carbon monoxide;dichloropalladium | 158363-66-7

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: carbon monoxide;dichloropalladium
• CAS: 158363-66-7
• 化学式: C₂Cl₄O₂Pd₂
• 分子量: 410.673
• InChiKey: FAIGFWUORXZRMR-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  2.68
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  2
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  carbon monoxide;dichloropalladium 以 氯化亚砜 为溶剂， 以49%的产率得到
  参考文献：
  名称：

  Molecular Structure of[Pd6Cl12] in Single Crystals Chemically Grown at Room Temperature

  摘要：

  A reduction of the CO partial pressure is sufficient to obtain single crystals of [Pd6Cl12] from the equilibrium (a) in thionyl chloride (solv.) at room temperature. The single‐crystal and powder X‐ray diffraction characterization of this PdII chloride is described. equation image

  DOI：

  10.1002/anie.199613311
• 作为产物：
  描述：

  一氧化碳 、 palladium dichloride 以 氯化亚砜 为溶剂， 生成 carbon monoxide;dichloropalladium
  参考文献：
  名称：

  Molecular Structure of[Pd6Cl12] in Single Crystals Chemically Grown at Room Temperature

  摘要：

  A reduction of the CO partial pressure is sufficient to obtain single crystals of [Pd6Cl12] from the equilibrium (a) in thionyl chloride (solv.) at room temperature. The single‐crystal and powder X‐ray diffraction characterization of this PdII chloride is described. equation image

  DOI：

  10.1002/anie.199613311

文献信息

• Halo-carbonyl complexes of platinum(II) and palladium(II)
  作者：Franco Bagnoli、Daniela Belli Dell'Amico、Fausto Calderazzo、Ulli Englert、Fabio Marchetti、Alessandra Merigo、Stefano Ramello

  DOI：10.1016/s0022-328x(00)00947-5

  日期：2001.3

  The mononuclear and binuclear square-planar complexes of palladium(II) and platinum(II) cis-PtCl2(CO)2 (1), trans- Pt2Cl4(CO)2 (2), cis-PtBr2(CO)2 (3), and cis-Pd2Cl4(CO)2 (4), have been prepared by new synthetic procedures and some of them (2, 3, and 4) structurally characterised by X-ray diffraction methods. In the mononuclear platinum derivatives, cis-PtX2(CO)2, X=Cl, Br, the molecules are arranged

  钯（II）和铂（II）的顺式-PtCl 2（CO）2（1），反式-Pt 2 Cl 4（CO）2（2），顺式-PtBr 2（CO ）2（3），和顺式-Pd 2氯4（CO）2（4），制备了由新的合成方法，其中一些（的2，3和4）通过X射线衍射法进行结构表征。在单核铂衍生物cis -PtX 2（CO）2，X = Cl，Br中，分子排列在列中，Pt ⋯ Pt的间距为3.378Å（X = Cl）或3.65Å（av。，X = Br）。氯化物桥连的双核氯-羰基配合物M 2 Cl 4（CO）2，M = Pd，Pt，含有末端氯和羰基，对于铂衍生物2是反式的，但是对于相应的钯化合物4却是顺式的。包装基于分子间C ⋯ X或Pt ⋯Pt相互作用取决于卤化物的性质。铂（II）的四卤代配合物在存在作为卤化物清除剂的AlX 3的情况下在大气压和室温下羰基化会生成[PtX 3（CO）] -或PtX 2（CO）2，具体取决于Pt
• Molecular Structure of[Pd6Cl12] in Single Crystals Chemically Grown at Room Temperature
  作者：Daniela Belli Dell'Amico、Fausto Calderazzo、Fabio Marchetti、Stefano Ramello

  DOI：10.1002/anie.199613311

  日期：1996.7.9

  A reduction of the CO partial pressure is sufficient to obtain single crystals of [Pd6Cl12] from the equilibrium (a) in thionyl chloride (solv.) at room temperature. The single‐crystal and powder X‐ray diffraction characterization of this PdII chloride is described. equation image