(2R,3S)-2-Ethyl-3-hydroxy-2-[2-(6-methoxy-3,4-dihydro-naphthalen-1-yl)-ethyl]-cyclopentanone | 54202-03-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: (2R,3S)-2-Ethyl-3-hydroxy-2-[2-(6-methoxy-3,4-dihydro-naphthalen-1-yl)-ethyl]-cyclopentanone
• CAS: 54202-03-8
• 化学式: C₂₀H₂₆O₃
• 分子量: 314.425
• InChiKey: XTHMSESJHXSXPR-AZUAARDMSA-N

反应信息

• 作为反应物：
  描述：

  (2R,3S)-2-Ethyl-3-hydroxy-2-[2-(6-methoxy-3,4-dihydro-naphthalen-1-yl)-ethyl]-cyclopentanone 在 sodium tetrahydroborate 作用下， 生成 (1S,3S)-2-Ethyl-2-[2-(6-methoxy-3,4-dihydro-naphthalen-1-yl)-ethyl]-cyclopentane-1,3-diol
  参考文献：
  名称：

  Cyglization of 13β-ethyl-3-methoxt-17β-ol-8, 14-Seco- -1,3,5(10),9-gonatstraen-14-one and its 17 acetate derivative

  摘要：

  13beta-Ethyl-3-methoxy-17beta-ol-8,14-seco-1,3,5(10),8-gonatetraen-14-one (IIIa) was isolated and its participation in the well-known acidic cyclization process was established.

  DOI：

  10.1016/0039-128x(75)90015-x
• 作为产物：
  描述：

  (2R,3S)-2-Ethyl-3-hydroxy-2-{2-[6-methoxy-3,4-dihydro-2H-naphthalen-(1E)-ylidene]-ethyl}-cyclopentanone 在 溶剂黄146 作用下， 生成 (2R,3S)-2-Ethyl-3-hydroxy-2-[2-(6-methoxy-3,4-dihydro-naphthalen-1-yl)-ethyl]-cyclopentanone
  参考文献：
  名称：

  Cyglization of 13β-ethyl-3-methoxt-17β-ol-8, 14-Seco- -1,3,5(10),9-gonatstraen-14-one and its 17 acetate derivative

  摘要：

  13beta-Ethyl-3-methoxy-17beta-ol-8,14-seco-1,3,5(10),8-gonatetraen-14-one (IIIa) was isolated and its participation in the well-known acidic cyclization process was established.

  DOI：

  10.1016/0039-128x(75)90015-x