2,9,10-tricyanoanthracene | 131357-85-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 2,9,10-tricyanoanthracene
• 英文别名: Anthracene-2,9,10-tricarbonitrile
• CAS: 131357-85-2
• 化学式: C₁₇H₇N₃
• 分子量: 253.263
• InChiKey: JGWSCBKUFCAADX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  20
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  71.4
• 氢给体数：
  0
• 氢受体数：
  3

文献信息

• Silver halide light sensitive emulsion layer having enhanced photographic sensitivity
  申请人：EASTMAN KODAK COMPANY

  公开号：EP0786692A1

  公开（公告）日：1997-07-30

  A photographic element comprises at least one silver halide emulsion layer in which the silver halide is sensitized with a compound of formula         Z-(L-XY)k wherein: Z is a light absorbing group; L is a linking group containing a least one C, N, S, or O atom; and k is 1 or 2; and XY represents a fragmentable electron donor moiety wherein: 1) XY has a an oxidation potential between 0 and about 1.4 V; 2) X is an electron donor group; 3) Y is a leaving group other than hydrogen; and 4) the oxidized form of XY undergoes a bond cleavage reaction to give the radical X• and the leaving fragment Y. In a preferred embodiment the radical X• has an oxidation potential of ≤ -0.7 V.

  感光元件包括至少一个卤化银乳剂层，其中的卤化银是用式 1 的化合物感光的。 Z-(L-XY)k 其中 Z 是光吸收基团 L 是连接基团，含有至少一个 C、N、S 或 O 原子的连接基团；以及 k 是 1 或 2；以及 XY 代表可碎裂的电子供体分子，其中 1) XY 的氧化电位在 0 至约 1.4 V 之间； 2) X 是电子供体基团 3) Y 是氢以外的离去基团；以及 4) XY 的氧化形式发生键裂反应，生成自由基 X- 和离去片段 Y。 在一个优选的实施方案中，自由基 X- 的氧化电位≤ -0.7 V。
• Methods for forming and using silver metal
  申请人：Eastman Kodak Company

  公开号：US10087331B2

  公开（公告）日：2018-10-02

  A method for providing electrically-conductive silver-containing metal in a thin film or one or more thin film patterns on a substrate. Electrically-conductive metallic silver is provided from a non-hydroxylic-solvent soluble silver complex represented by the following formula (I): (Ag+)a(L)b(P)c   (I) wherein L represents an α-oxy carboxylate; P represents a 5- or 6-membered N-heteroaromatic compound; a is 1 or 2; b is 1 or 2; and c is 1, 2, 3, or 4, provided that when a is 1, b is 1, and when a is 2, b is 2. A photosensitizer can also be present. The reducible silver ions in the photosensitive thin film or photosensitive thin film pattern can be photochemically converted to electrically-conductive metallic silver in the thin films or thin film patterns by irradiation with electromagnetic radiation having a wavelength within the range of at least 150 nm and up to and including 700 nm.

  一种在基底上以薄膜或一种或多种薄膜图案提供导电含银金属的方法。导电金属银由下式 (I) 所代表的非羟基溶剂可溶银络合物提供： (Ag+)a(L)b(P)c (I) 其中 L 代表α-氧基羧酸盐；P 代表 5 或 6 元 N-杂芳香族化合物；a 是 1 或 2；b 是 1 或 2；c 是 1、2、3 或 4，条件是当 a 是 1 时，b 是 1，当 a 是 2 时，b 是 2。光敏薄膜或光敏薄膜图案中的可还原银离子，可通过波长在至少 150 纳米至 700 纳米（含）范围内的电磁辐射照射，光化学地转化为薄膜或薄膜图案中的导电金属银。
• Articles with reducible silver ions or silver metal
  申请人：Eastman Kodak Company

  公开号：US10314173B2

  公开（公告）日：2019-06-04

  A precursor article has a substrate and a photosensitive thin film or photosensitive thin film pattern on one or both supporting sides. A non-hydroxylic-solvent soluble silver complex is present that is represented by the following formula (I): (Ag+)a(L)b(P)c   (I) wherein L represents an α-oxy carboxylate; P represents a primary alkylamine; a is 1 or 2; b is 1 or 2; and c is 1, 2, 3, or 4, provided that when a is 1, b is 1, and when a is 2, b is 2. A photosensitizer can also be present to enhance photosensitivity for conversion of reducible silver ions to electrically-conductive silver metal in a resulting product article or device. The electrically-conductive silver metal can be provided as a uniform electrically-conductive silver metal-containing thin film or layer, or as one or more electrically-conductive silver metal-containing thin film patterns.

