1,3-Ditert-butyl-2,4-dicyclohexyl-2,4-diphosphabicyclo[1.1.0]butane

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 英文名称: 1,3-Ditert-butyl-2,4-dicyclohexyl-2,4-diphosphabicyclo[1.1.0]butane
• 化学式: C₂₂H₄₀P₂
• 分子量: 366.507
• InChiKey: LMWKALGOEGAYLU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  24
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  pentamethylcyclopentadienyl niobium(V) tetrachloride 、 (Z)-[MgCl)OEt2)(C(Bu-t)=P(cyclohexyl)] 以 甲苯 为溶剂， 以0%的产率得到
  参考文献：
  名称：

  Trapping Intermediates in Phosphavinyl Coupling Reactions:  Synthesis and Structural Characterization of a Novel Bis(phosphinoalkylidene)−Tantalum Complex, [{Cp*TaCl₂[C(Bu^t)−P(Cy)−]}₂]

  摘要：

  The reactions of the stable phosphavinyl Grignard reagent (Z)-[MgCl(OEt2){C(Bu-t)=PCy}] with [Cp*TaCl4] or [Cp*NbCl4] have been investigated. In both cases phosphavinyl coupling reactions are the ultimate outcome to give the known 2,4-diphosphabicyclo[1.1.0]butane, Cy2P2C2Bu2t, in the former and a mixture of this compound and its 1,2-dihydro-1,2-diphosphete valence isomer in the latter. A novel bis(phosphinoalkylidene)-tantalum complex, [{Cp*TaCl(2)f=C(Bu-t)-P(Cy)]}(2)], has been isolated and structurally characterized as an intermediate in the tantalum reaction.

  DOI：

  10.1021/om010632+

文献信息

• Trapping Intermediates in Phosphavinyl Coupling Reactions:  Synthesis and Structural Characterization of a Novel Bis(phosphinoalkylidene)−Tantalum Complex, [{Cp*TaCl₂[C(Bu^t)−P(Cy)−]}₂]
  作者：Cameron Jones、Anne F. Richards、Sebastian Fritzsche、Evamarie Hey-Hawkins

  DOI：10.1021/om010632+

  日期：2002.1.1

  The reactions of the stable phosphavinyl Grignard reagent (Z)-[MgCl(OEt2)C(Bu-t)=PCy}] with [Cp*TaCl4] or [Cp*NbCl4] have been investigated. In both cases phosphavinyl coupling reactions are the ultimate outcome to give the known 2,4-diphosphabicyclo[1.1.0]butane, Cy2P2C2Bu2t, in the former and a mixture of this compound and its 1,2-dihydro-1,2-diphosphete valence isomer in the latter. A novel bis(phosphinoalkylidene)-tantalum complex, [Cp*TaCl(2)f=C(Bu-t)-P(Cy)]}(2)], has been isolated and structurally characterized as an intermediate in the tantalum reaction.