ethyl 2-(2-oxo-1,2-dihydronaphtho[2,1-b]thiophen-1-yl)-2-(1,1,1-triphenyl-λ⁵-phosphanylidene)acetate | 1160699-44-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: ethyl 2-(2-oxo-1,2-dihydronaphtho[2,1-b]thiophen-1-yl)-2-(1,1,1-triphenyl-λ⁵-phosphanylidene)acetate
• CAS: 1160699-44-4
• 化学式: C₃₄H₂₇O₃PS
• 分子量: 546.626
• InChiKey: FVENWIBDJQXSAC-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  以 丙酮 为溶剂， 生成 ethyl 2-(2-oxo-1,2-dihydronaphtho[2,1-b]thiophen-1-yl)-2-(1,1,1-triphenyl-λ⁵-phosphanylidene)acetate
  参考文献：
  名称：

  Synthesis of Alkyl 2-(2-Oxo-1,2-dihydronaphtho [2,1-b]thiophen-1-yl)-2-(1,1,1-triphenyl-λ ⁵-phosphanylidene)acetates from Triphenylphosphine, Acetylenic Esters, and 2-Naphthalenethiol

  摘要：

  A one-pot synthesis of alkyl 2-(2-oxo-1,2-dihydronaphtho[2,1-b]thiophen-1-yl)-2-(1,1,1-triphenyl-lambda(5) -phosphanylidene)acetates in fairly high yields by the reaction of 2-naphthalenethiol, dialkyl acetylenedicarboxylates and triphenylphosphine is reported. The formulas of these compounds were confirmed by IR, H-1,P-31, and C-13 NMR spectroscopy. The NMR spectra indicated that solutions of the phosphorus ylides (CDCl3 as solvent) contain two rotamers (E and Z). The relative percentages of rotamers in CDCl3 for each phosphorus ylide were determined from the P-31 NMR spectra.

  DOI：

  10.1080/10426500701839825