Thiophosphoric acid O,O',O''-tripentyl ester | 17513-82-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机硫代磷酸及其衍生物
• 英文名称: Thiophosphoric acid O,O',O''-tripentyl ester
• 英文别名: Tripentylphosphorothioate；tripentoxy(sulfanylidene)-λ5-phosphane
• CAS: 17513-82-5
• 化学式: C₁₅H₃₃O₃PS
• 分子量: 324.465
• InChiKey: KRGWQWQLDWWLIB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  20
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  59.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  Thiophosphoric acid O,O',O''-tripentyl ester 、 Triheptylphosphorothioate 、 Trioctylthiophosphat 、 Tridecylphosphorothioate 、 Tridodecylphosphorothioate 、 Tripentadecylphosphorothioate 、 Trioctadecylphosphorothioate 、 Trieicosylphosphorothioate 生成 O,O,O-三丁基硫代磷酸酯
  参考文献：
  名称：

  Lubricant composition containing an alkali-metal borate and a mixture of

  摘要：

  本发明涉及一种含有磷酸盐、单硫代磷酸盐和双硫代磷酸盐的且具有临界比例的碱金属硼酸盐润滑剂。

  公开号：

  US04431552A1

文献信息

• Refrigerating Machine Oil, and Working Fluid Composition for Refrigerating Machine Which is Produced Using Same
  申请人：KH NEOCHEM CO., LTD.

  公开号：US20160168500A1

  公开（公告）日：2016-06-16

  Provided is a refrigerating machine oil which comprises an ester between a polyol consisting of at least one of pentaerythritol and dipentaerythritol represented by formula (I) and 2-propylheptanoic acid, and is characterized in that the refrigerating machine oil can be used in combination with a refrigerant consisting of 1,3,3,3-tetrafluoropropene (HFO-1234ze). When the refrigerating machine oil is used in combination with a refrigerant consisting of HFO-1234ze, excellent miscibility with the refrigerant, lubricity, thermal and chemical stability and the like can be achieved.

  提供的是一种制冷机油，其包括一种酯，该酯由式（I）表示的至少含有一种戊四醇和重聚戊四醇的多元醇和2-丙基庚酸之间的酯化反应形成，其特征在于该制冷机油可以与由1,3,3,3-四氟丙烯（HFO-1234ze）组成的制冷剂结合使用。当该制冷机油与由HFO-1234ze组成的制冷剂结合使用时，可以实现与制冷剂的良好相容性、润滑性、热和化学稳定性等。
• Flame retardant polyphenylene oxide thermoplastics
  申请人：GENERAL ELECTRIC COMPANY

  公开号：EP0175281A2

  公开（公告）日：1986-03-26

  Flame retardant blends of polyphenylene oxide and styrene resin are provided as a result of the use of a minor amount of a triorganothiophosphate.

  由于使用了少量的三有机硫代磷酸酯，提供了聚苯醚和苯乙烯树脂的阻燃混合物。
• Process for preparing liquid triaryl thiophosphate mixtures
  申请人：AKZO N.V.

  公开号：EP0245852A2

  公开（公告）日：1987-11-19

  Liquid mixed triaryl thiophosphate mixtures can be prepared by forming a mixture of phenol and substituted phenols, forming a phosphite from that mixture and sulfurizing the phosphite, washing the thiophosphate with aqueous base, and drying the so washed thiophosphate under mild conditions. The products are liquid while containing at least 25 percent symmetrical triaryl thiophosphate. Colorless and odorless products are prepared.

  液态混合三芳基硫代磷酸酯混合物可通过以下方法制备：形成苯酚和取代苯酚的混合物，从该混合物中形成亚磷酸酯并对亚磷酸酯进行硫化，用水基洗涤硫代磷酸酯，并在温和条件下干燥洗涤后的硫代磷酸酯。 产品为液态，同时含有至少 25% 的对称三芳基硫代磷酸酯。 可制备出无色无味的产品。
• Metal free hydraulic fluid with amine salt
  申请人：THE LUBRIZOL CORPORATION

  公开号：EP0667389A2

  公开（公告）日：1995-08-16

  Functional fluids comprising an oil of lubricating viscosity, the reaction product of an amine and a sulfonic acid, and at least one sulfur-containing compound of the structure         (RX)3P=X where X is sulfur or oxygen exhibit good anti-rust and antiwear performance.

  功能性流体，包括具有润滑粘度的油、胺和磺酸的反应产物以及至少一种结构的含硫化合物 (RX)3P=X 其中 X 为硫或氧，具有良好的防锈和抗磨损性能。
• Base oil for carbon dioxide refrigerant and refrigerating machine oil composition
  申请人：Nippon Mitsubishi Oil Corporation

  公开号：EP1211302A1

  公开（公告）日：2002-06-05

  A refrigerating machine oil for a carbon dioxide refrigerant according to the present invention contains polyalkylene glycol represented by the following general formula (1):         R1-(OR3)n-OR2}m     (1) [where R1 represents a residue obtained by removing m hydroxyl groups from an organic compound having three to ten hydroxyl groups, R2 hydrogen, an alkylene group of one to five carbons, or an acyl group of one to five carbons, R3 an alkylene group of two to four carbons, m an integer of 3 to 10, and n such an integer that a number average molecular weight of the polyalkylene glycol (1) becomes 500 to 3000],    wherein a kinematic viscosity at 100°C of the polyalkylene glycol is 5-20 mm2/s.

  根据本发明，一种用于二氧化碳制冷剂的冷冻机油含有由以下通式（1）表示的聚亚烷基二醇： R1-(OR3)n-OR2}m (1) [其中 R1 代表从具有三至十个羟基的有机化合物中除去 m 个羟基而得到的残余物，R2 代表氢、一至五个碳原子的亚烷基或一至五个碳原子的酰基，R3 代表二至四个碳原子的亚烷基，m 代表 3 至 10 的整数，n 代表使聚亚烷基二醇（1）的平均分子量变为 500 至 3000 的整数]、 其中聚亚烷基二醇在 100°C 时的运动粘度为 5-20 mm2/s。