Adian-5-ene | 1615-95-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 类固醇和类固醇衍生物
• 英文名称: Adian-5-ene
• 英文别名: (3R,3aR,5aR,11bR,13aS)-3a,5a,8,8,11b,13a-hexamethyl-3-propan-2-yl-1,2,3,4,5,5b,6,9,10,11,11a,12,13,13b-tetradecahydrocyclopenta[a]chrysene
• CAS: 1615-95-8
• 化学式: C₃₀H₅₀
• 分子量: 410.727
• InChiKey: WZDKBHGEBSMIQO-GYGSZJQCSA-N

物化性质

• 熔点：
  190.5-191.5 °C
• 沸点：
  463.7±12.0 °C(Predicted)
• 密度：
  0.96±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  10.5
• 重原子数：
  30
• 可旋转键数：
  1
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.93
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Adian-5-ene 在 氧气 、 臭氧 作用下， 以 正己烷 为溶剂， 以63 mg的产率得到Adian-5-ene Ozonide
  参考文献：
  名称：

  Ozone-oxidation products of triterpenoid hydrocarbons belonging to the hopane and migrated hopane series.

  摘要：

  The ozone oxidation reaction of eleven triterpenoid monoenes belonging to the hopane and migrated hopane series was investigated. Under suitable reacftion conditions, various reaction products including three ozonides, seven epoxides and one ketone were obtained from the eight starting materials. The reaction of glutin-5-ene was also examined for comparison.

  DOI：

  10.1248/cpb.38.79
• 作为产物：
  描述：

  (3R,3aR,5aR,11bR,13aS)-3a,5a,8,8,11b,13a-hexamethyl-3-propan-2-yl-1,2,3,4,5,5b,6,9,10,12,13,13b-dodecahydrocyclopenta[a]chrysene 生成 Adian-5-ene
  参考文献：
  名称：

  AGETA, HIROYUKI;SHIOJIMA, KENJI;ARAI, YOKO, CHEM. AND PHARM. BULL., 35,(1987) N 7, 2705-2716

  摘要：

  DOI：

文献信息

• AGETA, HIROYUKI;SHIOJIMA, KENJI;ARAI, YOKO, CHEM. AND PHARM. BULL., 35,(1987) N 7, 2705-2716
  作者：AGETA, HIROYUKI、SHIOJIMA, KENJI、ARAI, YOKO

  DOI：——

  日期：——
• Ozone-oxidation products of triterpenoid hydrocarbons belonging to the hopane and migrated hopane series.
  作者：Kenji SHIOJIMA、Kazuo MASUDA、Hiroyuki AGETA

  DOI：10.1248/cpb.38.79

  日期：——

  The ozone oxidation reaction of eleven triterpenoid monoenes belonging to the hopane and migrated hopane series was investigated. Under suitable reacftion conditions, various reaction products including three ozonides, seven epoxides and one ketone were obtained from the eight starting materials. The reaction of glutin-5-ene was also examined for comparison.