5-Dimethylamino-3-methyl-1-pentanol | 55424-63-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 5-Dimethylamino-3-methyl-1-pentanol
• 英文别名: 5-Dimethylamino-3-methyl-pentanol；5-(dimethylamino)-3-methylpentan-1-ol
• CAS: 55424-63-0
• 化学式: C₈H₁₉NO
• 分子量: 145.245
• InChiKey: GZGKPOCYYNKGCV-UHFFFAOYSA-N

物化性质

• 沸点：
  197.8±23.0 °C(Predicted)
• 密度：
  0.876±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  10
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  23.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1-Dimethylamino-3-methyl-pent-4-en 在 sodium tetrahydroborate 、 三氟化硼乙醚 作用下， 以 二乙二醇二甲醚 为溶剂， 生成 5-Dimethylamino-3-methyl-1-pentanol
  参考文献：
  名称：

  Stern,P. et al., Collection of Czechoslovak Chemical Communications, 1974, vol. 39, p. 3538 - 3547

  摘要：

  DOI：

文献信息

• PROCESS FOR PRODUCING HYDROXYALKYLTRIETHYLENEDIAMINE, AND CATALYST COMPOSITION FOR THE PRODUCTION OF POLYURETHANE RESIN USING IT
  申请人：Tokumoto Katsumi

  公开号：US20110077376A1

  公开（公告）日：2011-03-31

  To provide a process for producing a hydroxyalkyltriethylenediamine or hydroxytriethylenediamine simply and in a small number of steps without requiring multi-stage reaction steps; a novel catalyst composition whereby a polyurethane product can be obtained with good productivity and good moldability without bringing about odor problems or environmental problems; and a process for producing a polyurethane resin using the catalyst composition. For example, a hydroxyalkyltriethylenediamine or hydroxytriethylenediamine is produced by subjecting a mono-substituted dihydroxyalkylpiperazine and/or a di-substituted hydroxyalkylpiperazine to an intramolecular dehydration condensation reaction in the presence of an acid catalyst. Further, for example, a polyurethane resin is produced by using a catalyst composition which comprises a hydroxyalkyltriethylenediamine or hydroxytriethylenediamine (A), and an amine compound (B) having, in its molecule, one or more substituents selected from the group consisting of a hydroxy group, a primary amino group and a secondary amino group, or a tertiary amine compound (C) having a value of [blowing reaction rate constant/gelling reaction rate constant] of at least 0.5.

  提供一种简单且步骤较少的工艺，用于生产羟基烷基三乙烯二胺或羟基三乙烯二胺，而无需进行多级反应步骤；一种新颖的催化剂组合物，可以在不产生异味或环境问题的情况下获得具有良好生产率和良好成型性的聚氨酯产品；以及使用催化剂组合物生产聚氨酯树脂的工艺。例如，通过在酸催化剂存在下，使单取代二羟基烷基哌嗪和/或双取代羟基烷基哌嗪经历分子内脱水缩合反应，可以生产羟基烷基三乙烯二胺或羟基三乙烯二胺。此外，例如，使用催化剂组合物生产聚氨酯树脂，该组合物包括羟基烷基三乙烯二胺或羟基三乙烯二胺（A），以及在其分子中具有一个或多个取代基的胺化合物（B），所述取代基选自羟基、一级胺基和二级胺基的群，或者具有至少0.5的[发泡反应速率常数/凝胶反应速率常数]值的三级胺化合物（C）。
• PROCESS FOR PRODUCING POLYURETHANE
  申请人：Kao Corporation

  公开号：EP1270630A1

  公开（公告）日：2003-01-02

  A catalyst for producing a polyurethane, comprising a dialkylaminoalkyl alcohol represented by the formula (I):         R1R2N-X-OH     (I) wherein each of R1 and R2 is independently an alkyl group having 1 to 4 carbon atoms; and X is a branched alkylene group having 4 to 8 carbon atoms; a process for producing a polyurethane, comprising reacting a polyol component with an isocyanate component in the presence of the above-mentioned catalyst for producing a polyurethane; and a process for producing a polyurethane foam, comprising reacting a polyol component with an isocyanate component in the presence of the above-mentioned catalyst for producing a polyurethane, and a compound having a primary amino group and a tertiary amino group in its molecule, and a blowing agent. The polyurethane can be used as heat insulating materials for construction materials, electric refrigerators, refrigerated warehouses, baths and the like, interior materials for automobiles, furnishings, cushioning materials for beddings, various sealing materials and the like.

