7a-hydroxy-6c-isopropyl-1,7b-dimethyl-2,7-dioxo-(2ar,4ac,7ac,7bc)-decahydro-cyclopenta[cd]indole-5t-carboxylic acid methyl ester | 57084-96-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异喹啉及其衍生物
• 英文名称: 7a-hydroxy-6c-isopropyl-1,7b-dimethyl-2,7-dioxo-(2ar,4ac,7ac,7bc)-decahydro-cyclopenta[cd]indole-5t-carboxylic acid methyl ester
• 英文别名: rac-10-hydroxy-2,9-dioxo-9,12-seco-13-nor-dendroban-12-oic acid methyl ester
• CAS: 57084-96-5
• 化学式: C₁₇H₂₅NO₅
• 分子量: 323.389
• InChiKey: LZKAFIPMEAQQFZ-FLLSWRMBSA-N

反应信息

• 作为反应物：
  描述：

  7a-hydroxy-6c-isopropyl-1,7b-dimethyl-2,7-dioxo-(2ar,4ac,7ac,7bc)-decahydro-cyclopenta[cd]indole-5t-carboxylic acid methyl ester 在 聚合甲醛 、 甲酸 作用下， 反应 6.0h， 生成 From Dendrobium nobile
  参考文献：
  名称：

  SYNTHESIS OF 2-HYDROXYDENDROBINE AND NOBILINE

  摘要：

  An efficient method of introducing a hydroxy group at the C-2 position of the dendrobine skeleton using a keto lactam (1) is described. By means of this method 2-hydroxydendrobine (9) was synthesized from a keto lactam (4). Further, 2-hydroxydendrobine was transformed into nobiline (10).

  DOI：

  10.1246/cl.1975.611