A polymerizable composition suitable as an electric material and the like used in an electric circuit board, which comprises a norbornene monomer, a metathesis polymerization catalyst, and a chain transfer agent composed of a compound represented by formula (A) :
CH2=CH-Y-OCO-CR1=CH2
wherein Y represents a divalent hydrocarbon group having 3 to 20 carbon atoms, and R1 represents a hydrogen atom or a methyl group. By further comprising a crosslinking agent in the polymerizable composition, obtaining a crosslinkable resin by carrying out bulk polymerization, and crosslinking the crosslinkable resin to obtain a molded article and a crosslinked resin composite having excellent characteristics such as electric insulation, adhesion, mechanical strength, heat resistance, dielectric properties and the like.
一种可聚合组合物,适用于电路板中的电工材料等,它包括
降冰片烯单体、偏聚合催化剂和由式(A)表示的化合物组成的链转移剂:
CH2=CH-Y-OCO-CR1=
其中 Y 代表具有 3 至 20 个碳原子的二价烃基,R1 代表氢原子或甲基。通过在可聚合组合物中进一步加入
交联剂,通过批量聚合获得可交联
树脂,并对可交联
树脂进行交联,从而获得具有优异特性(如电绝缘性、粘附性、机械强度、耐热性、介电性能等)的成型品和交联
树脂复合材料。