| 39115-18-9

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• CAS: 39115-18-9
• 化学式: CBrCl₃
• 分子量: 198.37
• InChiKey: XNNQFQFUQLJSQT-ULIRUUBJSA-N

反应信息

• 作为反应物：
  描述：

  以 neat (no solvent) 为溶剂， 生成 三氯甲基自由基
  参考文献：
  名称：

  Charge States of Molecular Fragments from CCl₃Br Following Nuclear Decay of Br^80mand Br⁸²

  摘要：

  A comparison of the positive ionic fragments from dissociation of trichlorobrommethane by β—, γ decay of 35.9-hr Br82 and from isomeric transition of 4.4-hr Br80m was made by mass spectrometric techniques. Virtually all the products following beta decay are singly charged, while distributions of multiply charged atomic species dominate the fragmentation pattern after the isomeric transition. The results indicate that negative beta decay affects the molecule rather mildly, while the effect is violent following isomeric transition with internal conversion. In the latter mode of nuclear decay the molecule apparently explodes as a result of multicenter Coulombic repulsion.

  DOI：

  10.1063/1.1732817

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: C: MVol.D2, 3.2.3, page 70 - 71
  作者：

  DOI：——

  日期：——