1,3-di[o-(o-vanillideneimino)phenoxo]-2-propanol | 219973-61-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 1,3-di[o-(o-vanillideneimino)phenoxo]-2-propanol
• 英文别名: 2-[[2-[2-Hydroxy-3-[2-[(2-hydroxy-3-methoxyphenyl)methylideneamino]phenoxy]propoxy]phenyl]iminomethyl]-6-methoxyphenol
• CAS: 219973-61-2
• 化学式: C₃₁H₃₀N₂O₇
• 分子量: 542.588
• InChiKey: HRTQFMNADMHTSF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  40
• 可旋转键数：
  12
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.16
• 拓扑面积：
  122
• 氢给体数：
  3
• 氢受体数：
  9

反应信息

• 作为反应物：
  描述：

  吡啶 、 tetrakis(acetato)diaquadicopper(II) 、 1,3-di[o-(o-vanillideneimino)phenoxo]-2-propanol 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  Synthesis, structure and electrochemistry of dinuclear copper(II) complex with dinucleating Schiff-base ligand

  摘要：

  A new ligand, 1,3-di[o-(o-vanillideneimino)phenoxo]-2-propanol H2L, has been prepared stepwise and identified by elemental analyses (EA), IR and H-1 NMR spectra. The title complex [Cu2L2](py)(2)(H2O)(2) has been synthesized by reaction of H2L and Cu(OAc)(2)H2O, and characterized by EA and IR. The redox properties of the dinuclear complex have been investigated by cyclic voltammetry. Two successive, one-electron, quasi reversible processes indicate an interaction between two copper centers. The title complex structure is solved by X-ray diffraction. In the centro-symmetric unit [Cu2L2], only phenolic and imino groups bind Cu atoms to form two distortional square coordination geometries, parallel to each other; and the Cu Cu separation is 9.87 Angstrom. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00136-3