(1R,6S,8S,11R)-4,11,12,12-Tetramethyl-7-oxa-tricyclo[6.3.1.0^1,6]dodeca-3,9-dien-11-ol | 33880-93-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异吲哚及其衍生物
• 英文名称: (1R,6S,8S,11R)-4,11,12,12-Tetramethyl-7-oxa-tricyclo[6.3.1.0^1,6]dodeca-3,9-dien-11-ol
• CAS: 33880-93-2
• 化学式: C₁₅H₂₂O₂
• 分子量: 234.338
• InChiKey: XYLIUBFMCKBRML-VIRABCJISA-N

反应信息

• 作为产物：
  描述：

  (1R,6S,8R,11R)-3,8-Dibromo-4,11,12,12-tetramethyl-7-oxa-tricyclo[6.3.1.0^1,6]dodeca-3,9-dien-11-ol 在 lithium aluminium tetrahydride 作用下， 以 乙醚 为溶剂， 以58%的产率得到(1R,6S,8S,11R)-4,11,12,12-Tetramethyl-7-oxa-tricyclo[6.3.1.0^1,6]dodeca-3,9-dien-11-ol
  参考文献：
  名称：

  STRUCTURES OF TWO NEW HALOGENATED CHAMIGRANE-TYPE SESQUITERPENOIDS FROM THE RED ALGALAURENCIA NIPPONICAYAMADA

  摘要：

  Two new halo-chamigrane derivatives have been isolated from the title alga and the structure of one of them was determined on the basis of the spectral and chemical evidence. The structure of another compound was established by X-ray diffraction study of its monoacetate epoxide.

  DOI：

  10.1246/cl.1983.561

文献信息

• Darias, Jose; San-Martin, Aurelio; Rovirosa, Juana, Chemistry Letters, <hi>1990</hi>, # 2, p. 259 - 262
  作者：Darias, Jose、San-Martin, Aurelio、Rovirosa, Juana

  DOI：——

  日期：——