diphenyl(2,3,4,5-tetrfluoro-6-phenylaminophenyl)phosphine oxide

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: diphenyl(2,3,4,5-tetrfluoro-6-phenylaminophenyl)phosphine oxide
• 英文别名: Diphenyl(2,3,4,5-tetrafluoro-6-phenylaminophenyl)phosphine oxide；2-diphenylphosphoryl-3,4,5,6-tetrafluoro-N-phenylaniline
• 化学式: C₂₄H₁₆F₄NOP
• 分子量: 441.365
• InChiKey: RDZMCNHYHMFUBR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  31
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  29.1
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  在 水 作用下， 以 乙醚 为溶剂， 反应 12.0h， 生成 diphenyl(2,3,4,5-tetrfluoro-6-phenylaminophenyl)phosphine oxide
  参考文献：
  名称：

  摘要：

  Reaction of pentafluorophenyl(diphenyl)phosphine with nitrilimines is a multistep process leading to formation of unstable fused heterocycles with a fluorophosphorane moiety as primary products. Their hydrolysis involves opening of the heteroring and subsequent cleavage of the N-N bond in intermediate phosphorylated hydrazones. The final products are diphenyl(6-arylamino-2,3,4,5-tetrafluorophenyl)phosphine oxides.

  DOI：

  10.1023/a:1012389908931

文献信息

• ——
  作者：Yu. G. Trishin、V. I. Namestnikov、V. K. Bel'skii

  DOI：10.1023/a:1012389908931

  日期：——

  Reaction of pentafluorophenyl(diphenyl)phosphine with nitrilimines is a multistep process leading to formation of unstable fused heterocycles with a fluorophosphorane moiety as primary products. Their hydrolysis involves opening of the heteroring and subsequent cleavage of the N-N bond in intermediate phosphorylated hydrazones. The final products are diphenyl(6-arylamino-2,3,4,5-tetrafluorophenyl)phosphine oxides.