  一种前体物品有一个基底和一个或两个支撑面上的感光薄膜或感光薄膜图案。其中有一种非羟基溶剂型银络合物，由下式（I）表示： (Ag+)a(L)b(P)c (I) 其中 L 代表α-氧羧酸盐；P 代表伯烷基胺；a 是 1 或 2；b 是 1 或 2；c 是 1、2、3 或 4，条件是当 a 是 1 时，b 是 1，当 a 是 2 时，b 是 2。还可以使用光敏剂来提高光敏性，以便在所得到的产品物品或装置中将可还原银离子转化为导电银金属。导电银金属可作为均匀的含导电银金属的薄膜或层，或作为一个或多个含导电银金属的薄膜图案提供。
• Methods of providing electrically-conductive silver
  申请人：Eastman Kodak Company

  公开号：US10366800B2

  公开（公告）日：2019-07-30

  A method for providing electrically-conductive silver-containing metal in a thin film or one or more thin film patterns on a substrate. Electrically-conductive metallic silver is provided from a non-hydroxylic-solvent soluble silver complex represented by the following formula (I): (Ag+)a(L)b(P)c  (I) wherein L represents an α-oxy carboxylate; P represents an oxime compound; a is 1 or 2; b is 1 or 2; and c is 1, 2, 3, or 4, provided that when a is 1, b is 1, and when a is 2, b is 2. A photosensitizer can also be present. The reducible silver ions in the photosensitive thin film or photosensitive thin film pattern can be photochemically converted to electrically-conductive metallic silver in the thin films or thin film patterns by irradiation with electromagnetic radiation having a wavelength within the range of at least 150 nm and up to and including 700 nm.

  一种在基底上以薄膜或一种或多种薄膜图案提供导电含银金属的方法。导电金属银由下式 (I) 所代表的非羟基溶剂可溶银络合物提供： (Ag+)a(L)b(P)c (I) 其中 L 代表α-氧基羧酸盐；P 代表肟化合物；a 为 1 或 2；b 为 1 或 2；c 为 1、2、3 或 4，条件是当 a 为 1 时，b 为 1，当 a 为 2 时，b 为 2。光敏薄膜或光敏薄膜图案中的可还原银离子，可通过波长在至少 150 纳米至 700 纳米（含）范围内的电磁辐射照射，光化学地转化为薄膜或薄膜图案中的导电金属银。
• Method for making devices having dielectric layers with thiosulfate-containing polymers
  申请人：Eastman Kodak Company

  公开号：US10374178B2

  公开（公告）日：2019-08-06

  A semiconductor device can be prepared using a precursor dielectric composition that comprises: (1) a photochemically or thermally crosslinked product of a photocurable or thermally curable thiosulfate-containing polymer that has a Tg of at least 50° C. and that comprises: an organic polymer backbone comprising (a) recurring units comprising pendant thiosulfate groups; and further comprises charge balancing cations, and (2) optionally, an electron-accepting photo sensitizer component. The electronic device can be prepared by independently applying the precursor dielectric composition and an organic semiconductor composition to a substrate to form an applied precursor dielectric composition and an applied organic semiconductor composition, respectively, and subjecting the applied precursor dielectric composition to curing conditions to form a gate dielectric layer that is in physical contact with the applied organic semiconductor composition.

  可以使用前驱体介电组合物制备半导体器件，前驱体介电组合物包括：(1) 光化学或热交联的含硫代硫酸盐聚合物的产物，该聚合物的 Tg 至少为 50°C，并且包括：有机聚合物主链，该聚合物主链包括(a) 包含悬挂硫代硫酸盐基团的循环单元；并且进一步包括电荷平衡阳离子；以及 (2) 可选的电子接受光敏剂成分。电子器件的制备方法是：将前体电介质组合物和有机半导体组合物独立地施加到基底上，以分别形成施加的前体电介质组合物和施加的有机半导体组合物，并将施加的前体电介质组合物置于固化条件下，以形成与施加的有机半导体组合物物理接触的栅极电介质层。