4,4'-(2-(4-iodophenyl)ethene-1,1-diyl)bis(N,N-dimethylaniline) | 1226622-45-2

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 4,4'-(2-(4-iodophenyl)ethene-1,1-diyl)bis(N,N-dimethylaniline)
• CAS: 1226622-45-2
• 化学式: C₂₄H₂₅IN₂
• 分子量: 468.38
• InChiKey: RZKIVVJRWQCGHX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.01
• 重原子数：
  27.0
• 可旋转键数：
  5.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  6.48
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  4,4'-(2-(4-iodophenyl)ethene-1,1-diyl)bis(N,N-dimethylaniline) 、 三甲基乙炔基硅 在 copper(l) iodide 、 bis(triphenylphosphine)palladium(II) dichloride 作用下， 以 四氢呋喃 、 三乙胺 为溶剂， 反应 2.0h， 以96%的产率得到
  参考文献：
  名称：

  Branched charge-transfer chromophores featuring a 4,5-dicyanoimidazole unit

  摘要：

  Six branched and stable push-pull chromophores featuring 4,5-dicyanoimidazole as an acceptor moiety, an N,N-dimethylamino group as a donor and various pi-conjugated linkers are reported. Systematic extension of the pi-linker revealed that the optical and electrochemical properties of A-pi-D chromophores are mainly affected by the nature of the pi-conjugated backbone (length and planarity) as well as by the number of appended donors. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.02.067
• 作为产物：
  描述：

  4,4'-(2-(4-bromophenyl)ethene-1,1-diyl)bis(N,N-dimethylaniline) 在 正丁基锂 、 碘 作用下， 以 四氢呋喃 为溶剂， 生成 4,4'-(2-(4-iodophenyl)ethene-1,1-diyl)bis(N,N-dimethylaniline)
  参考文献：
  名称：

  Branched charge-transfer chromophores featuring a 4,5-dicyanoimidazole unit

  摘要：

  Six branched and stable push-pull chromophores featuring 4,5-dicyanoimidazole as an acceptor moiety, an N,N-dimethylamino group as a donor and various pi-conjugated linkers are reported. Systematic extension of the pi-linker revealed that the optical and electrochemical properties of A-pi-D chromophores are mainly affected by the nature of the pi-conjugated backbone (length and planarity) as well as by the number of appended donors. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.02.067