(4-(9-phenyl-fluoren-9-yl)-phenyl)-(4-(9-phenyl-9H-carbazol-3-yl)-phenyl)-biphenyl-4-yl-amine | 1160294-92-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: (4-(9-phenyl-fluoren-9-yl)-phenyl)-(4-(9-phenyl-9H-carbazol-3-yl)-phenyl)-biphenyl-4-yl-amine
• 英文别名: 4-phenyl-N-[4-(9-phenylcarbazol-3-yl)phenyl]-N-[4-(9-phenylfluoren-9-yl)phenyl]aniline
• CAS: 1160294-92-7
• 化学式: C₆₁H₄₂N₂
• 分子量: 803.018
• InChiKey: DPEAUNUZXDLYCQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  16.2
• 重原子数：
  63
• 可旋转键数：
  8
• 环数：
  12.0
• sp3杂化的碳原子比例：
  0.02
• 拓扑面积：
  8.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  9-(4-溴苯基)-9-苯基芴 、 N-[4-(9-苯基-9H-咔唑-3-基)苯基]-[1,1'-联苯]-4-胺 在 三叔丁基膦 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ sodium t-butanolate 作用下， 以 正己烷 、 xylene 为溶剂， 反应 5.5h， 以76%的产率得到(4-(9-phenyl-fluoren-9-yl)-phenyl)-(4-(9-phenyl-9H-carbazol-3-yl)-phenyl)-biphenyl-4-yl-amine
  参考文献：
  名称：

  [EN] CARBAZOLE DERIVATIVE, AND LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, AND ELECTRONIC DEVICE USING CARBAZOLE DERIVATIVE
  [FR] DÉRIVÉ CARBAZOLE, ET ÉLÉMENT ÉMETTANT DE LA LUMIÈRE, DISPOSITIF ÉMETTANT DE LA LUMIÈRE, ET DISPOSITIF ÉLECTRONIQUE UTILISANT LE DÉRIVÉ CARBAZOLE

  摘要：

  为提供具有高发光效率的发光元件，并提供一种低功耗、低电压驱动的发光装置和电子设备，提供了由通式（1）表示的咔唑衍生物。在该式中，α1、α2、α3 和 α4 分别表示具有小于或等于 13 个碳原子的芳基基团；Ar1 和 Ar2 分别表示具有小于或等于 13 个碳原子的芳基基团；R1 表示氢原子、具有 1 到 6 个碳原子的烷基基团、取代或未取代的苯基团，以及取代或未取代的联苯基团中的任意一种；R2 表示具有 1 到 6 个碳原子的烷基基团、取代或未取代的苯基团，以及取代或未取代的联苯基团中的任意一种。此外，l、m 和 n 分别独立地为 0 或 1。

  公开号：

  WO2009072587A1

文献信息

• Carbazole Derivative, and Light-Emitting Element, Light-Emitting Device, and Electronic Device Using Carbazole Derivative
  申请人：Nomura Hiroko

  公开号：US20090160323A1

  公开（公告）日：2009-06-25

  To provide a light-emitting element having high luminous efficiency and to provide a light-emitting device and an electronic device which consumes low power and is driven at low voltage, a carbazole derivative represented by the general formula (1) is provided. In the formula, α 1 , α 2 , α 3 , and α 4 each represent an arylene group having less than or equal to 13 carbon atoms; Ar 1 and Ar 2 each represent an aryl group having less than or equal to 13 carbon atoms; R 1 represents any of a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted phenyl group, and a substituted or unsubstituted biphenyl group; and R 2 represents any of an alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted phenyl group, and a substituted or unsubstituted biphenyl group. In addition, l, m, and n are each independently 0 or 1.

  为了提供具有高发光效率的发光元件，并提供低功耗、低电压驱动的发光装置和电子装置，提供了由通式（1）表示的咔唑衍生物。在该式中，α1、α2、α3和α4各代表具有小于或等于13个碳原子的芳烃基；Ar1和Ar2各代表具有小于或等于13个碳原子的芳基；R1代表氢原子、具有1至6个碳原子的烷基、取代或未取代的苯基和取代或未取代的联苯基中的任意一种；R2代表具有1至6个碳原子的烷基、取代或未取代的苯基和取代或未取代的联苯基中的任意一种。此外，l、m和n各自独立地为0或1。
• CARBAZOLE-BASED COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME
  申请人：Samsung Display Co., Ltd.

