphate 生成 25,29,33,37-Tetramethyl-3,9,15,21-tetrakis(2,4,6-trimethylphenoxy)-2,4,8,10,14,16,20,22-octaoxa-3lambda5,9lambda5,15lambda5,21lambda5-tetraphosphanonacyclo[21.15.1.124,38.05,36.07,34.011,32.013,30.017,28.019,26]tetraconta-1(39),5,7(34),11,13(30),17(28),18,23,26,31,35,38(40)-dodecaene 3,9,15,21-tetraoxide
  参考文献：
  名称：

  Lippmann Tino, Wilde Horst, Dalcanale Enrico, Mavilla Luigi, Mann Gerhard+, J. Org. Chem, 60 (1995) N 1, S 235-242

  摘要：

  DOI：

文献信息

• METHOD FOR PRODUCING AN AMINO GROUP-CONTAINING PHOSPHATE COMPOUND, AND A FLAME-RETARDANT RESIN AND FLAME-RETARDANT RESIN COMPOSITION
  申请人：Kamata Hirotoshi

  公开号：US20100298506A1

  公开（公告）日：2010-11-25

  The present invention relates to a method for producing an amino group-containing phosphate compound, by which the compound can be easily synthesized through a one-step reaction. The method for producing an amino group-containing phosphate compound comprises reacting an aminophenol compound represented by the general formula (1) with a dichlorophosphoric acid compound represented by the general formula (2): (where X 1 , X 2 , X 3 , X 4 and X 5 each represent a hydrogen atom or an alkyl group having 1 to 3 carbon atoms) in the presence of an inorganic basic compound in an aprotic organic solvent, to obtain a amino group-containing phosphate compound represented by the following general formula (3) where X 1 , X 2 , X 3 , X 4 and X 5 are defined in the same way as in the general formula (2).

  本发明涉及一种制备含氨基磷酸盐化合物的方法，通过该方法，该化合物可以通过一步反应轻松合成。制备含氨基磷酸盐化合物的方法包括在无水有机溶剂中，在无机碱的存在下，将由通式（1）表示的氨基酚化合物与由通式（2）表示的二氯磷酸化合物反应（其中X1、X2、X3、X4和X5分别表示氢原子或具有1至3个碳原子的烷基），以得到由以下通式（3）表示的含氨基磷酸盐化合物（其中X1、X2、X3、X4和X5的定义与通式（2）中相同）。
• PROCESS FOR PRODUCTION OF AMINATED PHOSPHORIC ACID ESTER COMPOUND, FLAME-RETARDANT RESIN, AND FLAME-RETARDANT RESIN COMPOSITION
  申请人：SHOWA HIGHPOLYMER CO., LTD.

  公开号：EP2036911A1

  公开（公告）日：2009-03-18

  The present invention relates to a method for producing an amino group-containing phosphate compound, by which the compound can be easily synthesized through a one-step reaction. The method for producing an amino group-containing phosphate compound comprises reacting an aminophenol compound represented by the general formula (1) with a dichlorophosphoric acid compound represented by the general formula (2): (where X1, X2, X3, X4 and X5 each represent a hydrogen atom or an alkyl group having 1 to 3 carbon atoms) in the presence of an inorganic basic compound in an aprotic organic solvent, to obtain a amino group-containing phosphate compound represented by the following general formula (3) where X1, X2, X3, X4 and X5 are defined in the same way as in the general formula (2).

  本发明涉及一种生产含氨基的磷酸酯化合物的方法，通过该方法，可通过一步反应轻松合成该化合物。生产含氨基的磷酸酯化合物的方法包括使通式（1）代表的氨基苯酚化合物反应 与通式（2）所代表的二氯磷酸化合物反应： (其中 X1、X2、X3、X4 和 X5 各代表一个氢原子或一个具有 1 至 3 个碳原子的烷基），在无机碱性化合物存在下，在非烷基有机溶剂中反应，得到由以下通式 (3) 代表的含氨基的磷酸化合物 其中 X1、X2、X3、X4 和 X5 的定义与通式（2）相同。