cis,cis,trans-2,4,5-Trimethyl-1,3-dioxolan | 122045-48-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氧戊环
• 英文名称: cis,cis,trans-2,4,5-Trimethyl-1,3-dioxolan
• 英文别名: 2t,4t,5r-Trimethyl-<1,3>dioxolan；2c,4t,5r-Trimethyl-<1,3>dioxolan；r-2,cis-4,trans-5-Trimethyl-1,3-dioxolan；2,cis-4,trans-5-Trimethyl-1,3-dioxolan；2r,4c,5t-Trimethyl-<1,3>dioxolan；(4S,5S)-2,4,5-trimethyl-1,3-dioxolane
• CAS: 122045-48-1
• 化学式: C₆H₁₂O₂
• 分子量: 116.16
• InChiKey: HLEXJAVJCZLRTH-WHFBIAKZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  cis,cis,trans-2,4,5-Trimethyl-1,3-dioxolan 在 三氯化铝 、 lithium aluminium deuteride 作用下， 反应 2.0h， 生成 1,2-Dimethyl-3-oxa-1-pentanol-4-d
  参考文献：
  名称：

  Asymmetric synthesis at prochiral centers: substituted 1,3-dioxolanes

  摘要：

  DOI：

  10.1021/jo00338a011

文献信息

• INSECTICIDAL BIS(SUBSTITUTED PHENYL)-1-{[4-(SATURATED HETEROCYCLYL-SUBSTITUTED)PHENYLMETHYL]- (4-PIPERIDYL)}METHANE DERIVATIVES
  申请人：Lyga John W.

  公开号：US20090082203A1

  公开（公告）日：2009-03-26

  It has now been found that certain novel bis(substituted phenyl)-1 [4-(saturated heterocyclyl-substituted)phenyl-methyl](4-piperidyl)}methane derivatives have provided unexpected insecticidal activity. These compounds are represented by formula (I); where R through R 15 , m, n, s, A, B, D and W are defined herein. In addition, compositions comprising an insecticidally effective amount of at least one compound of formula (I), and optionally, an effective amount of at least one of a second compound, with at least one insecticidally compatible carrier are also disclosed; along with methods of controlling insects comprising applying said compositions to a locus where insects are present or are expected to be present.

  现在已经发现，某些新型的双（取代苯基）-1 [4-（饱和杂环取代）苯基甲基](4-哌啶基)}甲烷衍生物提供了意想不到的杀虫活性。这些化合物由式（I）表示; 其中R到R15，m，n，s，A，B，D和W在此定义。此外，本文还披露了包含式（I）中至少一种化合物的杀虫有效量和可选地至少一种第二化合物的有效量的组合物，其中至少包含一种杀虫剂兼容载体; 以及控制昆虫的方法，包括将所述组合物应用于昆虫存在或预计存在的地点。
• Asymmetric synthesis at prochiral centers: substituted 1,3-dioxolanes
  作者：Wolf Juergen Richter

  DOI：10.1021/jo00338a011

  日期：1981.12