| 106084-82-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• CAS: 106084-82-6
• 化学式: C₁₆H₃₆N*Cl₆Os
• 分子量: 645.387
• InChiKey: IKIQWCLMXQVKKH-UHFFFAOYSA-H

反应信息

• 作为产物：
  描述：

  bis(tetra-n-butylammonium) hexachloroosmate(IV) 在 (C₄H₉)3NBF₄ 作用下， 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Spectroelectrochemical studies of hexachlorometallates. Optical charge transfer spectra of [MCl6]1− anions

  摘要：

  Thin layer spectroelectrochemical techniques have been employed to show that the MCl62- anions (M = Re, Os, Ir and Ru) undergo a reversible one-electron oxidation in methylene chloride to the corresponding pentavalent complex at low temperatures. In the case of Ir and Ru this affords the first opportunity to examine the optical charge transfer spectrum of these highly oxidised complexes, whilst for Re and Os high quality spectral data are presented. A comparison of the ligand to metal charge transfer spectra of the electrochemically generated pentavalent complexes with their more familiar isoelectronic hexavalent analogues is presented.

  DOI：

  10.1016/s0020-1693(00)83856-6

文献信息

• Groth, Th.; Preetz, W., Zeitschrift für Naturforschung. Teil A, Physik, physikalische Chemie, Kosmophysik, 1986, vol. 41, p. 1222 - 1227
  作者：Groth, Th.、Preetz, W.

  DOI：——

  日期：——