bis(2-mercaptobenzothiazolato)cadmium(II) | 52139-05-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻唑类
• 英文名称: bis(2-mercaptobenzothiazolato)cadmium(II)
• 英文别名: bis(2-mercaptobenzothiazole)cadmium(II)；Cd(Mer)2；1,3-Benzothiazole-2-thiolate;cadmium(2+)
• CAS: 52139-05-6
• 化学式: C₁₄H₈CdN₂S₄
• 分子量: 444.905
• InChiKey: PALYVJMAJOQLGV-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  21
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  84.3
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  bis(2-mercaptobenzothiazolato)cadmium(II) 在 oleylamine 作用下， 以 neat (no solvent) 为溶剂， 生成 cadmium(II) sulphide
  参考文献：
  名称：

  Size-dependent blue luminescent CdS nanocrystals synthesized through a single-source molecular precursor route

  摘要：

  In this paper, we report on the synthesis of size-dependent blue luminescent US nanocrystals by using a new nonhydrolytic single-source molecular method. The size of the synthesized US nanocrystals could be easily controlled by adjusting the ratio of reaction sources under inert atmosphere. The studies on the optical properties reveal an obvious size-dependent photoluminescence characteristic of the synthesized nanocrystals. (C) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.materresbull.2007.06.012
• 作为产物：
  描述：

  cadmium(II) acetate 、 2-巯基苯并噻唑 以 乙醇 为溶剂， 生成 bis(2-mercaptobenzothiazolato)cadmium(II)
  参考文献：
  名称：

  Synthesis, characterization, 113Cd NMR and decomposition of some cadmium thiolates

  摘要：

  The synthesis and characterization of a number of cadmium complexes with sulphur-containing ligands including: 2-mercaptopyridine, 2-mercaptobenzothiazole, 2-mercaptothiazoline, 1,4,8,11-tetrathiaundecane, 5-mercapto-1-methyltetrazole and dithiocarbamates are reported. Cd-113 solid-state NMR spectroscopy has been used to characterize several of the compounds and many of the complexes decompose to cadmium sulphide.

  DOI：

  10.1016/s0277-5387(00)80152-7

文献信息

• Size-dependent blue luminescent CdS nanocrystals synthesized through a single-source molecular precursor route
  作者：Baoyou Geng、Xiaowang Liu、Qingbo Du、Jinzhu Ma、Xianming Liu

  DOI：10.1016/j.materresbull.2007.06.012

  日期：2008.5

  In this paper, we report on the synthesis of size-dependent blue luminescent US nanocrystals by using a new nonhydrolytic single-source molecular method. The size of the synthesized US nanocrystals could be easily controlled by adjusting the ratio of reaction sources under inert atmosphere. The studies on the optical properties reveal an obvious size-dependent photoluminescence characteristic of the synthesized nanocrystals. (C) 2007 Elsevier Ltd. All rights reserved.
• Synthesis, characterization, 113Cd NMR and decomposition of some cadmium thiolates
  作者：Omar F.Z. Khan、Paul O'Brien

  DOI：10.1016/s0277-5387(00)80152-7

  日期：1991.1

  The synthesis and characterization of a number of cadmium complexes with sulphur-containing ligands including: 2-mercaptopyridine, 2-mercaptobenzothiazole, 2-mercaptothiazoline, 1,4,8,11-tetrathiaundecane, 5-mercapto-1-methyltetrazole and dithiocarbamates are reported. Cd-113 solid-state NMR spectroscopy has been used to characterize several of the compounds and many of the complexes decompose to cadmium sulphide.