Methanesulfonic acid (1R,3aS,3bS,4S,5aR,8aR,8bS,10aR)-1-(1,5-dimethyl-hexyl)-8a,10a-dimethyl-6-methylene-hexadecahydro-dicyclopenta[a,f]naphthalen-4-yl ester | 77081-71-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 类固醇和类固醇衍生物
• 英文名称: Methanesulfonic acid (1R,3aS,3bS,4S,5aR,8aR,8bS,10aR)-1-(1,5-dimethyl-hexyl)-8a,10a-dimethyl-6-methylene-hexadecahydro-dicyclopenta[a,f]naphthalen-4-yl ester
• CAS: 77081-71-1
• 化学式: C₂₈H₄₈O₃S
• 分子量: 464.753
• InChiKey: JPNZDWYOLNFREB-LPNVNICJSA-N

反应信息

• 作为反应物：
  描述：

  Methanesulfonic acid (1R,3aS,3bS,4S,5aR,8aR,8bS,10aR)-1-(1,5-dimethyl-hexyl)-8a,10a-dimethyl-6-methylene-hexadecahydro-dicyclopenta[a,f]naphthalen-4-yl ester 在 lithium aluminium tetrahydride 作用下， 生成 (3aR,3bS,5aR,6R,8aS,8bS,10aR)-6-(1,5-Dimethyl-hexyl)-3a,5a-dimethyl-1-methylene-hexadecahydro-dicyclopenta[a,f]naphthalene
  参考文献：
  名称：

  Reductive cyclizations involving attack of radical anions derived from ketones, aldehydes and enones on isolated carbon-carbon triple and double bonds. Application of frontier molecular orbitals

  摘要：

  DOI：

  10.1021/jo00326a004