申请人:Vertac Chemical Corporation
公开号:EP0021294A1
公开(公告)日:1981-01-07
A method for the reduction of the content of toxic chlorinated aromatic compounds such as chlorinated aromatic dioxins and especially chlorinated dibenzo-p-dioxins in reaction products to virtually zero consisting essentially of reacting a mass containing chlorinated aromatic dioxins with an amount, in excess of stoichiometrical based on the total organic halogen content, of alkaline reactants selected from the group consisting of (1) alkali metal alcoholates of alcohols selected from the group consisting of alkanols having from 1 to 5 carbon atoms, polyalkoxyalkane glycols having 4 to 20 carbon atoms, alkanepolyols having from 2 to 5 carbon atoms and 2 to 3 hydroxyls, and monoalkyl ethers of such alkanepolyols with alkanols having from 1 to 4 carbon atoms, or (2) mixtures of said alcohols with alkaline reactants selected from the group consisting of alkali metal hydroxides and carbonates, at a reaction temperature of from 140°C. to 220°C. for a time sufficient to convert the organic halogen into inorganic halide, recovering a reaction mass essentialiy free of chlorinated aromatic dioxins, and optionally suspending said recovered reaction mass in water and extracting with an organic solvept to remove any minute residual chlorinated aromatic dioxins, and recycling said solvent extract to said reacting step.
一种将反应产物中的有毒氯化芳香族化合物,如氯化芳香族二恶英,特别是氯化二苯并对二恶英的含量降低到几乎为零的方法,该方法主要是将含有氯化芳香族二恶英的物质与一定量的碱性反应物反应,碱性反应物的数量超过有机卤素总含量的化学计量,碱性反应物选自以下组别:(1)选自具有 1 至 5 个碳原子的烷醇的醇的碱金属醇酸酯、(2) 上述醇与选自碱金属氢氧化物和碳酸盐的碱性反应物的混合物,反应温度为 140°C 至 220°C。至 220°C,时间足以将有机卤素转化为无机卤化物,回收基本不含氯化芳香族二恶英的反应物,并可选择将所述回收的反应物悬浮于水中,用有机溶液萃取以去除任何微量残留的氯化芳香族二恶英,然后将所述溶剂萃取物循环用于所述反应步骤。