  一种生产聚氨酯的催化剂，由式 (I) 所代表的二烷基氨基烷基醇组成： R1R2N-X-OH (I) 其中 R1 和 R2 各自独立地为具有 1 至 4 个碳原子的烷基；X 为具有 4 至 8 个碳原子的支链亚烷基； 生产聚氨酯的工艺，包括在上述生产聚氨酯的催化剂存在下，使多元醇组分与异氰酸酯组分反应；以及一种生产聚氨酯泡沫塑料的工艺，包括在上述催化剂存在下，使多元醇组分与异氰酸酯组分反应，以生产聚氨酯，以及在其分子中具有伯氨基和叔氨基的化合物和发泡剂。这种聚氨酯可用作建筑材料、电冰箱、冷藏库、浴缸等的隔热材料、汽车内饰材料、家具、床上用品的缓冲材料、各种密封材料等。
• Method for producing a rigid polyurethane foam
  申请人：Tosoh Corporation

  公开号：EP1273604A1

  公开（公告）日：2003-01-08

  A method for producing a rigid polyurethane foam, which comprises reacting a polyol with a polyisocyanate in the presence of an amine catalyst and a blowing agent, wherein as the amine catalyst, at least one amine compound having at least one type of substituent selected from the group consisting of a hydroxyl group, a primary amino group and a secondary amino group in its molecule, or N-(2-dimethylaminoethyl)-N'-methylpiperazine, is used, and as the blowing agent, 1,1,1,3,3-pentafluoropropane (HFC-245fa) and/or 1,1,1,3,3-pentafluorobutane (HFC-365mfc) is used.

  一种生产硬质聚氨酯泡沫塑料的方法，包括在胺催化剂和发泡剂存在下使多元醇与多异氰酸酯反应，其中作为胺催化剂，至少一种胺化合物在其分子中具有至少一种类型的取代基，该取代基选自由羟基、伯氨基和仲氨基组成的组，或 N-(2-二甲基氨基乙基)-N'-甲基哌嗪、或 N-（2-二甲基氨基乙基）-N'-甲基哌嗪，作为发泡剂，使用 1,1,1,3,3-五氟丙烷（HFC-245fa）和/或 1,1,1,3,3-五氟丁烷（HFC-365mfc）。
• Process for the production of flexible polyurethane foams
  申请人：Tosoh Corporation

  公开号：EP1312630A1

  公开（公告）日：2003-05-21

  Flexible polyurethane foams are produced by reacting a polyol and a polyisocyanate in the presence of a catalysts and other auxiliary agents, the process characterized in that a tin-based catalyst is not used. One process includes reacting a polyether polyol containing at least 5% by weight of an oxyethylene group in the chain and having a terminal secondary OH group, a toluene diisocyanate and/or a derivative, and one or more specified imidazole compounds, the process conducted in the absence of a tin-based catalyst.

  柔性聚氨酯泡沫塑料是通过多元醇和多异氰酸酯在催化剂和其他辅助剂的存在下发生反应而生产的，该工艺的特点是不使用锡基催化剂。一种工艺包括使一种在链中含有至少 5%（按重量计）氧乙烯基并具有末端仲羟基的聚醚多元醇、一种甲苯二异氰酸酯和/或衍生物以及一种或多种特定咪唑化合物发生反应，该工艺在无锡基催化剂的情况下进行。
• FLEXIBLE POLYURETHANE FOAM AND PROCESS FOR PRODUCING THE SAME
  申请人：ASAHI GLASS COMPANY LTD.

  公开号：EP1666514A1

  公开（公告）日：2006-06-07

  A process for producing a flexible polyurethane foam which comprises foaming a starting material composition (E) comprising a high molecular weight polyoxyalkylene polyol (A), an organic polyisocyanate compound (B), a blowing agent (C) and a catalyst (D) in a closed mold, characterized in that at least a part of the high molecular weight polyoxyalkylene polyol (A) is a polyoxyalkylene polyol (p) having at least two hydroxyl groups on the average and having a molecular weight (Mc) per hydroxyl group of from 1,800 to 2,800 and a total unsaturation value (USV) of at most 0.08 meq/g, and that the air flowability of a flexible polyurethane foam obtained by foaming the starting material composition (E) in a thickness of 26 mm, is at most 0.085 m3/min.

  一种生产软质聚氨酯泡沫塑料的工艺，包括在密闭模具中发泡由高分子量聚氧 乙烯多元醇(A)、有机多异氰酸酯化合物(B)、发泡剂(C)和催化剂(D)组成的起始 材料组合物(E)、其特征在于至少一部分高分子量聚氧亚烷基多元醇 (A) 是聚氧亚烷基多元醇 (p)，平均至少有两个羟基，每个羟基的分子量 (Mc) 在 1,800 至 2,800 之间，总不饱和值 (USV) 至多为 0.08 meq/g，通过发泡起始材料组合物(E)得到的软质聚氨酯泡沫的空气流动性至多为 0.085 立方米/分钟，厚度为 26 毫米。