5,5-dimethyl-4,7-diazadecane-1,10-diamine | 58770-16-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 5,5-dimethyl-4,7-diazadecane-1,10-diamine
• 英文别名: 5,5-dimethyl-4,7-diazadecane-1,10-diamine C10H26N4, orange；1-N,2-N-bis(3-aminopropyl)-2-methylpropane-1,2-diamine
• CAS: 58770-16-4
• 化学式: C₁₀H₂₆N₄
• 分子量: 202.343
• InChiKey: MCXNLWTXOPGHCQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.2
• 重原子数：
  14
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  76.1
• 氢给体数：
  4
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  copper(II) perchlorate hexahydrate 、 5,5-dimethyl-4,7-diazadecane-1,10-diamine 以 甲醇 、 乙醇 为溶剂， 生成 {(5,5-dimethyl-4,7-diazadecane-1,10-diamine-N,N',N'',N''')(perchlorato-O)copper(II)} perchlorate
  参考文献：
  名称：

  (5,5-Dimethyl-4,7-diazadecane-1,10-diamine-N,N',N'',N''')(perchlorato-O)copper(II) perchlorate

  摘要：

  The Cu(II) ion in the title complex, [Cu(ClO4)(C10H26N4)]ClO4, is five-coordinate with four N atoms equatorial and one perchlorato O atom axial. The two asymmetric N atoms are of the same R or S configuration. Each six-membered ring is in a stable chair conformation and the central five-membered ring is in a skew form. Hydrogen bonds help stabilize the crystal structure.

  DOI：

  10.1107/s010827019300959x

文献信息

• Two Forms of (5,5-Dimethyl-4,7-diazadecane-1,10-diamine)nickel(II) Diperchlorate
  作者：T. H. Tahirov、T. H. Lu、K. Shu、C. S. Chung

  DOI：10.1107/s0108270194009492

  日期：1995.2.15

  The title Ni(II) complex, [Ni(C10H26N4)](ClO4)2, crystallizes in yellow and orange forms. In both crystals, the stereochemistry and conformation of the complex cations are identical. Small differences arise from packing effects, differences in the orientations of the perchlorate groups and hydrogen bonding. The Ni(II) atom has square-planar coordination with the four tetraamine N atoms in equatorial positions. In each complex, the two chiral N-atom centres are in the (4RS,7RS) configuration. The tetraamine binds to the Ni(II) atom in a relatively strain-free planar manner; the central six-membered ring exhibits a stable chair conformation and the two terminal five-membered rings adopt stable skew forms.