Methyl 2-[2-[4-(1-methyl-6-trifluoromethyl-2,4(1H,3H)-pyrimidinedion-3-yl)phenoxymethyl]-5-methylphenoxy]propionate | 158755-92-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Methyl 2-[2-[4-(1-methyl-6-trifluoromethyl-2,4(1H,3H)-pyrimidinedion-3-yl)phenoxymethyl]-5-methylphenoxy]propionate
• 英文别名: Methyl 2-[5-methyl-2-[[4-[3-methyl-2,6-dioxo-4-(trifluoromethyl)pyrimidin-1-yl]phenoxy]methyl]phenoxy]propanoate
• CAS: 158755-92-1
• 化学式: C₂₄H₂₃F₃N₂O₆
• 分子量: 492.452
• InChiKey: XHQISKPZUUJOQD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  35
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  85.4
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为产物：
  描述：

  methyl 2-(2-(chloromethyl)-5-methylphenoxy)propanoate 、 1-methyl-3-(4-hydroxyphenyl)-6-trifluoromethyl-2,4(1H,3H)-pyrimidinedione 、 Methyl 2-[2-[4-(4-difluoromethyl-4,5-dihydro-3-methyl-1,2,4-triazol-5(1H)-on-1-yl)-3-fluorophenoxymethyl]-5-methylphenoxy]propionate 生成 Methyl 2-[2[4-1-Methyl-7-trifluoromethyl-2,4-(1H,3H)-pyrimidienedion-3-yl)phenoxymethyl]-5-methylphenoxy]propionate 、 Methyl 2-[2-[4-(1-methyl-6-trifluoromethyl-2,4(1H,3H)-pyrimidinedion-3-yl)phenoxymethyl]-5-methylphenoxy]propionate
  参考文献：
  名称：

  摘要：

  DOI：

文献信息

• HERBICIDAL 2- (4-HETEROCYCLIC-PHENOXYMETHYL)PHENOXY]-ALKANOATES
  申请人：FMC CORPORATION

  公开号：EP0656892B1

  公开（公告）日：2001-06-13
• US5344812A
  申请人：——

  公开号：US5344812A

  公开（公告）日：1994-09-06
• [EN] HERBICIDAL 2-[(4-HETEROCYCLIC-PHENOXYMETHYL)PHENOXY]-ALKANOATES<br/>[FR] 2-[(4-PHENOXYMETHYL HETEROCYCLIQUE)PHENOXY]-ALCANOATES HERBICIDES
  申请人：FMC CORPORATION

  公开号：WO1994004514A1

  公开（公告）日：1994-03-03

  (EN) Herbicidal compouds, compositions containing them, and a method for controlling weeds by application of the compositions are disclosed. The herbicidal compounds are 2-[(4-heterocyclic-phenoxymethyl)phenoxy]-alkanoates of formula (I), in which A is a derivative of an alkanoate bonded to the phenoxy oxygen at the alpha carbon, and Q is 4-difluoromethyl-4,5-dihydro-3-methyl-1,2,4-triazol-5(1H)-on-1-yl, 3,4,5,6-tetrahydrophthalimid-1-yl, 1-(1-methylethyl)imidazolidin-2,4-dion-3-yl, 1,4-dihydro-4-(3-fluoropropyl)-5H-tetrazol-5-on-1-yl, 3-chloro-4,5,6,7-tetrahydroindazol-2-yl, 4-methyl-1,2,4-triazine-3,5-dion-2-yl, 8-thia-1,6-diazabicyclo[4.3.0]-nonane-7-on-9-ylimino, or 1-methyl-6-trifluoromethyl-2,4-pyrimidinedione-3-yl; X is hydrogen, methyl, fluorine, or chlorine; Y is hydrogen; W is oxygen or sulfur; Z is hydrogen, fluorine, chlorine, bromine, lower alkyl, or methoxy; Z' is hydrogen, fluorine, or chlorine; and the group AO- may be in the 2, 3, or 4- position of the phenyl ring.(FR) Sont décrits des composés herbicides, des compositions les renfermant, et un procédé de désherbage par application de ces compositions. Ces composés herbicides sont des 2-[(4-phénoxyméthyl hétérocyclique)phénoxy]-alcanoates de formule (I) dans laquelle A est un dérivé d'un alcanoate lié au phénoxy oxygène au niveau du carbone alpha, et Q est 4-difluorométhyl-4,5-dihydro-3-méthyl-1,2,4-triazol-5(1H)-on-1-yle, 3,4,5,6-tétrahydrophtalimid-1-yle, 1-(1-méthyléthyl)imidazolidin-2,4-dion-3-yle, 1,4-dihydro-4-(3-fluoropropyl)-5H-tétrazol-5-on-1-yle, 3-chloro-4,5,6,7-tétrahydroindazol-2-yle, 4-méthyl-1,2,4-triazine-3,5-dion-2-yle, 8-thia-1,6-diazabicyclo[4.3.0]-nonane-7-on-9-ylimino, ou bien 1-méthyl-6-trifluorométhyl-2,4-pyrimidinedione-3-yle; X est hydrogène, méthyle, fluor, ou chlore; Y est hydrogène; W est oxygène ou soufre; Z est hydrogène, fluor, chlore, brome, alkyle inférieur, ou bien méthoxy; Z' est hydrogène, fluor ou chlore; et le groupe AO- peut être dans la position 2, 3, ou 4 du noyau phényle.