trans-{RuCl2(2,5,9,12-tetramethyl-2,5,9,12-tetraazatridecane)}Cl | 150413-04-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: trans-{RuCl2(2,5,9,12-tetramethyl-2,5,9,12-tetraazatridecane)}Cl
• CAS: 150413-04-0
• 化学式: C₁₃H₃₂Cl₂N₄Ru*Cl
• 分子量: 451.853
• InChiKey: QPUFDSFZLINNAD-UHFFFAOYSA-K

反应信息

• 作为反应物：
  描述：

  六氟磷酸钾 、 trans-{RuCl2(2,5,9,12-tetramethyl-2,5,9,12-tetraazatridecane)}Cl 在 HCl 、 NaOH 、 N₂ 作用下， 以 水 为溶剂， 以70%的产率得到trans{Ru(OH)(N2)(2,5,9,12-tetramethyl-2,5,9,12-tetraazatridecane)}PF6*H2O
  参考文献：
  名称：

  Dynamics in N₂Uptake by New Ruthenium(II) Tertiary Polyamine Complexes in Aqueous Solution

  摘要：

  When Ti(III)Cl3 was injected to aqueous 1 mM HCl solutions of trans-[Ru(III)Cl2L1]+ (L1 = 2,5,9,12-tetramethyl-2,5,9,12-tetraazatridecane) under N2, almost quantitative N2 uptake by the reduced ruthenium(II) complex was observed. The first order initial rate constant 2.6 ± 0.3 × 10−4 s−1 was obtained which is the highest value among those so far reported. Much lower rate constants and absorption ratios were observed for homologous ruthenium tertiary polyamine complexes.

  DOI：

  10.1246/cl.1993.1761