  公开号：US20170179400A1

  公开（公告）日：2017-06-22

  An organic light-emitting device including: a first electrode; a second electrode facing the first electrode; and an organic layer between the first electrode and the second electrode, the organic layer including an emission layer, wherein the organic layer includes a carbazole-based compound represented by Formula 1A or 1B: When the carbazole-based compound represented by Formula 1A or 1B is included in the hole transport layer, an organic light-emitting device may have improved driving voltage, efficiency, luminance, and lifespan characteristics.

  一种有机发光器件，包括：第一电极；与第一电极相对的第二电极；以及位于第一电极和第二电极之间的有机层，该有机层包括一个发射层，其中该有机层包括由式1A或1B表示的咔唑基化合物： 当由式1A或1B表示的咔唑基化合物包含在空穴传输层中时，有机发光器件的驱动电压、效率、亮度和寿命特性可能得到改善。
• Carbazole derivative, and light-emitting element, light-emitting device, and electronic device uing carbazole derivative
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：EP2757094A1

  公开（公告）日：2014-07-23

  The present invention provides a novel carbazole derivative which may be used for the production of a light-emitting element having high luminous efficiency, and for the manufacture of light-emitting devices and electronic devices which consume low power and are driven at low voltage.

  本发明提供了一种新型咔唑衍生物，可用于生产具有高发光效率的发光元件，以及制造低功耗、低电压驱动的发光器件和电子设备。
• Carbazole derivative, and light-emitting element, light-emitting device, and electronic device using the carbazole derivative
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US10556864B2

  公开（公告）日：2020-02-11

  To provide a light-emitting element having high luminous efficiency and to provide a light-emitting device and an electronic device which consumes low power and is driven at low voltage, a carbazole derivative represented by the general formula (1) is provided. In the formula, α1, α2, α3, and α4 each represent an arylene group having less than or equal to 13 carbon atoms; Ar1 and Ar2 each represent an aryl group having less than or equal to 13 carbon atoms; R1 represents any of a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted phenyl group, and a substituted or unsubstituted biphenyl group; and R2 represents any of an alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted phenyl group, and a substituted or unsubstituted biphenyl group. In addition, l, m, and n are each independently 0 or 1.

  为了提供一种具有高发光效率的发光元件，并提供一种低功耗和低电压驱动的发光器件和电子器件，提供了一种由通式（1）表示的咔唑衍生物。式中，α1、α2、α3 和 α4 分别代表具有小于或等于 13 个碳原子的芳基；Ar1 和 Ar2 分别代表具有小于或等于 13 个碳原子的芳基；R1 代表氢原子、具有 1 至 6 个碳原子的烷基、取代或未取代的苯基和取代或未取代的联苯基中的任一种；以及 R2 代表具有 1 至 6 个碳原子的烷基、取代或未取代的苯基和取代或未取代的联苯基中的任一种。此外，l、m 和 n 各自独立地为 0 或 1。
• Light-emitting element, light-emitting device, electronic device, and lighting device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US10897012B2

  公开（公告）日：2021-01-19

  A light-emitting element having a long lifetime is provided. A light-emitting element exhibiting high emission efficiency in a high luminance region is provided. A light-emitting element includes a light-emitting layer between a pair of electrodes. The light-emitting layer contains a first organic compound, a second organic compound, and a phosphorescent compound. The first organic compound is represented by a general formula (G0). The molecular weight of the first organic compound is greater than or equal to 500 and less than or equal to 2000. The second organic compound is a compound having an electron-transport property. In the general formula (G0), Ar1 and Ar2 each independently represent a fluorenyl group, a spirofluorenyl group, or a biphenyl group, and Ar3 represents a substituent including a carbazole skeleton.

  提供了一种使用寿命长的发光元件。提供了一种在高亮度区域具有高发射效率的发光元件。发光元件包括位于一对电极之间的发光层。发光层包含第一有机化合物、第二有机化合物和磷光化合物。第一种有机化合物的通式为 (G0)。第一种有机化合物的分子量大于或等于 500，小于或等于 2000。第二种有机化合物是一种具有电子传输特性的化合物。在通式（G0）中，Ar1 和 Ar2 各自独立地代表芴基、螺芴基或联苯基，Ar3 代表包括咔唑骨架的取代基。