4-ethenyl-3-methyl-N-[4-[4-(N-(3-methylphenyl)anilino)phenyl]phenyl]-N-phenylaniline | 847690-46-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4-ethenyl-3-methyl-N-[4-[4-(N-(3-methylphenyl)anilino)phenyl]phenyl]-N-phenylaniline
• CAS: 847690-46-4
• 化学式: C₄₀H₃₄N₂
• 分子量: 542.723
• InChiKey: CXRUGKMXCFPVKK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.5
• 重原子数：
  42
• 可旋转键数：
  8
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  甲基三苯基溴化膦 、 N,N'-二苯基-N,N'-二(3-甲基苯基)-1,1'-联苯-4,4'-二胺 、 N,N-二甲基甲酰胺 在 三氯氧磷 作用下， 反应 2.5h， 以75%的产率得到N-phenyl-N,N'-di[m-tolyl]-N'-[(4-vinylphenyl)]biphenyl-4,4'-diamine
  参考文献：
  名称：

  空穴传输主体聚合物系列，由三苯胺基本结构组成，用于磷光聚合物发光二极管

  摘要：

  合成了一系列具有三苯胺基单元的新型苯乙烯衍生单体及其聚合物，并将其与众所周知的N，N'-双（3-甲基苯基）-N，N的聚合物结构进行了比较'-二苯基联苯胺在磷光聚合物发光二极管（PLED）中的空穴传输行为方面。选择乙烯基三苯胺结构作为基本单元，在对位具有以下侧基的官能团：二苯胺，3-甲基苯基-苯胺，1-和2-萘胺，咔唑和吩噻嗪。该聚合物在PLED中用作以下系统配置的共混体系的主体聚合物：玻璃/铟锡氧化物/ PEDOT：PSS /聚合物共混物/ CsF / Ca / Ag。除空穴传输主体聚合物外，聚合物共混物还包括磷光掺杂剂[Ir（Me-ppy）3 ]和电子传输分子（2-（4-联苯）-5-（4-叔丁基）-丁基苯基）-1,3,4-恶二唑）。我们证明，对于这些共混体系而言，两种聚合物是出色的空穴传输基质材料，因为它们具有良好的整体电致发光性能和较高的玻璃化转变温度。对于咔唑取代的聚合物（T g =

  DOI：

  10.1002/pola.24127

文献信息

• Phosphorescent polymer compound and organic light emitting device using the same
  申请人：Koyama Tamami

  公开号：US20070155928A1

  公开（公告）日：2007-07-05

  The present invention relates to a phosphorescent polymer compound comprising a phosphorescent monomer unit and a hole transporting monomer unit having a triphenylamine structure represented by the formula (1): (in the formula, the symbols have the same meanings as defined in the Description), and an organic light emitting device using the compound. Use of the phosphorescent polymer compound of the present invention enables production of organic light emitting device with a high light emitting efficiency at a low voltage, which is suitable for increasing the emission area and mass production.

  本发明涉及一种荧光聚合物化合物，包括一个荧光单体单元和一个孔传输单体单元，该孔传输单体单元具有三苯胺结构，由公式（1）表示：（在公式中，符号与说明中定义的含义相同），以及使用该化合物的有机发光装置。使用本发明的荧光聚合物化合物可以在低电压下生产具有高发光效率的有机发光装置，适用于增加发射面积和大规模生产。
• COMPOSITION FOR ANODE BUFFER LAYERS, HIGH-MOLECULAR COMPOUND FOR ANODE BUFFER LAYERS, ORGANIC ELECTROLUMINESCENT ELEMENT, PROCESS FOR PRODUCTION OF SAME, AND USE THEREOF
  申请人：Showa Denko K.K.

  公开号：EP2495287A1

  公开（公告）日：2012-09-05

  There is provided a material for an anode buffer layer which permits the use of an organic solvent as a solvent of an anode buffer layer-forming solution, and is capable of forming an anode buffer layer that does not dissolve even when coated with a luminescent layer-forming material solution containing an organic solvent as a solvent, and which is capable of producing an organic EL element having high electrical power efficiency and long life. The composition for an anode buffer layer includes an electron-accepting compound and a high-molecular weight compound having a structural unit represented by the following formula (1) or the following formula (2) and having a weight average molecular weight of 20,000 to 1,000,000 as measured by GPC: wherein in each of the formulae (1) and (2), plural Ras are each a hydrogen atom or an alkyl group, with at least one Ra being the alkyl group, plural Rbs are each a hydrogen atom or an alkyl group, plural Rcs are each a hydrogen atom, an alkyl group or the like, X is a single bond or the like, Y is a structure derived from a vinyl group and the like, and p is 0, 1 or 2.

  本发明提供了一种用于阳极缓冲层的材料，该材料允许使用有机溶剂作为阳极缓冲层形成溶液的溶剂，并且能够形成即使涂覆了含有有机溶剂作为溶剂的发光层形成材料溶液也不会溶解的阳极缓冲层，并且能够生产出具有高电功率效率和长寿命的有机电致发光元件。 用于阳极缓冲层的组合物包括一种电子接受化合物和一种高分子量化合物，其结构单元由下式（1）或下式（2）表示，经 GPC 测定，其重量平均分子量为 20,000 至 1,000,000： 其中，在式（1）和式（2）中，多个 Ras 各为氢原子或烷基，其中至少一个 Ra 为烷基；多个 Rbs 各为氢原子或烷基；多个 Rcs 各为氢原子、烷基或类似物；X 为单键或类似物；Y 为乙烯基等衍生结构；p 为 0、1 或 2。
• PHOSPHORESCENT POLYMER COMPOUND AND ORGANIC LIGHT EMITTING DEVICE USING THE SAME
  申请人：Showa Denko K.K.

  公开号：EP1664237B1

  公开（公告）日：2008-10-08
• COMPOSITION FOR ANODE BUFFER LAYER, HIGH-MOLECULAR WEIGHT COMPOUND FOR ANODE BUFFER LAYER, ORGANIC ELECTROLUMINESCENCE ELEMENT, AND PRODUCTION PROCESS AND USES OF THE SAME
  申请人：Osako Haruka

  公开号：US20120217491A1

  公开（公告）日：2012-08-30

  There is provided a material for an anode buffer layer which permits the use of an organic solvent as a solvent of an anode buffer layer-forming solution, and is capable of forming an anode buffer layer that does not dissolve even when coated with a luminescent layer-forming material solution containing an organic solvent as a solvent, and which is capable of producing an organic EL element having high electrical power efficiency and long life. The composition for an anode buffer layer includes an electron-accepting compound and a high-molecular weight compound having a structural unit represented by the following formula (1) or the following formula (2) and having a weight average molecular weight of 20,000 to 1,000,000 as measured by GPC: wherein in each of the formulae (1) and (2), plural R a s are each a hydrogen atom or an alkyl group, with at least one R a being the alkyl group, plural R b s are each a hydrogen atom or an alkyl group, plural R c S are each a hydrogen atom, an alkyl group or the like, X is a single bond or the like, Y is a structure derived from a vinyl group and the like, and p is 0, 1 or 2.
• US9644048B2
  申请人：——

  公开号：US9644048B2

  公开（公告）日：2017-05-09